Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Systematic information

So little systematic information is available about transport in liquids, or strongly non-ideal gaseous mixtures, that attention will be limited throughout to the behavior of ideal gas mixtures. It is not intende thereby, to minimize the importance of non-ideal behavior in practice. [Pg.1]

Readers who want more systematic information on ordered molecular films are referred to the book by Ulman [31]. [Pg.89]

A question that often arises in multivariate data analysis is how many meaningful eigenvectors should be retained, especially when the objective is to reduce the dimensionality of the data. It is assumed that, initially, eigenvectors contribute only structural information, which is also referred to as systematic information. [Pg.140]

It was concluded from the data that flavonoid patterns are systematically informative at the infrageneric level and may facilitate the taxonomic classification of these types of plant species [155],... [Pg.170]

In Chapter 2 Reinhardt suggests establishing nonproht PharmacoEco-nomics Research Institutes (PERIs), as opposed to government-run organizations, to produce systematic information on the relative cost effectiveness of rival pharmaceutical products. Individual countries may beneht from information, whether or not they contribute to the information dissemination process. For this reason, the feasibility of multicountry efforts is worth exploring. [Pg.270]

This subject will be restricted almost exclusively to consideration of the fragmentation behavior of the parent heterocycle, thiophene (1). This approach is dictated chiefly by the fact that only for thiophene is a large enough information pool available for a reasonable analysis of the fragmentation pattern. For benzothiophenes there is very little systematic information available (8lAHC(29)l7l). [Pg.739]

Until quite recently there has been practically no systematic information on the gas phase reactions of atoms and radicals with a representative series of olefins. These reactions possess special features and their comparative study may be of considerable value. [Pg.115]

From the point of view of the present understanding of the intruder states, the even Pd nuclei are of special interest since they are expected to exhibit proton intruders of the type 2p-6h. Systematic information exists already for the 2p-2h and the 2p-4h intruders in the Sn and Cd isotopes [BR078, BAC81, APR84], so that the Pd isotopes represent the next step towards more complex states. Such a step is important since it may show whether, when going away from closed shells, the intruder picture will get obscured by the increasing number of the particle degrees of freedom. [Pg.226]

For acenaphthylene using PLS1, the cross-validated error is presented in Fig. 18. An immediate difference between autoprediction and cross-validation is evident. In the former case the data will always be better modelled as more components are employed in the calculation, so the error will always reduce (with occasional rare exceptions in the case of 1 Hcai). Flowever, cross-validated errors normally reach a minimum as the correct number of components are found and then increase afterwards. This is because later components really represent noise and not systematic information in the data. [Pg.21]

This subject really belongs to Chapter VII there is not yet much systematic information as to the relation between the constitution of the... [Pg.141]

When a chemical reaction takes place inside a porous catalyst, all reactants and products must find their way to and from the internal catalytically active surfaces. This transport can strongly influence the apparent reaction rates and selectivity, hence various mass transport models have been developed. Some of the best known and used models and the basic principles behind these models are described in this chapter. Since only little systematic information is available about transport in liquids, the discussion is mainly concerned gaseous mixtures. [Pg.41]

Studies on the gas-phase reactions of dichlorosilylene with conjugated dienes provided more systematic information about the addition reactions of dichlorosilylene (1,10,15,16, 20, 30, 91) ... [Pg.13]

The X data matrix which contains all information describing the probe-target interactions can be analyzed by PCA [29, 30]. PCA is a multivariate projection method which allows one to extract the systematic information which is contained in the data matrix and to present it in a simplified form. The original number of variables is reduced to a few factors called principal components (PCs). The result of such an analysis can then be visualized by means of two informative plots which allow a straightforward interpretation of the problem. In this way, PCA provides an understanding of similarities and dissimilarities between the different protein binding sites with respect to their interaction with potential ligands. [Pg.51]

This somewhat incomplete picture can be coordinated with known facts of homogeneous catalysis. We may say that the monoolefin complexes of Ni are too unstable to be reactive, while the simple analogues of Pt are too stable optimum reactivity therefore resides in complexes of Pd and Rh where these opposing effects balance properly. We must defer for the present a discussion of the effects which other coordinated groups e.g., PR3, GO, SnGl.r) have on the reactivity of coordinated olefins since much more systematic information is needed for this to be feasible. The limited catalytic activity of olefin complexes e.g., Gu Ag ) is presumably caused by the absence from these complexes of any vacant orbitals at which attack by another reactant can occur. [Pg.30]

There is very little systematic information on the etch rates of anodic oxides in the literature. Some of the etch rate data are listed in Table 4.1. In relative terms, the... [Pg.148]

Passive films formed on a silicon surface in aqueous solutions are in general oxide films. There is rather limited systematic information on the structure and properties of thin silicon anodic oxide films, particularly those formed in solutions of high silicon solubilities. On the other hand, the thicker oxide films formed at large potentials have been better characterized (see Chapter 3) and the information associated can be used for understanding the thin oxide films formed at relatively low potentials. [Pg.201]

There is a paucity of systematic information about the variation of arsenic concentration with time or with depth for a given well. Five separate shallow piezometers (10 m, 20 m, 30 m, 40 m and 50 m depth) and one deep piezometer (150 m) were therefore installed in each of the three Special Study Areas. Water levels were monitored and water samples collected from these piezometers at approximately two-weekly intervals for ten months. The variation of water levels in the Lakshmipur piezometers is shown in Fig. 5. [Pg.226]

The first level of nomenclature, beyond the assignment of totally trivial names, gives some systematic information about a substance but does not allow the inference of composition. Most of the common names of the oxoacids (e.g. sulfuric acid, perchloric acid) and of their salts are of this type. Such names may be termed semi-systematic and as long as they are used for common materials and understood by chemists, they are acceptable. However, it should be recognized that they may hinder compositional understanding by those with limited chemical training. [Pg.4]

The variation of the principal properties over the set of compounds is measured by the corresponding scores, fy. The important result of this is that we can now describe the systematic variation using fewer variables (the scores) than the K original descriptors. This is a considerable simplification without loss of systematic information. [Pg.348]

To provide comprehensive knowledge-based information on the principles and applications of a variety of LM separation processes. The book contains updated, useful, and systematized information. It contains a... [Pg.448]

The number of states is usually unknown, but some physical intuition about the system can provide a basis for defining M. Naturally, a small number of states usually results in poor estimation of the data, while a large number of states improves the estimation but leads to extended training times. The quality of the HMM can be gauged by considering the residuals of the model or the correlation coefficients of observed and estimated values of the variables. The residuals are expected to have a Normal distribution (A(0, (T )) if there is no systematic information left in them. Hence, the normality of the residuals can provide useful information about model performance in representing the data. [Pg.143]

Despite the absence of systematic information in these areas, there have been synthetic, structural, and reactivity studies which provide a useful background to the COg reduction problem, as has been described in... [Pg.58]

There is no systematic information so far on the effects of the shift towards activation in Germany on unemployment duration or on stability and quality of subsequent employment. Recent administrative data, however, shows that about 50% of all persons leaving UB II return within 1 year. Evidence-based impacts on wage dispersion and inequality before and after taxes and benefits will only become available later. However, a simulation study (Becker and Hauser 2006, see Fig. 8)... [Pg.56]


See other pages where Systematic information is mentioned: [Pg.5]    [Pg.798]    [Pg.78]    [Pg.1212]    [Pg.516]    [Pg.400]    [Pg.468]    [Pg.127]    [Pg.133]    [Pg.272]    [Pg.70]    [Pg.174]    [Pg.176]    [Pg.111]    [Pg.316]    [Pg.204]    [Pg.333]    [Pg.677]    [Pg.534]    [Pg.535]    [Pg.416]    [Pg.4]    [Pg.116]    [Pg.72]    [Pg.185]    [Pg.217]   
See also in sourсe #XX -- [ Pg.140 ]




SEARCH



© 2024 chempedia.info