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Simultaneous Operations matrix

In Eq. (177) in the presence of nonzero external fields, the spur operation over the internal degrees of freedom and the integration over the angles cannot be performed separately, since p depends on the angles fl and (l0 and is simultaneously the matrix in the basis of the vibronic states. The analysis of the density matrix p is given in the next section. [Pg.63]

A recent SPP-resonance Raman experiment explored the structural conformations of several carbon clusters. The Ci6, Ci8, and C20 clusters were created by laser ablation of a graphite rod and then deposited into a N2 matrix on the silvered SPP prism surface. After finding the SPP resonance condition (as described in Section VLB), Raman spectra were collected with six different excitation wavelengths. SPP-Raman enhancement is operative in all six spectra. The strong dependence of the Raman spectra for the C20 cluster on Xex shown in Fig. 10 indicates that enhancement due to RRS is simultaneously operative. It is important to emphasize that these signals shown in this figure are obtained from ca. 10 clusters in the laser focal spot. Upon comparing the Raman peak frequencies for all three carbon clusters to theoretical predictions, the researchers were able to hypothesize that all three carbon clusters adopt either a linear chain or poly-... [Pg.456]

A very convenient feature is that, in order to construct the p - SRH matrix it is not necessary to evaluate the 2 matrix and then apply the MCM since both operations can be combined and carried ont simultaneously. Thus, by replacing in relation (17)... [Pg.59]

It is desirable to "decouple" the system so that each manipulated variable appears to affect only one of the output variables. This requires a matrix upstream of the process which, in response to a change in only one of its input signals, will manipulate all the actual process inputs simultaneously so that only the desired output signal changes. If decoupling is to be accomplished only at steady state conditions this matrix is a set of constants. However, if decoupling is required during transient operation the matrix must contain dynamic transfer functions, some of which may not be physically realizable. [Pg.191]

Equations 4-4, 4-5, and 4-6 represent the three elements of the matrix product of [A] and [B], Note that each row of this resulting matrix contains only one element, even though each of these elements is the result of a fairly extensive sequence of arithmetic operations. Equations 4-4, 4-5, and 4-7, however, represent the symbolism you would normally expect to see when looking at the set of simultaneous equations that these matrix expressions replace. Note further that this matrix product [A][fl] is the same as the entire left-hand side of the original set of simultaneous equations that we originally set out to solve. [Pg.24]

Let us examine these symbolic transformations with a view toward seeing how they translate into the required arithmetic operations that will provide the answers to the original simultaneous equations. There are two key operations involved. The first is the inversion of the matrix, to provide the inverse matrix. This is an extremely intensive computational task, so much so that it is in general done only on computers, except in the simplest cases for pedagogical purposes, such as we did in our previous chapter. [Pg.26]

Unlike column chromatography approaches that can only process single samples sequentially, one TLC plate can accommodate and analyze multiple samples and standards. Numerous samples are processed simultaneously in a unique solvent tank, separating out the stabilizer or explosive analyte(s) away from the sample matrix. Semi-quantitative assessments with nanogram detection limits are readily obtained by inspection of the plates. This process allows numerous samples to be analyzed by a single operator per day. [Pg.127]

In the third stage, styrene and acrylonitrile - and, optionally, other monomers - are copolymerized, either simultaneously with the second, i.e., grafting, or separately in an independent operation, to form the rigid matrix. Again, this polymerization may be carried out in emulsion, bulk, or suspension (15). [Pg.333]

Solving Simultaneous Linear Equations with Excel Matrix Operations ... [Pg.405]

The absorbance of a mixture is the sum of absorbances of the individual components. At a minimum, you should be able to find the concentrations of two species in a mixture by writing and solving two simultaneous equations for absorbance at two wavelengths. This procedure is most accurate if the two absorption spectra have regions where they do not overlap very much. With a spreadsheet, you should be able to use matrix operations to solve n simultaneous Beer s law equations for n components in a solution, with measurements at n wavelengths. You should be able to use Excel SOLVER to decompose a spectrum into a sum of spectra of the components by minimizing the function (Aca c — Am)2. [Pg.417]

Obviously, the ease with which the enzyme support can be reclaimed and enzyme activity re-immobilized will make a significant contribution to the cost of bioreactor operation. The higher the initial cost of the support matrix, the more important this regenerative capability becomes. Thus, future development of well defined, stable enzyme supports may depend upon concomitant development of efficient, high affinity, and selective adsorption techniques to allow simultaneous isolation and immobilization. [Pg.247]

The energy dispersive x-ray fluorescence spectrometer, which had been developed recently as a qualitative analysis instrument, showed promise of meeting the goals of the new laboratory (1). Its unique features, which earned it the name, The Curators Dream Instrument, are The measurements require neither sampling nor alteration of the object in any way. Systems for obtaining quantitative analysis data are now operational (I). Concentrations of up to thirty elements above chlorine (Z = 17) can now be printed out simultaneously. Techniques have been developed that minimize errors caused by sample size, shape, position, overlapping spectral peaks, matrix effects, and baseline compensation. Interpretative procedures have been established that recognize the shallow depth of penetration of the excitation radiation (2). [Pg.143]


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