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Structural manipulation

Atomic and bond hash codes are helpful in structure manipulation programs, e.g., in reaction prediction or in synthesis design [99]. [Pg.75]

Ashwell GJ, Berry M (2005) Hybrid SAM/LB device structures manipulation of the molecular orientation for nanoscale electronic applications. J Mater Chem 15 108-110... [Pg.84]

The resulting heterocycles can be structurally manipulated, e.g., reduced or desilylated either during complexation or after demetallation. Another possibility consists in using the primary products, obtained by the cobalt-mediated cycloaddition, as synthetic intermediates for further catalytic transformations. Indole derivatives have been cocyclized at cpCo to give 4a,9a-dihydro-9 f-carbazoles or, after oxidation, precursors for strychnine (63T247 86JA2091 87MI7) [Eq.(36)]. [Pg.200]

An interesting feature of this enzymatic polymerization in [BMIM]PF6 is that the polymeric material exhibited remarkably narrow polydispersity values, Mw/Mn = 1.04-1.03, a value that was maintained in the seven-day test. The authors related this value to the insolubility of the polymer formed in the ionic liquid after it exceeds a certain molecular weight limit. This observation opens the possibility of tailoring ionic liquids with varying solvating abilities for structural manipulation of desired polymeric material. [Pg.200]

Alkaloid chemistry is a small part of chemistry, whose history began in 1805, when the first alkaloid was isolated. Since this time, there have been many famous achievements in research and product development. A host of excellent scientists have been working successfully in this field. Alkaloid chemistry has saved many millions of lives by producing the knowledge, on the bases of which alkaloid-based medicines have been developed against malaria and other diseases. Chemistry has not only investigated alkaloids, their structures and activity, but also developed methods for their modifications and structural manipulation. These methods are successfully used in both the pharmaceutical industry and biotechnology. [Pg.139]

Given a set of molecules, the REVIEW command is used to display the chemical structure and associated information of any member of the set. The review mode allows the user to both page through the current set of molecules, one after another, as well as to jump to a specific entry within the set. The chemical structure currently displayed is referenced by MAECIS as the "current" structure. The user can also designate a second member of the set as the "alternate" structure. This allows for comparison of structures which will be described in the section on chemical structure manipulation. [Pg.13]

Pyrethroids, e.g. cypermethrin (89) and fenvalerate (90), are being employed. This class of compound is the result of structural manipulation by medicinal chemists of the naturally occurring pyrethrins (91) to overcome the latters photoinstability and lack of persistence when in use as ectoparasiticides. There are no heterocyclic representatives of this important class of insecticide/acaricide in use though many heterocyclic examples have appeared in the patent literature. [Pg.218]

In addition to the above chemistry rules, it also declares other structure manipulation methods such as neutralize(), getFragmentCount(), and getCharge(). [Pg.170]

The structural manipulation at different positions of adenosine provided a wide number of ligands at the A3 AR exerting different levels of potency, selectivity, and intrinsic efficacy. The exact combination of modifications showed to affect the balance between full agonism, partial agonism and antagonism (Joshi and Jacobson 2005). [Pg.136]

This review article describes progress made in scanning force microscopy of polymers during the last 5 years including fundamental principles of SFM and recent developments in instrumentation relevant to polymer systems. It focuses on the analytical capabilities of SFM techniques in areas of research where they give the most unique and valuable information not accessible by other methods. These include (i) quantitative characterisation of material properties and structure manipulation on the nanometer scale, and (ii) visualisation and probing of single macromolecules. [Pg.61]

All the optically active terpenes mentioned in this chapter are commercially available in bulk (>kg) quantities and are fairly inexpensive. Although many of them are isolated from natural sources, they can also be produced economically by synthetic methods. Actually, two thirds of these monoterpenes sold in the market today are manufactured by synthetic or semi-synthetic routes. These optically active molecules usually possess simple carbocyclic rings with one or two stereo-genic centers and have modest functionality for convenient structural manipulations. These unique features render them attractive as chiral pool materials for synthesis of optically active fine chemicals or pharmaceuticals. Industrial applications of these terpenes as chiral auxiliaries, chiral synthons, and chiral reagents have increased significantly in recent years. The expansion of the chiral pool into terpenes will continue with the increase in complexity and chirality of new drug candidates in the research and development pipeline of pharmaceutical companies. [Pg.72]

SCHEME 7. Structural manipulations for the conversion of bile acids and diosgenin.63... [Pg.241]

At the very bottom level of most structure handling algorithms two structures are compared atom by atom and bond by bond (ref. 1). However, the preprocessing steps, the I/O conditions, the constraints in the query or in the reference structures, and requirements for a match or failure differ considerably from application to application. The most frequent used structure manipulating procedures are substructure and superstructure searches. [Pg.75]

The chapters in this volume present detailed insights into the synthesis-structure-properties relationships of nanostructured materials. In particular, the catalytic and photocatalytic properties of nanoclusters and nanostructured materials with ultrahigh surface-to-volume ratio are demonstrated. The gas absorption characteristics and surface reactivity of nanoporous and nanocrystalline materials are shown for various separation and reaction processes. In addition, the structural manipulation, quantum confinement effects, transport properties, and modeling of nanocrystals and nanowires are described. The biological functionality and bioactivity of nanostructured ceramic implants are also discussed. [Pg.234]

Understanding of ER structure and function has been greatly extended by the recent cloning and structural manipulation of ER cDNAs from a number of species including human [15-17,21,22,31]. chicken [17,18], rat [32], Xenopus [33] and mouse [34],... [Pg.203]


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See also in sourсe #XX -- [ Pg.53 , Pg.72 ]




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