Specialty foams

MISCELLANEOUS AND SPECIALTY FOAMS (Epoxy Foams, Polyester Foams, Silicone Foams, Urea-Formaldehyde Foams, Polybenzimidazole, Foams, Polyimide Foams, Polyphosphazene Foams, and Syntactic Foams)... 

Chapter 3 and all subsequent chapters were prepared by the editor, A.H. Landrock. Chapter 3 covers all types of thermoplastic foams, including rigid, semi-rigid, and structural foams. Chapter 4 briefly discusses elastomeric foams. Chapter 5 discusses a number of miscellaneous and specialty foams, many of which were also covered in Chapter 2. 

Over 90% of all flexible PU foam production is now based on polyether polyols and 80 20 TDI. Some specialty foams have been developed recently using MDI, either alone or in combination with TDI. These new materials have been produced primarily for furniture and vehicle seating. ... 

Voranate. Pow Dow Ahlen] Specialty isocyanates for polyurediane industry for appliances, specialty foams. 

Uses Specialty foam booster/stabilizer, detergent, vise, builder tor shampoo, bubble baths, liq. dishwashing and general detergents emulsifier in heavy-duty built liqs. 

Uses Surfactant blend used in household and industrial liq. laundry, hand dish-wash, hard surf cleaners, and specialty foam applies. functions well in hard water... 

Uses Specialty foaming and wetting agent in high electrolyte cones. primary emulsifier in emulsion polymerization... 

STEPAN MC-48/LM 80/20 Blend surfactant blend, oil post-emergence herbicides Crop Oil Concentrate surfactant blend, specialty foam applies. 

The isocyanates used with rigid foam systems are either polymeric MDI or specialty types of TDI. Both contain various levels of polymerized isocyanate groups which contribute to molecular weight per cross-link and also may affect reactivity due to steric hindrance of some isocyanate positions. 

Betaines, or specialty quaternaries, are used in the personal care industry in shampoos, conditioners, foaming, and wetting agents. 

Synthetic Resins. Various polymers and resins are utilized to produce some specialty carbon products such as glassy carbon or carbon foam and as treatments for carbon products. Typical resins include phenoHcs, furan-based polymers, and polyurethanes. These materials give good yields of carbon on pyrolysis and generally carbonize directly from the thermoset polymer state. Because they form Httle or no mesophase, the ultimate carbon end product is nongraphitizing. 

Carbon—graphite foam is a unique material that has yet to find a place among the various types of commercial specialty graphites. Its low thermal conductivity, mechanical stabiHty over a wide range of temperatures from room temperature to 3000°C, and light weight make it a prime candidate for thermal protection of new, emerging carbon—carbon aerospace reentry vehicles. 

As of 1992, the first specialty platable plastic, acrylonitrile—butadiene—styrene (ABS) terpolymer (see Acrylonitrile polymers, ABS resins), is used ia over 90% of POP appHcatioas. Other platable plastics iaclude poly(pheayleae ether) (see PoLYETPiERs), ayloa (see Polyamides), polysulfoae (see Polymers CONTAINING sulfur), polypropyleae, polycarboaate, pheaoHcs (see Pphenolic resins), polycarboaate—ABS alloys, polyesters (qv), foamed polystyreae (see Styrene plastics), and other foamed plastics (qv). 

Plastic also refers to a material that has a physical characteristic such as plasticity and toughness. The general term commodity plastic, engineering plastic, advanced plastic, advanced reinforced plastic, or advanced plastic composite is used to indicate different performance materials. These terms and others will be reviewed latter in this chapter. Plastics are made into specialty products that have developed into major markets. An example is plastic foams that can provide flexibility to rigidity as well as other desired properties (heat and electrical insulation, toughness, filtration, etc.). 

Polyester polyols account for only ca. 10% of the total polyol market, which is dominated by polyether polyols such as hydroxy-terminated polyoxyethylene or polyoxypropylene. Polyester polyols are preferred for applications where better mechanical properties, wear resistance, and UV stability are required. The largest application of polyester polyols is flexible specialty polyurethane foam in the furniture, packaging, and automotive industries. Polyester polyols are also used for nonfoam applications such as coatings, paints, sealants, and adhesives 47... 

Place Arcol Polyol F-3022 (100 g, 0.1 eq., 56 OH, mixed PO/EO triol from Bayer) into a suitable container. To this add distilled water (3.3 g, 0.4125 eq.), Niax Silicone L-620 (0.5 g, a silicone surfactant from OSi Specialties), and Niax C-183 (0.12 g, an amine catalyst from OSi Specialties). Thoroughly blend this mixture without incorporating air bubbles. Then add Dabco T-9 (0.25 g, stannous octoate from Air Products) and mix again. The T-9 must be added last because it is quite water sensitive, so its exposure to the water-containing polyol blend should be kept to a minimum. To this polyol blend, quickly add Mondur TD-80 (42.6 g, 0.4868 eq., a mixture of 80% 2,4-TDI and 20% 2,6-TDI isomers from Bayer) and immediately stir at 3000 rpm for 5 s. Quickly pour the reaction mixture into a suitable container such as a 1-qt paper or plastic cup and allow the foam to free-rise. The stir blade may be wiped or brushed clean. 

In the production of aerated confections it is very important to add various hydrocolloids, in order to obtain a foam which will withstand the specific stability requirements of the specialty food product involved. 

Isocyanates that are produced fi om aliphatic amines are utilized in a limited range of polyurethane products, mainly in weatherable coatings and specialty applications where the yellowing and photodegradation of the aromatic polyurethanes are undesirable [5]. The aliphatic isocyanates are not used more widely in the industry due to the remarkably slow reaction kinetics of aliphatic isocyanates compared to their aromatic counterparts [6]. Due to the slow reactivity of aliphatic isocyanates, it is not practical to use them in the preparation of flexible or rigid foams, which are the main commercial applications for polyurethane chemistry. 

Perhaps the most interesting application of polyurethane foam as a substratum for cell growth was studied by Bailliez et al. While not specifically a remediation study, their work compared hydrophobic and hydrophilic polyurethanes, TDI- and MDI-based prepolymers, and entrapment and adsorption methods, and also investigated the production of hydrocarbons by Botryococcus braunii. An unfortunate feature of biotechnical research in the use of polyurethanes is that the chemistry is rarely explained. While Bailliez includes some detail, much of their work simply designates products without specific references to the polyols. It is, of course, part of the mission of this book to show that polyurethanes are specialty chemicals. It cannot be assumed... 

Specialty Glass Products. Foam glass insulation and glass building blocks are two specialty glass products with construction applications. 

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