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Shear flow direction

The impact strength was measured in three fractured directions along the shear flow direction, perpendicular to, and 45° angle with respect to the flow directions. They showed the fracmre directions and the morphology of rubber domains could be strongly correlated with the impact strength. [Pg.214]

In stiU another case, nucleating agent may self-assemble into the form of fibrils which align themselves along the shear flow direction. These assemblies induce the formation of highly orientated PL A lamellae. ... [Pg.58]

Fig. 3.4 Representative TEM morphology seen in quenched linear PE crystallized isothermally at 115°C. Sample had been sheared at 25 s. The arrow indicates the shear flow direction in the melt. Y. An et al. (2006) Polymer 47 5643-5656... Fig. 3.4 Representative TEM morphology seen in quenched linear PE crystallized isothermally at 115°C. Sample had been sheared at 25 s. The arrow indicates the shear flow direction in the melt. Y. An et al. (2006) Polymer 47 5643-5656...
Amount of birefringence An at start of steady shear flow. Directions of pips represent rates of shear pip up, 0.0066 s" with successive 45° rotations clockwise representing 0.0118, 0.0216, 0.038, 0.066, 0.118, and 0.214 s , respectively. Open and solid circles, respectively, indicate data obtained with 2 and 3 mm widths of cylindrical gap. From Osaki et al. (1979). [Pg.416]

It is not uncommon for the presence of bulk nanofiller particles in a conventional polymer system to lead to a reduction in melt spiimability or even provoke the formation of aggregates, owing to instabilities, such as localisation and phase segregation. However, in this work, because the layered-silicate had already been intercalated and partially exfoliated via compounding prior to melt-spinning, the resultant particles would exhibit an improved aspect ratio and anisotropy. This, in effect, should lead to an enhanced mesoscopic reorientation ability of the silicate platelets in the shear flow direction, which, in turn, could promote the realignment of the polymer chain (Giannelis et al., 1999). [Pg.503]

Figure 3.10 Illustration of the implementation of simple shear in Lees-Edwards boundary conditions for a packing of bidisperse disks. The particles in the main cell are given the affine deformation in Equation 3.9. The image cells above and below in the central cell in the shear gradient direction are also shifted by LAy in the shear flow direction. Figure 3.10 Illustration of the implementation of simple shear in Lees-Edwards boundary conditions for a packing of bidisperse disks. The particles in the main cell are given the affine deformation in Equation 3.9. The image cells above and below in the central cell in the shear gradient direction are also shifted by LAy in the shear flow direction.
Figure 3.11 Illustration of the implementation of simple shear in 2D systems with fixed walls (dark shading) in the shear gradient direction and periodic boundary conditions in the shear flow direction. In this example, only the boundaries were moved with no affine bulk (light shading) deformation, followed by energy minimization at fixed locations of the boundaries. The particle positions before and after a shear strain step (center) and before and after the energy minimization (right) are shown. Figure 3.11 Illustration of the implementation of simple shear in 2D systems with fixed walls (dark shading) in the shear gradient direction and periodic boundary conditions in the shear flow direction. In this example, only the boundaries were moved with no affine bulk (light shading) deformation, followed by energy minimization at fixed locations of the boundaries. The particle positions before and after a shear strain step (center) and before and after the energy minimization (right) are shown.
Amphiphilic dye molecules such as sulfonated chromogens can be used in place of PVA iodine for the preparation of thin polarizing films [60]. These molecules are usually water soluble and at a wide range of concentrations, temperatures, and pH values they self-assemble and stack up to form hexagonal complexes. This is usually referred to as the lyotropic LC phase [1]. It can be orientated, by mechanical shear stress, so that the lyotropic liquid crystal (LLC) is orientated parallel to the shear flow direction (Figure 4.21). [Pg.90]

The drag force is exerted in a direction parallel to the fluid velocity. Equation (6-227) defines the drag coefficient. For some sohd bodies, such as aerofoils, a hft force component perpendicular to the liquid velocity is also exerted. For free-falling particles, hft forces are generally not important. However, even spherical particles experience lift forces in shear flows near solid surfaces. [Pg.676]

Liquids are able to flow. Complicated stream patterns arise, dependent on geometric shape of the surrounding of the liquid and of the initial conditions. Physicists tend to simplify things by considering well-defined situations. What could be the simplest configurations where flow occurs Suppose we had two parallel plates and a liquid drop squeezed in between. Let us keep the lower plate at rest and move the upper plate at constant velocity in a parallel direction, so that the plate separation distance keeps constant. Near each of the plates, the velocities of the liquid and the plate are equal due to the friction between plate and liquid. Hence a velocity field that describes the stream builds up, (Fig. 15). In the simplest case the velocity is linear in the spatial coordinate perpendicular to the plates. It is a shear flow, as different planes of liquid slide over each other. This is true for a simple as well as for a complex fluid. But what will happen to the mesoscopic structure of a complex fluid How is it affected Is it destroyed or can it even be built up For a review of theories and experiments, see Ref. 122. Let us look into some recent works. [Pg.766]

Unfortunately, a few papers are known where normal stresses during shear flow of filled polymers were measured directly. Here an additional problem is connected with the solution of the problem what is considered a one-valued measure of elasticity of a material and under what conditions to compare the measured values of normal stresses. Moreover, the data at hand often represent rather a contradictory picture. [Pg.92]

A 2 IB. Braun airlift fermenter with a working volume of about 2000 ml was used. Sterile air is sparged through a sintered plate located near the bottom of the central concentric tube. There was no mechanical stirring only the air nozzle was forced through the centred tube and the flow directed to the annulus tube side. Aeration causes circulation of media the flow is gentle without serious shear forces. The temperature is maintained at 26 °C. [Pg.269]

The Giesekus criterion for local flow character, defined as

extensional flow, 0 in simple shear flow and — 1 in solid body rotation [126]. The mapping of J> across the flow domain provides probably the best description of flow field homogeneity current calculations in that direction are being performed in the authors laboratory. [Pg.126]

Sundararajan et al. [131] in 1999 calculated the slurry film thickness and hydrodynamic pressure in CMP by solving the Re5molds equation. The abrasive particles undergo rotational and linear motion in the shear flow. This motion of the abrasive particles enhances the dissolution rate of the surface by facilitating the liquid phase convective mass transfer of the dissolved copper species away from the wafer surface. It is proposed that the enhancement in the polish rate is directly proportional to the product of abrasive concentration and the shear stress on the wafer surface. Hence, the ratio of the polish rate with abrasive to the polish rate without abrasive can be written as... [Pg.258]

Flow is generally classified as shear flow and extensional flow [2]. Simple shear flow is further divided into two categories Steady and unsteady shear flow. Extensional flow also could be steady and unsteady however, it is very difficult to measure steady extensional flow. Unsteady flow conditions are quite often measured. Extensional flow differs from both steady and unsteady simple shear flows in that it is a shear free flow. In extensional flow, the volume of a fluid element must remain constant. Extensional flow can be visualized as occurring when a material is longitudinally stretched as, for example, in fibre spinning. When extension occurs in a single direction, the related flow is termed uniaxial extensional flow. Extension of polymers or fibers can occur in two directions simultaneously, and hence the flow is referred as biaxial extensional or planar extensional flow. [Pg.780]


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