Protective shell/coating

Using this method, homogeneous alloys, segregated alloys, layered bi-metallics, and decorated particles are all readily accessible. An obvious advantage of the precursor concept over the conventional salt-impregnation method is that both the size and the composition of the colloidal metal precursors may be tailored independent of the support. Further, the metal particle surface may be modified by lipophilic or hydrophilic protective shells and coated by intermediate layers, e.g., of oxide. The modification of the precursor by dopants is also possible. 

On the other hand, the interest towards this field is accounted for by the possibility to create polymeric systems, combining the unique properties of low-molecular liquid crystals and high molecular compounds, making it feasible to produce films, fibers and coatings with extraordinary features. It is well-known that the utilization of low-molecular thermotropic liquid crystals requirs special hermetic protective shells (electrooptical cells, microcapsules etc.), which maintain their shape and protect LC compounds from external influences. In the case of thermotropic LC polymers there is no need for such sandwich-like constructions, because the properties of low-molecular liquid crystals and of polymeric body are combined in a single individual material. This reveals essentially new perspectives for their application. 

Figure 11.9 Schematic representation of the SiC>2 nanoparticles prepared by Greenway and coworkers64 for the detection of lipid peroxidation 15 nm Si02 nanoparticles covalently coated with the coumarin dye are embedded in a 100 nm silica protecting shell.

In conclusion, it was found that complexes of poly(ethylene oxide)-h-poly(L-lysine) with retinoic acid with short poly(L-lysine) segments of 18 and 30 monomers form core shell micelles. The cores of the micelles contain a lamellar smectic A-like structure, formed by a poly(L-lysine) retinoate complex, which is surrounded by a corona of poly(ethylene oxide). Although the poly(L-lysine) chains are relatively short, they adopt an a-helical conformation to a pH as low as 9. This effective stabilization of the a-helix structure seems to be due to the formation of a protective surrounding coat of retinoate and a shell of poly(ethylene oxide). 

A combination of AFM, STM and XPS has revealed [14,96] the interaction of platinum hydrosols with oxide (sapphire, quartz) and graphite single crystal substrates. The metal core is immediately adsorbed e.g. on the HOPG surface when dipped into aqueous Pt colloid solutions at 20 °C. As shown in Fig. 2.17, the protecting shell (composed of either residual surfactants or al-organic residues) forms a carpetlike coat which cannot... 

Other encapsulations utilize more or less similar methods for the formation of the capsule wall. Complex coacervation utilizes the reaction of an anionic water-soluble polymer with a cationic material to form the shell wall that separates from the solution. As the coacervate separates from the solution, it will tend to coat suspended particles with a protective shell. The shell wall is then hardened with a cross-linking agent. In situ polymerization is used to form urea formaldehyde or melamine formaldehyde shells by using heat to cross-link the monomers forming the shell waU. Interfacial polymerization with isocyanates via hydrolysis is another method to form a shell wall at an organic-water interface. In this case, water acts to hydrolyze some of the polyisocyanate to an amine, which cross-links to form the polyurea microcapsule waU. 

The synthesis and characterization of the dye-labeled silicone particles with the core-shell architecture was described [18]. In the first step, the chlorobenzyl-functionabzed core was formed via co-condensation of MeSi(OMe)j and trimethoxy-chlorobenzylsilane (ClSi(OMe)3) in the presence of benzetho-nium chloride under basic conditions. Next, a nonfunctional homogeneous shell was formed by the addition of variable amounts of MeSi(OMe)j. The obtained core-shell particles were coated with a hydrophobic surface layer by the end-cap-ping reaction with Me SiOMe and (Me Sil NH, and isolated from the surfactant. This procedure results in the well-defined silicone nanoparticles having a chlorobenzyl-functionahzed core of 10 nm in size that is surrounded with a non-functional-ized protective shell of the thickness in the range 0-3.2 nm. The dye labels (orfho-nitrostilbene (ONS), rhodamine B, coumarin 343, and pyrene) were chemically attached to the core-shell particles by an esterification reaction of the cesium salt of the chromophores with chlorobenzyl functions present in the core. 

Vimses are one of the smallest biological entities (except viroids and prions) that carry all the iaformation necessary for thek own reproduction. They are unique, differing from procaryotes and eucaryotes ia that they carry only one type of nucleic acid as genetic material, which can be transported by the vims from one cell to another. Vimses are composed of a shell of proteki enclosing a core of nucleic acid, either ribonucleic acid (RNA) or deoxyribonucleic acid (DNA), that codes for vkal reproduction. The outer shell serves as a protective coat to keep the nucleic acid kitact and safe from enzymatic destmction. In addition to thek proteki coat, some vimses contain an outer covering known as an outer envelope. This outer envelope consists of a Hpid or polysaccharide material. 

Anode supports, cable insulators and the coating on the object to be protected can be destroyed by anodic evolution of chlorine (see Section 7.1), Only chorine-resistant materials should be used. Anodes on retaining walls or between pile foundations can be installed in perforated or fabricated plastic tubes (half-shells) (see Fig. 16-8). They must naturally be provided with very many holes to avoid uneven removal of anode material. Filter tubes of a chlorine-resistant special material or... 

The modern motor car is made from steel, zinc or zinc alloy-coated steel and some plastic parts, all of which require painting. The main component is the body shell, made from the above metals, and this is coated in a continuous production process. A full finishing system with all four coatings is usually applied for maximum protection and a high quality appearance. 

A final category of encapsulating materials consists of reaction products of the nucleus material and a reagent. For example, pellets of nitronium perchlorate have been encapsulated in shells of the less reactive amm perchlorate (AP) by exposing the pellets to ammonia gas. The fragile AP shells were usually further protected by a top-coating of A1 or a polymer film (Ref 2). The most familiar example of this process is the natural one wherein A1 powders (or articles) become coated with a protective coating of A1 oxide thru exposure to atmospheric air... 

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