Purified water evaporator condensate

Evaporation is a quick and efficient means of separating solvents and solutes. It is used in extracting sugar from cane syrup and in purifying salt. The process, when followed by condensation, is called distillation, as you know, and is used to purify water for special purposes. 

Soiar Distiiiation - The process of distilling (purifying) water using solar energy. Water can be placed in an air tight solar collector with a sloped glazing material, and as it heats and evaporates, distilled water condenses on the collector glazing, and runs down where it can be collected in a tray. 

By means of evaporation, dissolved pollution is concentrated with the aim of obtaining distilled purified water from wastewater. In mechanical vapor recompression (MVR), the influent is inserted in the system, where it is distributed across heat elements and as a consequence is partly evaporated. This vapor is compressed by a compressor and is then transported to the inner surface of the heat element where it condenses and is collected. The concentrated wastewater is deposited onto the bottom of the device and is subsequently transported by the concentrate pump, after which the cycle starts all over. The technique is effective (ca. 99%), which is dependent on the influent and the type of pollution. 

The discussion of water systems includes the most basic treatment of raw water supplies to allow them to serve as plant utility water. More advanced treatment to allow higher-grade uses follows. Evaporator process condensate is included as a special grade of purified water. The most detailed discussions are those dealing with cooling water and chilled water. 

Provided a correct design and performance, distillation is a very reliable process. However the apparatus does not tolerate being fed with tap water quahty because calcium, magnesium and silicates would precipitate in the evaporator. In addition volatile components from the tap water could co-distil and condensate in the product water. Examples of those volatile constituents are trihalomethanes, ammonia and carbon dioxide. Therefore the feed water has to be pre-treated. Purified Water Ph. Eur. is suitable as feed water. The chemical and microbiological properties of this water are defined unequivocally. Other non qualified water should not be accepted as feed water for a pharmaceutical distillation apparatus. 

Fig. 38. Caustic purification system a, 50% caustic feed tank b, 50% caustic feed pumps c, caustic feed preheater d, amonia feed pumps e, ammonia feed preheater f, extractor g, trim heater h, ammonia subcooler i, stripper condenser j, anhydrous ammonia storage tank k, primary flash tank 1, evaporator reboiler m, evaporator n, caustic product transfer pumps o, purified caustic product cooler p, purified caustic storage tank q, ammonia stripper r, purified caustic transfer pumps t, overheads condenser u, evaporator v, evaporator vacuum pump w, aqueous storage ammonia tank x, ammonia scmbber y, scmbber condenser 2, ammonia recirculating pump aa, ammonia recycle pump. CW stands for chilled water.

The UCB collection and refining technology (owned by BP Chemicals (122,153—155)) also depends on partial condensation of maleic anhydride and scmbbing with water to recover the maleic anhydride present in the reaction off-gas. The UCB process departs significantly from the Scientific Design process when the maleic acid is dehydrated to maleic anhydride. In the UCB process the water in the maleic acid solution is evaporated to concentrate the acid solution. The concentrated acid solution and condensed cmde maleic anhydride is converted to maleic anhydride by a thermal process in a specially designed reactor. The resulting cmde maleic anhydride is then purified by distillation. 

In a 100-ml flask is placed a mixture of 19.5 g (0.18 mole) of freshly sublimed, pulverized selenium dioxide, 15 g (0.10 mole) of df/-camphor and 15 ml of acetic anhydride. The flask is fitted with a magnetic stirrer and a condenser, and the mixture is heated to 135° on an oil bath with stirring for 16 hours. After cooling, the mixture is diluted with ether to precipitate selenium, which is then filtered off, and the volatile materials are removed under reduced pressure. The residue is dissolved in ether (200 ml), washed four times with 50-ml portions of water and then washed several times with saturated sodium bicarbonate solution (until the washes are basic). The ether solution is finally washed several times with water, then dried, and the ether is evaporated. The residue may be purified by sublimation at reduced pressure or recrystallized from aqueous ethanol (with clarification by Norit, if necessary). The product is yellow, mp 197-199°. 

The carbonyl compound to be reduced (0.1 mole) is placed in a 250-ml round-bottom flask with 13.5 g of potassium hydroxide, 10 ml of 85% hydrazine hydrate, and 1(X) ml of diethylene glycol. A reflux condenser is attached and the mixture is heated to reflux for I hour (mantle). After refluxing 1 hour, the condenser is removed and a thermometer is immersed in the reaction mixture while slow boiling is continued to remove water. When the pot temperature has reached 200°, the condenser is replaced and refluxing is continued for an additional 3 hours. The mixture is then cooled, acidified with concentrated hydrochloric acid, and extracted with benzene. The benzene solution is dried, and the benzene is evaporated to afford the crude product, which is purified by recrystallization or distillation. 

B. 1,4-Cyclohexanedione. The purified 2,5-dicarbethoxy-l,4-cyclohexanedione (170 g., 0.66 mole) (Note 5) and 170 ml. of water are placed in a glass liner (vented) of a steel pressure vessel of 1.5-1. capacity (fitted with a pressure-release valve). The vessel is sealed, heated as rapidly as possible to 185-195°, and kept at this temperature for 10-15 minutes (Note 6). The reaction vessel is immediately removed from the heater, placed in a large tub of ice water, and cooled to room temperature. The gas pressure then is carefully released. The resulting yellow to orange liquid is transferred to a distillation flask with the aid of a minimum volume of ethanol, and most of the water and ethanol is removed under reduced pressure by means of a rotary evaporator. The flask is attached to a short heated column fitted with a short air condenser. The remainder of the water and ethanol is removed under reduced pressure, and the 1,4-cyclohexanedione is distilled, b.p, 130-133° (20 mm.). The product solidifies to a white to pale-yellow solid, m.p. 77-79°, deld 60-66 g. (81-89% yield from 2,5-dicarbethoxy-l,4-cyclohexanedione). The compound may be conveniently recrystallized from carbon tetrachloride (7 ml. per gram of dione) the purified product is obtained as white plates, m.p. 77-79° (90% recovery). 

A solution of product A (0.31 g, 0.5 mmol) and L12C03 (0.15 g, 2.0 mmol) in a mixture of 10 mL ethanol, 26 pL (0.5 mmol) acetonitrile, and 2,4-dimethylpenta-1,3-diene (Aldrich) (0.38 g, 4.0 mmol) is heated at reflux for 4 h in a 100-mL round-bottomed flask with a standard tapered joint. The solvent is evaporated under reduced pressure, and the flask is connected to a short, straight, water-cooled reflux condenser (Fig. 1). The top of the reflux condenser is attached to a high-vacuum pump, and the brown cmde product is purified by sublimation at 80°C and 10 bar. The yellow solid product is collected from the lower end of the reflux condenser. On a larger scale, it is more convenient to extract the dry brown cmde product with diethyl ether, filter the solution through a pad of alumina, evaporate the solvent, and then sublime the product. Yield 95%. 

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