Thermodynamic properties inorganic compounds

George, P, and McClure, D. S. The Effect of Inner Orbital Splitting on the Thermodynamic Properties of Compounds and Complexes of the Transition Metals, in Cotton s Progress in Inorganic Chemistry, Vol. I, 381-464, Interscience Publishers, New York (1959). 

References D. D. Wagman, et ah, The NBS Tables of Chemical Thermodynamic Properties, in J. Phys. Chem. Ref. Data, 11 2,1982 M. W. Chase, et ah, JANAF Thermochemical Tables, 3rd ed., American Chemical Society and the American Institute of Physics, 1986 (supplements to JANAF appear in J. Phys. Chem. Ref. Data) Thermodynamic Research Center, TRC Thermodynamic Tables, Texas A M University, College Station, Texas I. Barin and O. Knacke, Thermochemical Properties of Inorganic Substances, Springer-Verlag, Berlin, 1973 J. B. Pedley, R. D. Naylor, and S. P. Kirby, Thermochemical Data of Organic Compounds, 2nd ed.. Chapman and Hall, London, 1986 V. Majer and V. Svoboda, Enthalpies of Vaporization of Organic Compounds, International Union of Pure and Applied Chemistry, Chemical Data Series No. 32, Blackwell, Oxford, 1985. 

The values given in the following table for the heats and free energies of formation of inorganic compounds are derived from a) Bichowsky and Rossini, Thermochemistry of the Chemical Substances, Reinhold, New York, 1936 (h) Latimer, Oxidation States of the Elements and Their Potentials in Aqueous Solution, Prentice-Hall, New York, 1938 (c) the tables of the American Petroleum Institute Research Project 44 at the National Bureau of Standards and (d) the tables of Selected Values of Chemical Thermodynamic Properties of the National Bureau of Standards. The reader is referred to the preceding books and tables for additional details as to methods of calculation, standard states, and so on. 

The thermodynamic properties of magnesium make it a natural choice for use as an anode material in rechargeable batteries, as it may provide a considerably higher energy density than the commonly used lead-acid and nickel-cadmium systems, while in contrast to Pb and Cd, magnesium is inexpensive, environmentally friendly, and safe to handle. However, the development of Mg-ion batteries has so far been limited by the kinetics of Mg " " diffusion and the lack of suitable electrolytes. Actually, in spite of an expected general similarity between the processes of Li and Mg ion insertion into inorganic host materials, most of the compounds that exhibit fast and reversible Li ion insertion perform very poorly in Mg " ions. Hence, there... 

Most energetic contributions are, as we have discussed, difficult to predict and large experimental efforts have for that reason been devoted to derive systematic trends in the energetics of classes of materials. In this chapter we will try to convey an overview of periodic trends in the thermodynamic properties of inorganic compounds and we will also present selected examples illustrating some of the more usual rationalization schemes. Finally, trends in enthalpy of mixing are treated. Also here we aim to look at trends and rationalization schemes. The chapter is by no means exhaustive - only selected classes of compounds and selected rationalization schemes are discussed. 

Special mention should be made of recently published volumes of the Landolt-Bomstein Tables, references (35) and (51). These contain a large amount of data on aqueous solutions presented in a compact form. Reference (58) cites a new handbook on the thermodynamic properties of inorganic compounds. It gives tables of enthalpy, Gibbs energy, entropy, and heat... 

Duby, P., "The Thermodynamic Properties of Aqueous Inorganic Copper Compounds" Monograph IV, International Copper Research Association Inc., 1977. 

THERMODYNAMIC PROPERTIES FOR EXPLOSION CALCULATIONS - INORGANIC COMPOUNDS... 

Thermodynamic properties for explosion calculations are presented for inorganic chemical compounds. The thermodynamic properties include enthalpy of formation, Gibbs free energy of formation, internal energy of formation and Helmholtz free energy of formation. The inorganic chemicals include Ag - Zr compounds. 

App. B Thermodynamic Properties for Explosion Calculations -Inorganic Compounds 201... 

Landolt-Bornstein, Volume 19, Thermodynamic Properties of Inorganic Materials, Subvolume Al, Pure Substances. Part 1 Elements and Compounds from AgBr to Bajfl, P- Franke and D. Neuschtitz Guest eds., 1999, http //www.springerlink.com/link.asp id=KH6W2TXlRQ77. 

A. D. Mah and L.B. Pankratz, Contributions to the Data on Theoretical Metallurgy, XVI. Thermodynamic properties of Nickel and Its Inorganic Compounds, Bulletin 668, Bureau of Mines, U.S. Department of the Interior, Washington, D.C. 1976. 

Kelley, K. K., Contributions to the data on theoretical metallurgy VII. The thermodynamic properties of sulfur and its inorganic compounds. U.S. Bur. Mines Bull., 406, 1937. 

TRC Thermodynamic Tables Non-Hydrocarbons, NIST Standard Reference Data Program, Gaithersburg, MD. Thirteen volumes of critically evaluated data on physical and thermodynamic properties of selected nonmetallic inorganic compounds and organic componnds other than hydrocarbons and sulfur compounds. 

This journal publishes high-quality experimental data on the physical, thermodynamic, and transport properties of organic and inorganic compounds and their mixtures in the gaseous, liquid, and solid states, including systems... 

Metallurgical, materials, ceramic and chemical engineers worldwide will welcome this new compilation of thermochemical data by Professor Barin. Here they will find the most comprehensive tables yet available for the thermodynamic properties of pure substances as a function of temperature at 100° intervals. Almost twenty-four hundred substances are included - the elements, and compounds of two, three, and four elements. The vast majority of substances are inorganic, but Dr. Barin has included a generous selection of the more common hydrocarbons, carbohydrates, and a few chlorinated hydrocarbons. The format of the tables conforms to that of the JANAF tables, and SI units are employed. 

Inorganic and organic compounds which are frequently used as SCFs are listed, together with leading references for their volumetric behavior, in Tables 1.1-1 and 1.1-2. The listed SCFs include those that are most commonly employed for syntheses and chemical reactions and they are compared in terms of critical parameters, physical properties and approximate cost. For critical parameters and volumetric data of other SCFs, the reader is referred to several reviews [22-26] and the series of contributions by the lUPAC Commission 1.2 on Thermodynamics, Subcommittee on Thermodynamic Data [27-33]. Even more detailed volumetric data for SCFs can be found in two excellent series of monographs the lUPAC Thermodynamic Tables Project [11,34-43] and the Thermodynamic Properties series by the National Standard Reference Data Service of the USSR [44-50]. 

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