Staple formation

Before the filament or staple is used in yam spinning, spin finishes are added to give lubricity and antistatic characteristics to the fibers and to provide a greater degree of fiber cohesiveness. Such finishes are usually mixtures including such materials as fatty acid esters, mineral oils, synthetic esters, silicones, cationic amines, phosphate esters, emulsifiers, and/or nonionic surfactants. Spin finishes are formulated to be oxidation resistant, to be easily removed by scouring, to give a controlled viscosity, to be stable to corrosion, to resist odor and color formation, and to be non-volatile and readily emulsifiable. 

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Briggs, T., M. W. Whitehouse, and E. Staple Formation of bile acids from cholesterol in the alligator. Arch. Biochem. 85, 275 (1959). 

Process conditions that favor chemical crimp formation are similar to those used for improved tenacity staple (2inc/modifier route). However, spin bath temperature should be as high as possible (ca 60°C) and the spin-bath acid as low as possible (ca 7%). Attempts have been made to overcome some of the leanness of high strength rayons by increasing the crimp levels. ITT Rayonier developed the Prim a crimped HWM fiber (36) and made the process available to their customers. Avtex developed Avdl 111. Neither remain in production. 

Johnson, LV, Ozaki, S, Staples, MK, Erickson, PA, and Anderson, DH, 2000. A potential role for immune complex pathogenesis in drusen formation. Exp Eye Res 70,441 449. 

Johnson, LV, Leitner, WP, Staples, MK, and Anderson, DH, 2001. Complement activation and inflammatory processes in drusen formation and age related macular degeneration. Exp Eye Res 73, 887-896. 

Starch is an abundant, inexpensive polysaccharide that is readily available from staple crops such as com or maize and is thus is mostly important as food. Industrially, starch is also widely used in papermaking, the production of adhesives or as additives in plastics. For a number of these applications, it is desirable to chemically modify the starch to increase its hydrophobicity. Starch modification can thus prevent retrodegradation improve gel texture, clarity and sheen improve film formation and stabilize emulsions [108], This may, for example, be achieved by partial acetylation, alkyl siliconation or esterification however, these methods typically require environmentally unfriendly stoichiometric reagents and produce waste. Catalytic modification, such as the palladium-catalyzed telomerization (Scheme 18), of starch may provide a green atom-efficient way for creating chemically modified starches. The physicochemical properties of thus modified starches are discussed by Bouquillon et al. [22]. 

The reversibility of cyanohydrin formation is of more than theoretical interest. In parts of Africa the staple food is cassava. This food contains substantial quantities of the glucoside of acetone cyanohydrin (a glucoside is an acetal derived from glucose). We shall discuss the structure of glucose later in this chapter, but for now, just accept that it stabilizes the cyanohydrin. 

Polyester. The most common polyester in use is derived from the homopolymer poly (ethylene terephthalate). Many types of this fiber contain a delustrant, usually titanium dioxide. Optically brightened polymers are quite common. The optical brightener, such as specially stabilized derivatives of either stilbenes or phenylcoumarins, can be added to the polyester before formation of the fiber (107). Some commercial fibers contain minor amounts of copolymerized modifier to confer such properties as basic dyeability. A wide range of polyester fibers is used for consumer end-uses. Both staple fiber and filament yarn are available. Filament yarns with noncircular cross-sections are made (107). 

Fig. 12.28. Flow diagram for manufacture of textile glass fiber (1) glass batch (2) batch cans (3) marble forming (4) cullet cans (5) marbles (6) melting furnaces (7) filament yarn formation (8) gathering and sizing (9) yarn packaging (10) air jets (11) lubricant spray (12) collection for staple fibers (13) staple fiber packaging. (Courtesy Owens-Coming Fiberglass Corp.)...

As a form of direct fabric evidence, the physical shapes of textile fabric pseudomorphs have been studied to identify fiber type and yam and fabric construction. Pseudomorphs of paired filaments in mineralized fabric formations found on Shang-period bronze weapons were determined to be replaced silk (I, 2) S-and Z-twisted silk staple yarn pseudomorphs were identified as well as fabric constructions, including float yams and a ribbed weave. 

In a study of skin wormd repair, using sutures or staples on rats, it was shown that covering the wormd with gel-formers allows the use of half the number of interrupted suture stitches or staples while minimizing scar formation. 

As manual, multichannel pipeting devices and plate-based detection systems became staple tools in the modem discovery laboratory, bioassays for moderate throughput have been developed in a wide variety of formats. The flexibility of these detection devices allowed assays that utilize visible-, fluorescence-, luminescence-, and radioactive-based readouts. Manual pi-... 

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