Reaction cyclone

The fast pyrolysis (flash pyrolysis) of biomass to bio-oil, which has gained attention as a renewable source for fuels or chemicals [78], is such a case (Fig. 15.8). 

The desired primary liquid products of biomass pyrolysis react readily in secondary cracking reactions, shifting the product yield from liquids to gases. Those cracking reactions are assisted by contact of the volatiles to the remaining solids, which can be reduced significantly by running the fast pyrolysis in a reaction cyclone [79, 80]. A simplified flow sheet of such a laboratory plant for the fast pyrolysis of biomass is shown in Fig. 15.9. 

The manner of heat transfer is unusual, as this reaction cyclone is solar-heated. In any other cases, the carrier gas (e.g., nitrogen or product gas from the fast pyrolysis) must be preheated, because the heat transfer by direct contact of the particles to the cyclone wall is poor and only sufficient to keep the reactor at adiabatic conditions. Lede built two different cyclone reactors for experiments on the fast pyrolysis of 

Reactive filters for the removal of reactive solids (i.e., diesel soot) have already passed through the test rig state. For the reactive filtration of diesel soot, industrially manufactured devices are available, but improved reaction kinetics and models predicting accurately the loading and regeneration cycles are yet to be produced. 

Forstner, P. Jacobs, F. v.d. Kammer, Fresenius]. Anal. Chem., 2001, 

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The first case covers for example flue-gas treatment, which requires the filtration of fly-ash and the reduction of NOx, or gasification processes, where particulates and high-boiling tars have to be removed. An example of the second case is that of combustion processes, where incomplete combustion leads to the emission of carbonaceous particulates. The most relevant topic in this category is the reduction of diesel particulate emissions ( diesel soot ) by catalytic filtration. A more exotic example is the reaction cyclone for the thermal conversion of biomass, which also combines chemical reactions and separation in one apparatus, though its separation mechanism is not filtration. 

Fig. 15.9. Pyrolysis of biomass in a solar-heated reaction cyclone (from Ref. [79]).

Fresh butane mixed with recycled gas encounters freshly oxidized catalyst at the bottom of the transport-bed reactor and is oxidized to maleic anhydride and CO during its passage up the reactor. Catalyst densities (80 160 kg/m ) in the transport-bed reactor are substantially lower than the catalyst density in a typical fluidized-bed reactor (480 640 kg/m ) (109). The gas flow pattern in the riser is nearly plug flow which avoids the negative effect of backmixing on reaction selectivity. Reduced catalyst is separated from the reaction products by cyclones and is further stripped of products and reactants in a separate stripping vessel. The reduced catalyst is reoxidized in a separate fluidized-bed oxidizer where the exothermic heat of reaction is removed by steam cods. The rate of reoxidation of the VPO catalyst is slower than the rate of oxidation of butane, and consequently residence times are longer in the oxidizer than in the transport-bed reactor. 

The reaction mixture can either be crystallised, centrifuged, and dried, or spray-dried and cyclone-separated to produce a fine crystalline powder having a particle size of 50 p.m. Metal analysis of the AP produced by this method is reported to be less than 0.02 p.g/g. 

After the SO converter has stabilized, the 6—7% SO gas stream can be further diluted with dry air, I, to provide the SO reaction gas at a prescribed concentration, ca 4 vol % for LAB sulfonation and ca 2.5% for alcohol ethoxylate sulfation. The molten sulfur is accurately measured and controlled by mass flow meters. The organic feedstock is also accurately controlled by mass flow meters and a variable speed-driven gear pump. The high velocity SO reaction gas and organic feedstock are introduced into the top of the sulfonation reactor,, in cocurrent downward flow where the reaction product and gas are separated in a cyclone separator, K, then pumped to a cooler, L, and circulated back into a quench cooling reservoir at the base of the reactor, unique to Chemithon concentric reactor systems. The gas stream from the cyclone separator, M, is sent to an electrostatic precipitator (ESP), N, which removes entrained acidic organics, and then sent to the packed tower, H, where SO2 and any SO traces are adsorbed in a dilute NaOH solution and finally vented, O. Even a 99% conversion of SO2 to SO contributes ca 500 ppm SO2 to the effluent gas. 

The oxide exiting either the Barton or ball mill reactor is conveyed by an air stream to separating equipment, ie, settling tank, cyclone, and baghouse, after which it is stored in large hoppers or dmmmed for use in paste mixing. Purity of the lead feed stock is extremely critical because minute quantities of some impurities can either accelerate or slow the oxidation reaction markedly. Detailed discussions of the oxide-making process and product are contained in references 55—57. 

A salient feature of the fluidized bed reactor is that it operates at nearly constant temperature and is, therefore, easy to control. Also, there is no opportunity for hot spots (a condition where a small increase in the wall temperature causes the temperature in a certain region of the reactor to increase rapidly, resulting in uncontrollable reactions) to develop as in the case of the fixed bed reactor. However, the fluidized bed is not as flexible as the fixed bed in adding or removing heat. The loss of catalyst due to carryover with the gas stream from the reactor and regenerator may cause problems. In this case, particle attrition reduces their size to such an extent where they are no longer fluidized, but instead flow with the gas stream. If this occurs, cyclone separators placed in the effluent lines from the reactor and the regenerator can recover the fine particles. These cyclones remove the majority of the entrained equilibrium size catalyst particles and smaller fines. The catalyst fines are attrition products caused by... 

Formal Diels-Alder additions of dienesters (111,332-335) and dien-ketones (336) to enammes have provided synthetic paths which may be applied to some natural products syntheses. However, a reaction of tetra-cyclone (330) gave only the cyclopentenone, rather than a Diels-Alder adduct. 

Reduction of the catalyst/hydrocarbon time in the riser, coupled with the elimination of post-riser cracking, reduces the saturation of the already produced olefins and allows the refiner to increase the reaction severity. The actions enhance the olefin yields and still operate within the wet gas compressor constraints. Elimination of post-riser residence time (direct connection of the reactor cyclones to the riser) or reducing the temperature in the dilute phase virtually eliminates undesired thermal and nonselective cracking. This reduces dry gas and diolefin yields. 

Since the mid-1980s, FCC technology licensors and a number of oil companies have employed a number of RTD s to reduce non-selective post-riser cracking reactions. Two general approaches have been used to reduce post riser cracking. The most widely used approach is direct connection of the cyclones to the riser and on to the reactor vapor line. The second approach is quenching the reactor vapors downstream of the riser-cyclones (rough-cut cyclones). 

Matsen (1985) pointed out a number of additional problem areas in scale-up such as consideration of particle size balances which change over time due to reaction, attrition and agglomeration. Erosion of cyclones, slide valves and other components due to abrasive particles are important design considerations for commercial units which may not be resolved in pilot plants. 

All the CO resulting from the pseudo solid-solid reaction is conducted, together with entrained char, from the top fluidized section through a constriction, in which the high-velocity gas flow prevents backflow, to a transport combustor, where the CO is burned to C02 with preheated air, along with as much of the char as is called for by heat balance to maintain the endothermic FeO-C reaction. The heated recycled char is separated from the off gas at the top of this transport combustor in a hot cyclone and is returned as a thermal carrier to the lower part of the lowest j igged section, while the hot flue gas from the transport combustor is used to preheat the incoming air in a recuperator. 

Further studies of the reactions of secondary and tertiary phosphites with cyclo-pentadienones have included the keto-cyclone (26), which gives the phosphonates (27) and (28), respectively.18 Ketenphosphoranes (29) have been prepared by the reaction of diphenylcyclopropenone with a variety of tervalent phosphorus compounds.19... 

Tetraphenylcyclopent-3-enone and dimethyl phosphonate are the major products from the base-catalysed reaction of methyl phosphonate with tetra-cyclone.75 A mechanism involving initial hydride transfer from dimethyl phosphinate anion to the ketone followed by kinetically controlled protonation to give (98) is suggested. 

The reaction of dichlorocarbene with the fused-ring cyclone (Scheme 7.15) follows an unusual pathway. After initial reaction at the C=C bond, further attack occurs at the carbonyl group. Ring-opening of the oxirane, followed by decarboxylation (see Section 7.4) leads to the final product in 52% yield [73]. 

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