The tools

An alternative type of downhole mud motor is the mud turbine, (multistage axial flow turbine) which directly drives the bit. The tool consists of an upper section containing the turbine blades and lower section with bearings. As mud is pumped through the upper section the blades are turned. Turbines are designed to rotate at higher speed than the displacement motor. The higher rotation speed requires diamond or composite bits. 

The sidewall sampling tool (Sl/VS) can be used to obtain small plugs (2 cm diameter, 5 cm length, often less) directly from the borehole wall. The tool is run on wireline after the hole has been drilled. Some 20 to 30 individual bullets are fired from each gun (Fig. 5.35) at different depths. The hollow bullet will penetrate the formation and a rock sample will be trapped inside the steel cylinder. By pulling the tool upwards, wires connected to the gun pull the bullet and sample from the borehole wall. 

In a more recent development a new wireline tool has been developed that actually drills a plug out of the borehole wall. With sidewall coring (Fig. 5.36) some the main disadvantages of the SWS tool are mitigated, in particular the crushing of the sample. Up to 20 samples can be individually cut and are stored in a container inside the tool. 

One method of sampling reservoir fluids and taking formation pressures under reservoir conditions in open hole is by using a wireline formation tester. A number of wireline logging companies provide such a tool under the names such as RFT (repeat formation tester) and FMT (formation multi tester), so called because they can take a series of pressure samples in the same logging run. A newer version of the tool is called a modular dynamic tester or MDT (Schlumberger tool), shown in Figure 3.8. 

In some cases when drilling fluids invade a very low permeability zone, pressure equalisation in the formation can take a considerable time. The pressure recorded by the tool will then be close to the pressure of the mud and much higher than the true formation pressure. This is known as supercharging. Supercharging pressures indicate tight formation, but are not useful in establishing the true fluid pressure gradient. 

Because the neutron tool responds to hydrogen it can be used to differentiate between gas and liquids (oil or water) in the formation. A specific volume of gas will contain a lot fewer hydrogen atoms than the same volume of oil or water (at the same pressure), and therefore in a gas bearing reservoir the neutron porosity (which assumes the tool is... 

The most oommon method for measuring formation resistivity and henoe determining hydrocarbon saturation is by logging with a resistivity tool such as the Laterolog. The tool is designed to force electrical current through the formation adjacent to the borehole... 

Petroleum economics provides the tools with which to quantify and assess the financial risks involved in field exploration, appraisal and development, and allows a consistent approach with which alternative investments can be compared. The techniques are applied to advise management on the attractiveness of such investment opportunities, to assist in selecting the best options, and to determine how to maximise the value of existing assets. 

A programme of monitoring the reservoir is carried out, in which me asurements are made and data are gathered. Figure 14.2 indicates some of the tools used to gather data, the information which they yield, and the way In which the information is fed back to update the models and then used to refine the ongoing reservoir development strategy. 

The above example reveals that layer C is not contributing to flow at all (zero increase in total production as the tool passes this layer), and that a denser fluid (water) is being produced from layer B, which is also a major contributor to the total flowrate in the well. 

Hydrocarbon-water contact movement in the reservoir may be determined from the open hole logs of new wells drilled after the beginning of production, or from a thermal decay time (TDT) log run in an existing cased production well. The TDT is able to differentiate between hydrocarbons and saline water by measuring the thermal decay time of neutrons pulsed into the formation from a source in the tool. By running the TDT tool in the same well at intervals of say one or two years (time lapse TDTs), the rate of movement of the hydrocarbon-water contact can be tracked. This is useful in determining the displacement in the reservoir, as well as the encroachment of an aquifer. 

Computer system of defect assessments as applied to primary circuit piping is developed as the tool of expert ISI strength supporting. Results of defect assessments are governed by adequate data on stress distributions and defect geometry. 

Classification Societies exist to promote the safe construction of ships and to protect that condition throughout the life of the vessel. One of the tools available to shipbuilders, shipowners and surveyors that can be used to achieve these aims is Non-Destructive Examination (NDE). The intent of this presentation is to describe the application of NDE to hull structure during construction and also during periodic surveys as seen from the viewpoint of the Classification Surveyor. 

The Driving Module houses power supply, circuits for determination of travel distance (odometer wheels) and circumferential orientation, and a computer and a storage facility for all data recorded. The Driving Module has cups extending to the pipe wall, thus providing the movement of the tool after its launching into the continuous oil flow. 

Clearly, the physical chemistry of surfaces covers a wide range of topics. Most of these subjects are sampled in this book, with emphasis on fundamentals and important theoretical models. With each topic there is annotation of current literature with citations often chosen because they contain bibliographies that will provide detailed source material. We aim to whet the reader s appetite for surface physical chemistry and to provide the tools for basic understanding of these challenging and interesting problems. 

Surfaces are investigated with surface-sensitive teclmiques in order to elucidate fiindamental infonnation. The approach most often used is to employ a variety of techniques to investigate a particular materials system. As each teclmique provides only a limited amount of infonnation, results from many teclmiques must be correlated in order to obtain a comprehensive understanding of surface properties. In section A 1.7.5. methods for the experimental analysis of surfaces in vacuum are outlined. Note that the interactions of various kinds of particles with surfaces are a critical component of these teclmiques. In addition, one of the more mteresting aspects of surface science is to use the tools available, such as electron, ion or laser beams, or even the tip of a scaiming probe instrument, to modify a surface at the atomic scale. The physics of the interactions of particles with surfaces and the kinds of modifications that can be made to surfaces are an integral part of this section. 

The study of clean surfaces encompassed a lot of interest in the early days of surface science. From this, we now have a reasonable idea of the geometric and electronic structure of many clean surfaces, and the tools are readily available for obtaining this infonnation from other systems, as needed. 

This interface is critically important in many applications, as well as in biological systems. For example, the movement of pollutants tln-ough the enviromnent involves a series of chemical reactions of aqueous groundwater solutions with mineral surfaces. Although the liquid-solid interface has been studied for many years, it is only recently that the tools have been developed for interrogating this interface at the atomic level. This interface is particularly complex, as the interactions of ions dissolved in solution with a surface are affected not only by the surface structure, but also by the solution chemistry and by the effects of the electrical double layer [31]. It has been found, for example, that some surface reconstructions present in UHV persist under solution, while others do not. 

By its nature, the application of direct dynamics requires a detailed knowledge of both molecular dynamics and quantum chemistry. This chapter is aimed more at the quantum chemist who would like to use dynamical methods to expand the tools at theh disposal for the study of photochemistry, rather than at the dynamicist who would like to learn some quantum chemishy. It hies therefore to introduce the concepts and problems of dynamics simulations, shessing that one cannot strictly think of a molecule moving along a trajectory even though this is what is being calculated. 

Counterpropagation neural networks (CFG NN) were then used to establish relationships between protons and their H NMR chemical shifts. A detailed description of this method is given in the Tools Section 10,2.4.2,... 

Once entered into a spreadsheet, data can be manipulated column at a time. For example, let us take the top cells in Table 1-3 as cells A3 and B3 (columns A and B, line 3 in Table 1-3) containing 5 and 0.305 to avoid dividing 0 by 0. Using the easycalc option of the tools menu in Excel, divide the contents of B3 by A3 and place the results in cell C3. Now select C3 and the remaining 12 unfilled cells in the column, C3 to Cl 5, and fill down using the mouse. The results of the calculation of Cp/T appear for all remaining cells in the C column. 

This Introductory Section was intended to provide the reader with an overview of the structure of quantum mechanics and to illustrate its application to several exactly solvable model problems. The model problems analyzed play especially important roles in chemistry because they form the basis upon which more sophisticated descriptions of the electronic structure and rotational-vibrational motions of molecules are built. The variational method and perturbation theory constitute the tools needed to make use of solutions of... 

In the case of a pair of non-equivalent p orbitals (e.g., in a 2pi3pi configuration), even more states would arise. They can also be found using the tools provided above. 

The tools of time-dependent perturbation theory can be applied to transitions among electronic, vibrational, and rotational states of molecules. 

D i,i,o - D i,-i,0, and the tools of angular momentum coupling allows these integrals to be expressed, as above, in terms of products of the following 3-j symbols ... 

SpartanView software with which you can browse through an archive of already prepared models on the Learning By Modeling CD These models include many of the same substances that appear m this text SpartanView is the tool you will use to view... 

Three types of geometry measurements can be made using SpartanBuild distances between pairs of atoms angles involving any three atoms and dihedral angles mvolv mg any four atoms These are accessible from the Geometry menu and from the tool bar Try these operations now... 

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