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Sensitivity minimizing

In recent years, CE has been successfully applied in the field of biochemical and analytical chemistry. It has been found to be attractive for pharmaceutical analysis because of its advantages related to excellent separation efficiency, high mass sensitivity, minimal use of samples and solvents, and the possibility of using different direct and indirect detection systems. This review focuses on analytical assays for barbiturates by CE. [Pg.217]

PCR has the advantage of increased sensitivity, minimal tissue requirements, and potential sequencing of the amplified product for specific identification of the microbial genotype or strain of the agent involved. There are PCR assays for most microorganisms that have been or can be adapted for use on formalin-fixed... [Pg.72]

The main benefit of the on-line coupling of an extraction to a chromatographic technique is that the whole analysis can be performed in a closed system. The main advantages are the improved sensitivity, minimal sample contamination and the possibility for a totally automated analytical... [Pg.120]

Atomic emission and atomic absorption techniques are highly selective because the number of elemental analytes is small, and each has a unique atomic spectmm. Frequencies are selected for measurements to maximize selectivity and sensitivity, minimize interferences, and correct for interferences when necessary. Mass spectrometry measures mass to charge ratios of elemental ions in the gas... [Pg.64]

Fortnulating Considerations Add to water/polar liquid phase with sufficient agitation to fully disperse. Material is not overly shear-or heat-sensitive. Minimize ionic concentration Form Supplied Gel concentrate... [Pg.594]

On-column Sample condensed in cooled zone at top of column, then volatilized by programmed heating Increased sensitivity, minimal thermal degradation of solutes, no discrimination effects... [Pg.140]

A number of experimental parameters have to be optimized in order to obtain the best SPECT image. These include attenuation, scatter, linearity of detector response, spatial resolution of the collimator and camera, system sensitivity, minimization of mechanical movements, image slice thickness, reconstruction matrix size and filter methods, sampling intervals and system deadtime. In a hospital, calibrating and monitoring these functions are usually performed by a Certified Nuclear Medicine Technician or a medical physicist. [Pg.994]

So in order to improve selective characteristics of eddy current testing one should minimize phase change under interference factors influence. Analysis of the above characteristics has indicated that in case of interacting under-surface defects, there is an optimal frequency providing the best sensitivity to defect in amplitude. [Pg.288]

For sensitivity detection the standard defectometers were used. Relative sensitivity comparison at steel objects radiographic control by radiation with energy of 25 and 45 MeV shows that sensitivity minimum for 45 MeV energy is very displaced towards the big thickness and has not yet reached its minimal meaning at 500mm thickness. [Pg.515]

Ions are also used to initiate secondary ion mass spectrometry (SIMS) [ ], as described in section BI.25.3. In SIMS, the ions sputtered from the surface are measured with a mass spectrometer. SIMS provides an accurate measure of the surface composition with extremely good sensitivity. SIMS can be collected in the static mode in which the surface is only minimally disrupted, or in the dynamic mode in which material is removed so that the composition can be detemiined as a fiinction of depth below the surface. SIMS has also been used along with a shadow and blocking cone analysis as a probe of surface structure [70]. [Pg.310]

One fiirther method for obtaining surface sensitivity in diffraction relies on the presence of two-dimensional superlattices on the surface. As we shall see fiirtlrer below, these correspond to periodicities that are different from those present in the bulk material. As a result, additional diffracted beams occur (often called fractional-order beams), which are uniquely created by and therefore sensitive to this kind of surface structure. XRD, in particular, makes frequent use of this property [4]. Transmission electron diffraction (TED) also has used this property, in conjunction with ultrathin samples to minimize bulk contributions [9]. [Pg.1756]

Historically, the first and most important capacitance method is the vibrating capacitor approach implemented by Lord Kelvin in 1897. In this technique (now called the Kelvin probe), the reference plate moves relative to the sample surface at some constant frequency and tlie capacitance changes as tlie interelectrode separation changes. An AC current thus flows in the external circuit. Upon reduction of the electric field to zero, the AC current is also reduced to zero. Originally, Kelvin detected the zero point manually using his quadrant electrometer. Nowadays, there are many elegant and sensitive versions of this technique. A piezoceramic foil can be used to vibrate the reference plate. To minimize noise and maximize sensitivity, a phase-locked... [Pg.1894]

Few of the naturally occurring elements have significant amounts of radioactive isotopes, but there are many artificially produced radioactive species. Mass spectrometry can measure both radioactive and nonradioactive isotope ratios, but there are health and safety issues for the radioactive ones. However, modem isotope instmments are becoming so sensitive that only very small amounts of sample are needed. Where radioactive isotopes are a serious issue, the radioactive hazards can be minimized by using special inlet systems and ion pumps in place of rotary pumps for maintaining a vacuum. For example, mass spectrometry is now used in the analysis of Pu/ Pu ratios. [Pg.354]

Ferroelectric Ceramic—Polymer Composites. The motivation for the development of composite ferroelectric materials arose from the need for a combination of desirable properties that often caimot be obtained in single-phase materials. For example, in an electromechanical transducer, the piezoelectric sensitivity might be maximized and the density minimized to obtain a good acoustic matching with water, and the transducer made mechanically flexible to conform to a curved surface (see COMPOSITE MATERIALS, CERAMiC-MATRix). [Pg.206]


See other pages where Sensitivity minimizing is mentioned: [Pg.293]    [Pg.28]    [Pg.325]    [Pg.279]    [Pg.903]    [Pg.922]    [Pg.2935]    [Pg.356]    [Pg.470]    [Pg.207]    [Pg.248]    [Pg.293]    [Pg.28]    [Pg.325]    [Pg.279]    [Pg.903]    [Pg.922]    [Pg.2935]    [Pg.356]    [Pg.470]    [Pg.207]    [Pg.248]    [Pg.640]    [Pg.257]    [Pg.562]    [Pg.1280]    [Pg.1318]    [Pg.1475]    [Pg.1930]    [Pg.2440]    [Pg.234]    [Pg.440]    [Pg.143]    [Pg.504]    [Pg.110]    [Pg.101]    [Pg.26]    [Pg.58]    [Pg.443]    [Pg.692]    [Pg.206]    [Pg.389]    [Pg.38]    [Pg.39]    [Pg.577]   
See also in sourсe #XX -- [ Pg.389 ]




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