Strain properties tests

These tests, also called short-term stress and strain properties tests, are perfectly described in a special book devoted to the physical testing of rubbers [1], so that only a brief description will be given in this subsection. Such tests have been of enormous value, particularly in quality control tests, and have been studied and standardized... 

Fig. 2. Cellulose acetate stress—strain properties at standard and wet conditions, tested at 60% min extension rate, 3.9 cm gauge length. Sample conditions standard, 21°C, 65% rh wet, 21°C, water wet. To convert N/tex to gf/den, multiply by 11.33.

This effect was estimated from the experimental comparison of the stress-strain properties in three sample series which were brought to different phase contents by means of heat treatment. All samples were hydrogen-alloyed to a = 0.35 at T = 1053 K, then furnace cooled. Before straining, samples of the first series were maintained at the test temperature for 0.5 h. Series 2 samples were heated to the j9-phase, T = 1163 K, for 15 min, then cooled to the test temperature and treated like series 1 samples. The phase content in the third series was equilibrated by heating to 1163 K and slow cooling to 903 K before the test temperature was fixed. 

Fig. 10 shows that the flow stress of the hydrogen-alloyed compacts is essentially less than that of the outgassed ones at all test temperatuics. The flow stress relation between the hydrogen-alloyed and outgassed compacts depended on the strain. At equal strains at test temperatures, this ratio could achieve 2 or more. Thus, the effect of hydrogen on the properties of compacted powders is much similar to that observed on bulk titanium. 

Edwards e/a/. carried out controlled potential, slow strain-rate tests on Zimaloy (a cobalt-chromium-molybdenum implant alloy) in Ringer s solution at 37°C and showed that hydrogen absorption may degrade the mechanical properties of the alloy. Potentials were controlled so that the tensile sample was either cathodic or anodic with respect to the metal s free corrosion potential. Hydrogen was generated on the sample surface when the specimen was cathodic, and dissolution of the sample was encouraged when the sample was anodic. The results of these controlled potential tests showed no susceptibility of this alloy to SCC at anodic potentials. 

When materials are evaluated against each other, the flexural data of those that break in the test cannot be compared unless the conditions of the test and the specimen dimensions are identical. For those materials (most TPs) whose flexural properties are calculated at 5% strain, the test conditions and the specimen are standardized, and the data can be analyzed for relative preference. For design purposes, the flexural properties are used in the same way as the tensile properties. Thus, the allowable working stress, limits of elongation, etc. are treated in the same manner as are the tensile properties. 

Static and dynamic property The uses of these foams or porous solids are used in a variety of applications such as energy absorbers in addition to buoyant products. Properties of these materials such as a compressive constitutive law or equation of state is needed in the calculation of the dynamic response of the material to suddenly applied loads. Static testing to provide such data is appealing because of its simplicity, however, the importance of rate effects cannot be determined by this one method alone. Therefore, additional but numerically limited elevated strain-rate tests must be run for this purpose. 

Reliable data in the literature for the stress versus strain properties of composite propints are exceedingly difficult to find. Since the binder chemical properties and curing additions are susceptible in many cases to hydrolytic degradation, the exact formulations under test should be specified. Additionally, the binder to oxidizer adhesion properties are dependent upon particle size distribution used in the pro-pint. This should be specified and in almost all literature sources unearthed, it remained unknown. As some of these data show, the manner of conducting the test and control of such... 

In TPE, the hard domains can act both as filler and intermolecular tie points thus, the toughness results from the inhibition of catastrophic failure from slow crack growth. Hard domains are effective fillers above a volume fraction of 0.2 and a size <100 nm [200]. The fracture energy of TPE is characteristic of the materials and independent of the test methods as observed for rubbers. It is, however, not a single-valued property and depends on the rate of tearing and test temperature [201]. The stress-strain properties of most TPEs have been described by the empirical Mooney-Rivlin equation... 

At sufficiently low strain, most polymer materials exhibit a linear viscoelastic response and, once the appropriate strain amplitude has been determined through a preliminary strain sweep test, valid frequency sweep tests can be performed. Filled mbber compounds however hardly exhibit a linear viscoelastic response when submitted to harmonic strains and the current practice consists in testing such materials at the lowest permitted strain for satisfactory reproducibility an approach that obviously provides apparent material properties, at best. From a fundamental point of view, for instance in terms of material sciences, such measurements have a limited meaning because theoretical relationships that relate material structure to properties have so far been established only in the linear viscoelastic domain. Nevertheless, experience proves that apparent test results can be well reproducible and related to a number of other viscoelastic effects, including certain processing phenomena. 

There are various test methods, one being the De Mattia Flex Test method which is suitable for rubbers that have reasonably stable stress-strain properties, at least after a period of cycling, and do not show undue stress softening or set, or highly viscous behaviour. The results obtained for some thermoplastic rubber should be treated with caution if the elongation at break is below,... 

Standard geotechnical test reports address typical static properties of soil such as shear strength and bearing capacity but may not provide dynamic properties unless they are specifically requested. In these situations, it is necessary to use the static properties. Dynamic soil properties which are reported may be based on low strain amplitude tests which may or may not be applicable to the situation of interest. Soils reports will generally provide vertical and lateral stiffness values for the foundation type recommended. These can be used along with ultimate bearing capacities to perform a dynamic response calculation of the foundation for the applied blast load. 

In measurement of tensile stress-strain properties, a test piece is stretched to breaking point and the force and elongation are measured at different stages. Tensile strength, elongation at break or work to failure (the area under the stress-strain curve) provide... 

The determination of tensile stress-strain properties is conducted in accordance with ISO 527 [4] and the values that can be obtained are illustrated in Figure 7.1. For weathering tests where cabinet space is restricted some workers have used a tensile impact dumbbell from ISO 8256 [5] with a square central section which allows test pieces to be exposed edge on. The considerable disadvantage is that modulus cannot be measured as there is no parallel gauge length. 

Tear strength is only applicable to flexible materials and is very little used to monitor ageing simply because tensile strength will serve perfectly well. There are circumstances where compression stress-strain properties would be relevant but the relatively bulky test pieces will be subject to the limitation of oxygen diffusion in any accelerated tests and changes can probably be estimated from tensile measurements. Similarly, shear stress-strain is very rarely used for monitoring ageing. 

ISO 844 2001 Rigid cellular plastics - Determination of compression properties ISO 3386-1 1986 Polymeric materials, cellular flexible - Determination of stress-strain characteristics in compression - Part 1 Low-density materials ISO 3386-2 1997 Flexible cellular polymeric materials - Determination of stress-strain characteristics in compression - Part 2 High-density materials ISO 5893 2002 Rubber and plastics test equipment - Tensile, flexural and compression types (constant rate of traverse) - Specification ISO 7743 2004 Rubber, vulcanized or thermoplastic - Determination of compression stress-strain properties... 

The classical means for following vulcanization by physical methods is to vulcanize a series of sheets for increasing time intervals and then measure the stress strain properties of each and plot the results as a function of vulcanization time. A modification of this test generally called a rapid modulus test is widely used in the industry as a production control test. A single sample taken from a production batch of compounded rubber is vulcanized at a high temperature and its tensile modulus is measured. Temperatures as high as 380°F are used to reduce the vulcanization test time to only a few minutes. Any modulus value deviating from a predetermined acceptance limit indicates that the batch is defective and is to be rejected. 

The measurement of extension (or other mode of deformation) is an essential part of several tests, notably tensile or compression stress/strain properties and also thermal expansion. The precision required must be specified in the individual test method and is unlikely to be the same as that required for test piece dimensions. The method of measurement will also be dependent on the test in question and particular techniques will be given in most cases. Hence, the requirements for specific tests will be discussed in the relevant sections in later chapters. 

Because the duration for one measurement is very short (e.g., with a 1-Hz input, a cycle is completed in 1 sec), a dynamic test is suitable for gaining information in a short time frame or for monitoring time-dependent changes in gel network properties. When monitoring the gelation process at a fixed frequency, it usually takes a few hours for G to become approximately constant. The constancy can be judged by a constant value of G at a fixed frequency during a subsequent frequency or strain sweep test, which usually takes several minutes. 

Rubber, vulcanized or thermoplastic Determination of tensile stress-strain properties Standard test methods for vulcanized rubber and thermoplastic elastomers-tension... 

Determination of tensile strength at break, tensile stress at yield, elongation at break, and stress values of rubber in a tensile test Physical testing of rubber Part A2 Method for determination of tensile stress-strain properties... 

To relate the physical properties of carbon black to rubber properties, we tested these tread blacks in the ASTM natural rubber recipe and in an SBR 1500 test recipe. In both elastomers, we checked standard stress/strain properties of modulus, tensile strength, and hardness. In the natural rubber recipe we also tested Firestone running temperature and rebound, and Goodyear rebound. In the SBR we checked percent swell, extrusion rate, viscosity, and laboratory abrasion. 

Fatigue is the decay of mechanical properties after repeated application of stress and strain. Fatigue tests given information about the ability of a material to resist the development of cracks or crazes resulting from a large number of deformation cycles. 

Despite the difficulties associated with the BMI/copper laminates (as just discussed), an understanding of their adhesion characteristics remains important. In particular there is an interest in the relationship between adhesive fracture toughness and temperature. This can be approached by use of either test geometry. The fixed arm peel procedure can be conducted at different test temperatures. The tensile stress-strain properties of the peel arm can also be measured at these temperatures and adhesive fracture toughness calculated in the usual manner and plotted against temperature. This can be a time-consuming process that can be overcome by use of a T-peel procedure operating as a temperature scan. 

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