Spectroscopy chemistry

D. Klapstein, J. P. Maier and L. Misev, in Molecular Ions Spectroscopy, Chemistry and Structure (Eds. T. A. Miller and V. Bondybey), North-Holland, Amsterdam, 1983. 

Deng, Q., Moore, R. B. and Mauritz, K. A. 1995. Novel Nation ORMOSIL hybrids via in situ sol-gel reactions. 1. Probe of ORMOSIL phase nanostructures by infrared spectroscopy. Chemistry of Materials 7 2259-2268. 

Mantsch, H. H. and McElhaney, M. J. Phospholipid phase transitions in model and biological membranes as studied by infrared spectroscopy. Chemistry and Physics of Lipids 57(2-3) 2l3-226, 1991. 

Chen J, Jiang J, Gao X, Liu G, Shen G, Yu R (2008) A new aptameric biosensor for cocaine based on surface-enhanced Raman scattering spectroscopy. Chemistry 14(27) 8374—8382... 

Marcelo F, Dias C, Martins A, Madeira PJ, Jorge T, Florencio MH et al (2013) Molecular recognition ofrosmarinic acid from Salvia scla-reoides extracts by acetylcholinesterase A new binding site detected by NMR spectroscopy. Chemistry 19 6641-6649... 

Muik, B., Lendl, B., Malina-Diaz, A., and Ayora-Canada, M.J. Direct monitoring of bpid oxidation in edible oils by Fourier transform Raman spectroscopy. Chemistry and Physics of Lipids, 134, 173-182. 2005. 

Wu B, Liu Y, Zhang YM, Wang H (2009) Probing intermolecular interactions in ionic liquid-water mixtures by near-infrared spectroscopy. Chemistry 15 6889-6893... 

In an electron spin resonance spectrometer, transitions between the two states are brought about by the application of the quantum of energy hv which is equal to g H. The resonance condition is defined when hv = g H and this is achieved experimentally by varying H keeping the frequency (v) constant. Esr spectroscopy is used extensively in chemistry in the identification and elucidation of structures of radicals. 

M. L. Hair, Infrared Spectroscopy in Surface Chemistry, Marcel Dekker, New York,... 

L. H. Little, Infrared Spectra of Adsorbed Molecules, Academic, New York, 1966. 68a. M. L. Hair, Infrared Spectroscopy in Surface Chemistry, Marcel Dekker, New... 

Although a separation of electronic and nuclear motion provides an important simplification and appealing qualitative model for chemistry, the electronic Sclirodinger equation is still fomiidable. Efforts to solve it approximately and apply these solutions to the study of spectroscopy, stmcture and chemical reactions fonn the subject of what is usually called electronic structure theory or quantum chemistry. The starting point for most calculations and the foundation of molecular orbital theory is the independent-particle approximation. 

Lee S-Y 1995 Wave-packet model of dynamic dispersed and integrated pump-probe signals in femtosecond transition state spectroscopy Femtosecond Chemistry ed J Manz and L Wdste (Heidelberg VCH)... 

Temperature progranuned desorption (TPD), also called thenual desorption spectroscopy (TDS), provides infonuation about the surface chemistry such as surface coverage and the activation energy for desorption [49]. TPD is discussed in detail in section B 1.25. In TPD, a clean surface is first exposed to a gaseous... 

Avouris P and Woikow R 1989 Atom-resoived chemistry studied by scanning tunneiing microscopy and spectroscopy Phys. Rev. B 39 5091... 

Moseley J and Durup J 1981 Fast ion beam photofragment spectroscopy Annual Review of Physical Chemistry ed B S Rabinovitch, J M Schurr and H L Strauss (Palo Alto, CA Annual Reviews)... 

Dessent C E FI and Johnson M A 1998 Fundamentals of negative ion photoelectron spectroscopy Fundamentals and Applications of Gas Phase Ion Chemistry ed K R Jennings (Berlin Kluwer)... 

Flowever, in order to deliver on its promise and maximize its impact on the broader field of chemistry, the methodology of reaction dynamics must be extended toward more complex reactions involving polyatomic molecules and radicals for which even the primary products may not be known. There certainly have been examples of this notably the crossed molecular beams work by Lee [59] on the reactions of O atoms with a series of hydrocarbons. In such cases the spectroscopy of the products is often too complicated to investigate using laser-based techniques, but the recent marriage of intense syncluotron radiation light sources with state-of-the-art scattering instruments holds considerable promise for the elucidation of the bimolecular and photodissociation dynamics of these more complex species. 

Quack M 1993 Molecular quantum dynamics from high resolution spectroscopy and laser chemistry J. Mol. Struct. 292 171-95... 

Quack M 1992 Time dependent intramolecular quantum dynamics from high resolution spectroscopy and laser chemistry Time Dependent Quantum Molecular Dynamics Experiment and Theory. Proc. NATO ARW 019/92 (NATO ASI Ser. Vol 299) ed J Broeckhove and L Lathouwers (New York Plenum) pp 293-310... 

Quack M 1981 Faraday Discuss. Chem. Soc. 71 309-11, 325-6, 359-64 (Discussion contributions on flexible transition states and vibrationally adiabatic models statistical models in laser chemistry and spectroscopy normal, local, and global vibrational states)... 

Meier C and Engel V 1995 Pump-probe ionization spectroscopy of a diatomic molecule sodium molecule as a prototype example Femtosecond Chemistry Proc. Berlin Conf Femtosecond Chemistry (Berlin, March 1993) (Weinheim Verlag Chemie)... 

Vibrational spectroscopy is an enomiously large subject area spamiing many scientific disciplines. The methodology, both experimental and theoretical, was developed primarily by physical chemists and has branched far and wide over the last 50 years. This chapter will mainly focus on its importance with regard to physical chemistry. 

Within physical chemistry, the long-lasting interest in IR spectroscopy lies in structural and dynamical characterization. Fligh resolution vibration-rotation spectroscopy in the gas phase reveals bond lengths, bond angles, molecular symmetry and force constants. Time-resolved IR spectroscopy characterizes reaction kinetics, vibrational lifetimes and relaxation processes. 

Vibrational spectroscopy has been, and will continue to be, one of the most important teclmiques in physical chemistry. In fact, the vibrational absorption of a single acetylene molecule on a Cu(lOO) surface was recently reported [ ]. Its endurance is due to the fact that it provides detailed infonnation on structure, dynamics and enviromnent. It is employed in a wide variety of circumstances, from routine analytical applications, to identifying novel (often transient) species, to providing some of the most important data for advancing the understanding of intramolecular and intemiolecular interactions. 

Asher S A 1993 UV resonance Raman-spectroscopy for analytical, physical and biophysical chemistry 2 Anal. Chem. 

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