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The emission method

The emission methods of EEP detection are based on the ability of some metastable particles (N2(A ZJ, metastable atoms of rare gases) to knock electrons out of the surface of metals [59]. The present-day technique of measuring small currents allows one to record any small fluxes... [Pg.295]

One of the advantages of the emission method is that it makes possible studies of molecules adsorbed on massive pieces of metal. This advantage is shared by the reflection method by which spectra of monolayers adsorbed on mirrorlike surfaces are obtained. Work on the development of reflection techniques has been carried out by Pickering and Eckstrom (66) and by Francis (67). [Pg.53]

This is a classic method for the analysis of rare earths. L-spectra of the elements in the region 1500-2500 A show that for each element it is possible to select 2-5 lines for analysis. These analytical lines are given in Table 1.38. By this method rare earths in a complex mixture can be analyzed. The emission method has a sensitivity of 0.1 to 0.01 %. The time of analysis is 1.5-2.0 h. The method has been used in the analysis of minerals, alloys, etc. [Pg.65]

The Emission Method. If the effective temperature in local thermodynamic equilibrium is known, the relative strength of spectral fines from a fight... [Pg.323]

Calcium may be determined by atomic absorption spectrophotometry. This technique has been used for the estimation of calcium in biological fluids and agricultural materials. It is a speedy method, superior to the more tedious chemical determination by oxalate precipitation and more specific than the EDTA titration method. The accuracy is of the order of 2 per cent and sensitivity limits have been reported at 0 08 to 1 p.p.m. of calcium in solution. The interference problems are very similar to those experienced with the emission method although not quite so formidable. [Pg.150]

This view is supported by the inconsistency which has been discovered between the abundances of elements determined from photospheric absorption lines and those obtained from the intensity of coronal emission lines (Pottasch (1963, 1964)). As shown in Table 10.3,- discrepancies of at least a factor of ten exist for all of the elements in the iron group. In the case of iron this difficulty has now been resolved. Recent measurements of f-values of iron by the beam-foil technique have shown conclusively that previous f-values for iron obtained by the emission method contained serious systematic errors and there has been a consequent revision of the abundance of iron in the Sun toivards the coronal value. [Pg.310]

X-ray fluorescence A method of analysis used to identify and measure heavy elements in the presence of each other in any matrix. The sample is irradiated with a beam of primary X-rays of greater energy than the characteristic X-radiation of the elements in the sample. This results in the excitation of the heavy elements present and the emission of characteristic X-ray energies, which can be separated into individual wavelengths and measured. The technique is not suitable for use with elements of lower atomic number than calcium. [Pg.429]

Parallel to tliese tests, CETIM has informed the administration which establish regulations for pressure vessels of the advantage of the acoustic emission method for the inspection in-service. [Pg.56]

The present work was done with the aim to evaluate the efficiency of the acoustic emission method as a diagnostic tool for analysing a carbon plastic composite and its adhesive joints. The samples of the carbon plastic type UKN-5000 were used in the test. Non-defected samples and samples with artificial defects were tested. [Pg.83]

Thus, carrying out tests of the samples shows that the acoustic emission method is quite effective at the quality estimation of carbon plastic and its adhesive joints. Depending on the chosen diagnostic diagram of the construction material loading, the criteria parameters are K, S or AS (a C). [Pg.85]

Description of Method. Quinine is an alkaloid used in treating malaria (it also is found in tonic water). It is a strongly fluorescent compound in dilute solutions of H2SO4 (f = 0.55). The excitation spectrum of quinine shows two absorption bands at 250 nm and 350 nm, and the emission spectrum shows a single emission band at 450 nm. Quinine is rapidly excreted from the body in urine and is easily determined by fluorescence following its extraction from the urine sample. [Pg.431]

Atomic emission is used for the analysis of the same types of samples that may be analyzed by atomic absorption. The development of a quantitative atomic emission method requires several considerations, including choosing a source for atomization and excitation, selecting a wavelength and slit width, preparing the sample for analysis, minimizing spectral and chemical interferences, and selecting a method of standardization. [Pg.437]

Standardizing the Method Equation 10.34 shows that emission intensity is proportional to the population of the excited state, N, from which the emission line originates. If the emission source is in thermal equilibrium, then the excited state population is proportional to the total population of analyte atoms, N, through the Boltzmann distribution (equation 10.35). [Pg.438]

To examine a sample by inductively coupled plasma mass spectrometry (ICP/MS) or inductively coupled plasma atomic-emission spectroscopy (ICP/AES) the sample must be transported into the flame of a plasma torch. Once in the flame, sample molecules are literally ripped apart to form ions of their constituent elements. These fragmentation and ionization processes are described in Chapters 6 and 14. To introduce samples into the center of the (plasma) flame, they must be transported there as gases, as finely dispersed droplets of a solution, or as fine particulate matter. The various methods of sample introduction are described here in three parts — A, B, and C Chapters 15, 16, and 17 — to cover gases, solutions (liquids), and solids. Some types of sample inlets are multipurpose and can be used with gases and liquids or with liquids and solids, but others have been designed specifically for only one kind of analysis. However, the principles governing the operation of inlet systems fall into a small number of categories. This chapter discusses specifically substances that are normally liquids at ambient temperatures. This sort of inlet is the commonest in analytical work. [Pg.103]

For these reasons, CEC and DOE concluded that the only cost-effective method of getting alcohol fueled vehicles would be from original equipment manufacturers (OEM). Vehicles produced on the assembly line would have lower unit costs. The OEM could design and ensure the success and durabihty of the emission control equipment. [Pg.425]


See other pages where The emission method is mentioned: [Pg.236]    [Pg.365]    [Pg.323]    [Pg.51]    [Pg.157]    [Pg.21]    [Pg.272]    [Pg.306]    [Pg.236]    [Pg.365]    [Pg.323]    [Pg.51]    [Pg.157]    [Pg.21]    [Pg.272]    [Pg.306]    [Pg.37]    [Pg.263]    [Pg.924]    [Pg.1279]    [Pg.1426]    [Pg.1604]    [Pg.1891]    [Pg.1892]    [Pg.1893]    [Pg.2060]    [Pg.2073]    [Pg.2205]    [Pg.2489]    [Pg.305]    [Pg.376]    [Pg.447]    [Pg.648]    [Pg.97]    [Pg.1]    [Pg.377]    [Pg.244]    [Pg.384]    [Pg.147]    [Pg.280]    [Pg.198]    [Pg.119]   


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