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Solvents in analytical chemistry

SFE has also replaced many regulated solvents in analytical chemistry applications in recent years, primarily because it provides a more reliable measure of the concentrations of environmental contaminants and can play an important role in pollution assessment, abatement, and control. Advantages have been shown for using SFE compared to the conventional Soxhlet extraction with toluene for determining the presence of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in ashes from a municipal incinerator (Dolezal et al., 1995). SFE allows the complete extraction of the analytes from the sample, whereas conventional extraction results in an incomplete, and hence, inferior extraction. [Pg.244]

Morrison, G. Fi. Freiser, H. Solvent Extraction in Analytical Chemistry, John Wiley and Sons New York, 1957. [Pg.231]

Finally, we note that the size and shape of the particles of the packing, the packing technique, and column dimensions and configuration are additional factors which influence a GPC experiment. In addition, the flow rate, the sample size, the sample concentration, the solvent, and the temperature must all be optimized. Details concerning these considerations are found in analytical chemistry references, as well as in the technical literature of instrument manufacturers. [Pg.652]

Arsonium salts have found considerable use in analytical chemistry. One such use involves the extraction of a metal complex in aqueous solution with tetraphenyiarsonium chloride in an organic solvent. Titanium(IV) thiocyanate [35787-79-2] (157) and copper(II) thiocyanate [15192-76-4] (158) in hydrochloric acid solution have been extracted using tetraphenyiarsonium chloride in chloroform solution in this manner, and the Ti(IV) and Cu(II) thiocyanates deterrnined spectrophotometricaHy. Cobalt, palladium, tungsten, niobium, and molybdenum have been deterrnined in a similar manner. In addition to their use for the deterrnination of metals, anions such as perchlorate and perrhenate have been deterrnined as arsonium salts. Tetraphenyiarsonium permanganate is the only known insoluble salt of this anion. [Pg.339]

A knowledge of stability constant values is of considerable importance in analytical chemistry, since they provide information about the concentrations of the various complexes formed by a metal in specified equilibrium mixtures this is invaluable in the study of complexometry, and of various analytical separation procedures such as solvent extraction, ion exchange, and chromatography.2,3... [Pg.53]

H Freiser, Solvent extraction in analytical chemistry and separation science Bunseki Kagaku, 1981, 30, S47-S57... [Pg.253]

Standardization. Standardization in analytical chemistry, in which standards are used to relate the instrument signal to compound concentration, is the critical function for determining the relative concentrations of species In a wide variety of matrices. Environmental Standard Reference Materials (SRM s) have been developed for various polynuclear aromatic hydrocarbons (PAH s). Information on SRM s can be obtained from the Office of Standard Reference Materials, National Bureau of Standards, Gaithersburg, MD 20899. Summarized in Table VII, these SRM s range from "pure compounds" in aqueous and organic solvents to "natural" matrices such as shale oil and urban and diesel particulate materials. [Pg.115]

Many of the classical techniques used in the preparation of samples for chromatography are labour-intensive, cumbersome, and prone to sample loss caused by multistep manual manipulations. During the past few years, miniaturisation has become a dominant trend in analytical chemistry. At the same time, work in GC and UPLC has focused on improved injection techniques and on increasing speed, sensitivity and efficiency. Separation times for both techniques are now measured in minutes. Miniaturised sample preparation techniques in combination with state-of-the-art analytical instrumentation result in faster analysis, higher sample throughput, lower solvent consumption, less manpower in sample preparation, while maintaining or even improving limits. [Pg.123]

Miniaturisation of scientific instruments, following on from size reduction of electronic devices, has recently been hyped up in analytical chemistry (Tables 10.19 and 10.20). Typical examples of miniaturisation in sample preparation techniques are micro liquid-liquid extraction (in-vial extraction), ambient static headspace and disc cartridge SPE, solid-phase microextraction (SPME) and stir bar sorptive extraction (SBSE). A main driving force for miniaturisation is the possibility to use MS detection. Also, standard laboratory instrumentation such as GC, HPLC [88] and MS is being miniaturised. Miniaturisation of the LC system is compulsory, because the pressure to decrease solvent usage continues. Quite obviously, compact detectors, such as ECD, LIF, UV (and preferably also MS), are welcome. [Pg.726]

K. Burger, Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents (Experimental Methods for their Investigation), Studies in Analytical Chemistry, Vol. 6, Elsevier, Amsterdam, 1983, Ch. 2 and 3 and Ch. 9, pp. 256-257. [Pg.313]

Some ionizing solvents are of major importance in analytical chemistry whilst others are of peripheral interest. A useful subdivision is into protonic solvents such as water and the common acids, or non-protonic solvents... [Pg.31]

Morrison, G.H., and F. Freiser, Solvent Extraction in Analytical Chemistry , New York, Wiley, 1957. [Pg.408]

Many hydroxyp5rranones and hydroxypyridinones and their metal complexes have been of importance in analytical chemistry, solvent extraction, and metal separation. Here their excellent chelating properties in conjunction with the possibility of synthesizing strongly lipophilic derivatives make this class of ligands particularly useful. [Pg.214]

Solvent extraction is used in nnmerons chemical industries to produce pure chemical compounds ranging from pharmaceuticals and biomedicals to heavy organics and metals, in analytical chemistry and in environmental waste purification. The scientific explanation of the distribution ratios observed is based on the fundamental physical chemistry of solute-solvent interaction, activity factors of the solutes in the pure phases, aqueous complexation, and complex-adduct interactions. Most university training provides only elementary knowledge about these fields, which is unsatisfactory from a fundamental chemical standpoint, as well as for industrial development and for protection of environmental systems. Solvent extraction uses are important in organic, inorganic, and physical chemistry, and in chemical engineering, theoretical as well as practical in this book we try to cover most of these important fields. [Pg.12]

Valcarcel, M. Liquid-Liquid Extraction in Continuous Flow Analysis. In Developments in Solvent Extraction, S. Alegret, Ed., Ellis Horwood Series in Analytical Chemistry West Sussex, UK, 1988 p. 135. [Pg.602]


See other pages where Solvents in analytical chemistry is mentioned: [Pg.31]    [Pg.192]    [Pg.31]    [Pg.606]    [Pg.42]    [Pg.530]    [Pg.26]    [Pg.270]    [Pg.133]    [Pg.212]    [Pg.204]    [Pg.288]    [Pg.239]    [Pg.31]    [Pg.192]    [Pg.31]    [Pg.606]    [Pg.42]    [Pg.530]    [Pg.26]    [Pg.270]    [Pg.133]    [Pg.212]    [Pg.204]    [Pg.288]    [Pg.239]    [Pg.52]    [Pg.26]    [Pg.121]    [Pg.100]    [Pg.216]    [Pg.435]    [Pg.631]    [Pg.23]    [Pg.215]    [Pg.144]    [Pg.352]    [Pg.12]    [Pg.3]    [Pg.559]    [Pg.560]    [Pg.570]    [Pg.38]    [Pg.49]   
See also in sourсe #XX -- [ Pg.41 ]

See also in sourсe #XX -- [ Pg.41 ]




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