Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Reactions with Separation Operations

Examples of PI where reactions are combined with separation operations include... [Pg.135]

Several authors have shown the industrial profit in the development of chemical engineering equipment based on the integration of different functions in a single device (Taylor et al., 2000 Stankiewicz et al, 2000). Multifunctional reactors are processes that combine reaction with other operations like heat exchange or separation in order to enhance chemical conversion. Reactive distillation is certainly one of the most significant example. It presents several benefits (such as reduction of energy consumption, overcome of the limitation of the thermodynamic chemical equilibrium, limitation of side reactions, decrease of waste production) and it is applied in various... [Pg.846]

Reactive adsorption is a multifunctional process that results by integrating any chemical reaction with adsorption operation in a single unit. Reactive adsorption is favorable for those reactions in which the product of interest is in fluid phase and needs to be separated instantaneously. It is also advantageous to those fluid-solid separations, where the incorporation of reaction... [Pg.18]

Another possibility to improve selectivity is to reduce the concentration of monoethanolamine in the reactor by using more than one reactor with intermediate separation of the monoethanolamine. Considering the boiling points of the components given in Table 2.3, then separation by distillation is apparently possible. Unfortunately, repeated distillation operations are likely to be very expensive. Also, there is a market to sell both di- and triethanolamine, even though their value is lower than that of monoethanolamine. Thus, in this case, repeated reaction and separation are probably not justified, and the choice is a single plug-flow reactor. [Pg.51]

Given the choice of a batch rather than continuous process, does this need a different approach to the synthesis of the reaction and separation and recycle system In fact, a different approach is not needed. We start by assuming the process to be continuous and then, if choosing to use batch operation, replace continuous steps by batch steps. It is simpler to start with continuous process operation... [Pg.117]

Experience in air separation plant operations and other ciyogenic processing plants has shown that local freeze-out of impurities such as carbon dioxide can occur at concentrations well below the solubihty limit. For this reason, the carbon dioxide content of the feed gas sub-jec t to the minimum operating temperature is usually kept below 50 ppm. The amine process and the molecular sieve adsorption process are the most widely used methods for carbon dioxide removal. The amine process involves adsorption of the impurity by a lean aqueous organic amine solution. With sufficient amine recirculation rate, the carbon dioxide in the treated gas can be reduced to less than 25 ppm. Oxygen is removed by a catalytic reaction with hydrogen to form water. [Pg.1134]

Significant characteristics of homogeneous catalysis are that they are highly specific and proceed under relatively mild conditions— again in contrast to solid catalysis, which is less discriminating as to reaction and may require extremes of temperature and pressure. A problem with homogeneous operation is the difficulty of separating product and catalyst. [Pg.2092]

A. ot-Chloroelhyl ethyl ether. A mixture of 200 g. (201 ml.) of redistilled paraldehyde, b.p. 121-122.5° (equivalent to 4.54 moles of acetaldehyde), and 200 g. (254 ml., 4.34 moles) of absolute ethanol is placed in a 1-1. three-necked flask fitted with a mechanical stirrer and a gas inlet tube reaching to the bottom of the flask. The mixture is cooled to —5° in a mixture of Dry Ice and acetone, and dry hydrogen chloride (Note 1) is passed into the stirred reaction mixture maintained at about —5° until 200 g. (5.48 moles) has been absorbed. During this operation, which requires about 2 hours, the reaction mixture separates into two layers. The upper layer of crude a-chloroethyl ethyl ether is re-... [Pg.60]

Intelligent engineering can drastically improve process selectivity (see Sharma, 1988, 1990) as illustrated in Chapter 4 of this book. A combination of reaction with an appropriate separation operation is the first option if the reaction is limited by chemical equilibrium. In such combinations one product is removed from the reaction zone continuously, allowing for a higher conversion of raw materials. Extractive reactions involve the addition of a second liquid phase, in which the product is better soluble than the reactants, to the reaction zone. Thus, the product is withdrawn from the reactive phase shifting the reaction mixture to product(s). The same principle can be realized if an additive is introduced into the reaction zone that causes precipitation of the desired product. A combination of reaction with distillation in a single column allows the removal of volatile products from the reaction zone that is then realized in the (fractional) distillation zone. Finally, reaction can be combined with filtration. A typical example of the latter system is the application of catalytic membranes. In all these cases, withdrawal of the product shifts the equilibrium mixture to the product. [Pg.9]

As mentioned earlier, a major cause of high costs in fine chemicals manufacturing is the complexity of the processes. Hence, the key to more economical processes is reduction of the number of unit operations by judicious process integration. This pertains to the successful integration of, for example, chemical and biocatalytic steps, or of reaction steps with (catalyst) separations. A recurring problem in the batch-wise production of fine chemicals is the (perceived) necessity for solvent switches from one reaction step to another or from the reaction to the product separation. Process simplification, e.g. by integration of reaction and separation steps into a single unit operation, will provide obvious economic and environmental benefits. Examples include catalytic distillation, and the use of (catalytic) membranes to facilitate separation of products from catalysts. [Pg.54]

Before a system of batch reaction and separation processes is considered, the main operations that will be used in batch processes need to be reviewed, but with the emphasis on how they will differ from the corresponding operations in continuous processes. [Pg.291]

The product distribution is insensitive to the concentration of reactant B. If B is cheap and does not offer a potential pollution problem downstream, its concentration may be kept at any convenient level. If B is costly or must be removed for other reasons, one has the options of operating with low B concentrations at high conversions in a relatively large reactor to produce a product containing very little B, or of operating at higher B concentrations in a smaller reactor with separation and recycle of unused B. The specified product distribution requires that the mole ratio of V to W be 3 1. To produce 1 mole of W and three of F, one must consume 4 moles of A and 5 moles of B. The feed ratio employed in an actual situation may differ appreciably from 1.25 to enhance the reaction rate or to allow for discarding some A and B. [Pg.335]

As demonstrated by Hoffmann and coworkers, hydroformylation can also be combined with an allylboration and a second hydroformylation, which allows the formation of carbocycles and also heterocycles [213]. A good regioselectivity in favor of the linear aldehyde was obtained by use of the biphephos ligand [214]. Reaction of the allylboronate 6/2-76 having an B-configuration with CO/H2 in the presence of catalytic amounts of Rh(CO)2(acac) and biphephos led to the lactol 6/2-80 via 6/2-77-79 (Scheme 6/2.17). In a separate operation, 6/2-80 was oxidized to give the lactone 6/2-81 using tetrabutyl ammonium perruthenate/N-methylmorpholine N-oxide. [Pg.434]


See other pages where Reactions with Separation Operations is mentioned: [Pg.135]    [Pg.10]    [Pg.135]    [Pg.10]    [Pg.108]    [Pg.71]    [Pg.174]    [Pg.70]    [Pg.11]    [Pg.47]    [Pg.195]    [Pg.247]    [Pg.271]    [Pg.433]    [Pg.19]    [Pg.1281]    [Pg.2552]    [Pg.824]    [Pg.114]    [Pg.19]    [Pg.91]    [Pg.413]    [Pg.539]    [Pg.216]    [Pg.597]    [Pg.5]    [Pg.84]    [Pg.504]    [Pg.200]    [Pg.441]    [Pg.51]    [Pg.566]    [Pg.55]    [Pg.80]    [Pg.285]    [Pg.428]    [Pg.36]   
See also in sourсe #XX -- [ Pg.135 , Pg.136 , Pg.137 ]




SEARCH



Operators reaction

Reaction with Separation

Reactions separation

Separation operation

© 2024 chempedia.info