Surface polystyrene

Figure I. Fracture surface polystyrene reinforced with V4-incn polyester fiber...

To differentiate potystyrene from potymethyt methacrylate (PMMA), tisten to their acoustic emission when dropping a test specimen onto a non-metai-lic flat surface polystyrene sounds like sheet metal, PMMA sounds like hard wood. 

The polar character of asphaltenes impacts their adsorption at interfaces (Abudu Goual, 2009 Saraji et al., 2010). Figure 6 depicts the adsorption amounts from 5 wt % crude oil in toluene and heptane on different substrates (Abudu Goual, 2009). The substrates consist of hydrophilic surfaces (gold, silica, and stainless steel) and hydrophobic surfaces (polystyrene). The amount adsorbed from toluene on hydrophilic surfaces varies from 350 to 450 ng/cm2, with the highest being on silica. 

The refractograp of figure 4 shows highly oriented micro cracks of a polystyrene sample. The orientation of the cracks is perpendicular to the mechanical strain direction. The X-ray refracted intensitiy can be interpreted as crack density, i.e. the inner surfaces within a unit volume. Changing the tilt angle (of polystyrene and polystyrene blend samples) with respect to the primary beam leads to significantly different distributions of crack orientation (Fig. 5). 

Plot the scaling behavior for the surface tension of polystyrene solutions using Eq. III-64, for N = 1,000 and T from zero to Tc- Now plot the behavior for T = 0.87 for N = 100-1000. Comment on the influence of polymers on surface tension. 

These equations imply that A132 will exceed A12 if A33 is larger than A13 + A23. This effect, termed lyophobic bonding, occurs if the solvent-surface interaction is weaker than that between the solvent molecules. More interestingly, the dispersion interaction will be repulsive (A 132 < 0) when An and/or A23 are sufficiently large. Israelachvili [1] tabulates a number of Am values Awhw Ahwh 0-4X 10 erg, Apwp 1 x 10" erg, and Aqwq = O.SX -IO erg, where W, H, P, and Q denote water, hydrocarbon, polystyrene and quartz respectively. 

Fig. XI-7. Volume fraction profile of 280,000-molecular-weight poly(ethylene oxide) adsorbed onto deuterated polystyrene latex at a surface density of 1.21 mg/m and suspended in D2O, from Ref. 70.

Klein and co-workers have documented the remarkable lubricating attributes of polymer brushes tethered to surfaces by one end only [56], Studying zwitterionic polystyrene-X attached to mica by the zwitterion end group in a surface forces apparatus, they found /i < 0.001 for loads of 100 and speeds of 15-450 nm/sec. They attributed the low friction to strong repulsions existing between such polymer layers. At higher compression, stick-slip motion was observed. In a related study, they compared the friction between polymer brushes in toluene (ji < 0.005) to that of mica in pure toluene /t = 0.7 [57]. 

Experimental investigations of the model system of dye molecules adsorbed onto surfaces of polystyrene spheres have finuly established the sensitivity and surface specificity of the SHG method even for particles of micrometre size [117]. The surface sensitivity of die SHG process has been exploited for probing molecular transport across the bilayer in liposomes [118], for measurement of electrostatic potentials at the surface of small particles [119] and for imaging... 

Stouffer J M and McCarthy T J 1988 Polymer monolayers prepared by the spontaneous adsorption of sulphur-functionalized polystyrene on gold surfaces Macromolecules 2 1204-8... 

An important step in tire progress of colloid science was tire development of monodisperse polymer latex suspensions in tire 1950s. These are prepared by emulsion polymerization, which is nowadays also carried out industrially on a large scale for many different polymers. Perhaps tire best-studied colloidal model system is tliat of polystyrene (PS) latex [9]. This is prepared with a hydrophilic group (such as sulphate) at tire end of each molecule. In water tliis produces well defined spheres witli a number of end groups at tire surface, which (partly) ionize to... 

A twin-screw extmder is used to reduce residual monomers from ca 50 to 0.6%, at 170°C and 3 kPa with a residence time of 2 min (94). In another design, a heated casing encloses the vented devolatilization chamber, which encloses a rotating shaft with specially designed blades (99,100). These continuously regenerate a large surface area to faciUtate the efficient vaporization of monomers. The devolatilization equipment used for the production of polystyrene and ABS is generally suitable for SAN production. 

Physical or chemical vapor-phase mechanisms may be reasonably hypothesized in cases where a phosphoms flame retardant is found to be effective in a noncharring polymer, and especially where the flame retardant or phosphoms-containing breakdown products are capable of being vaporized at the temperature of the pyrolyzing surface. In the engineering of thermoplastic Noryl (General Electric), which consists of a blend of a charrable poly(phenylene oxide) and a poorly charrable polystyrene, experimental evidence indicates that effective flame retardants such as triphenyl phosphate act in the vapor phase to suppress the flammabiUty of the polystyrene pyrolysis products (36). 

In 1954 the surface fluorination of polyethylene sheets by using a soHd CO2 cooled heat sink was patented (44). Later patents covered the fluorination of PVC (45) and polyethylene bottles (46). Studies of surface fluorination of polymer films have been reported (47). The fluorination of polyethylene powder was described (48) as a fiery intense reaction, which was finally controlled by dilution with an inert gas at reduced pressures. Direct fluorination of polymers was achieved in 1970 (8,49). More recently, surface fluorinations of poly(vinyl fluoride), polycarbonates, polystyrene, and poly(methyl methacrylate), and the surface fluorination of containers have been described (50,51). Partially fluorinated poly(ethylene terephthalate) and polyamides such as nylon have excellent soil release properties as well as high wettabiUty (52,53). The most advanced direct fluorination technology in the area of single-compound synthesis and synthesis of high performance fluids is currently practiced by 3M Co. of St. Paul, Minnesota, and by Exfluor Research Corp. of Austin, Texas. 

CeUular urea—formaldehyde and phenoHc resin foams have been used to some extent in interior sound-absorbing panels and, in Europe, expanded polystyrene has been used in the design of sound-absorbing doors (233). In general, cost, dammabUity, and cleaning difficulties have prevented significant penetration of the acoustical tile market. The low percent of redection of sound waves from plastic foam surfaces has led to their use in anechoic chambers (216). 

If an adsorbed chemical group (anchor) is more strongly bound to the surface than a solvent molecule would be at that site, an equiHbrium expression may be written for the displacement of solvent by adsorbate. Adsorption is particularly strong if the chemical nature of the adsorbed group is similar to that of the particle surface for example, in aqueous systems perfluoroalkane groups adsorb weU on polytetrafluoroethene particles and aromatic polyethene oxides adsorb weU on polystyrene. 

The spreading rate of a polymer droplet on a surface has been measured (363,364). The diffusion constant was at least an order of magnitude smaller than that of the bulk. The monomer—surface friction coefficient for polystyrene has been measured on a number of surfaces and excellent... 

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