Processing, thermoplastics blown film extrusion

Extrusion is a cost effective manufacturing process. Extrusion is popularly used in large scale production of food, plastics and composite materials. Most widely used thermoplastics are processed by extrusion method. Many biopolymers and their composite materials with petroleum-based polymers can also be extruded. These include pectin/starch/poly(vinyl alcohol) (Fishman et al. 2004), poly(lactic acid)/sugar beet pulp (Liu et al. 2005c), and starch/poly(hydroxyl ester ether) (Otey et al. 1980), etc. In this study, composite films of pectin, soybean flour protein and an edible synthetic hydrocolloid, poly(ethylene oxide), were extruded using a twin-screw extruder, palletized and then processed into films by compression molding process or blown film extrusion. The films were analyzed for mechanical and structural properties, as well as antimicrobial activity. 

Thermoplasticity. High molecular weight poly(ethylene oxide) can be molded, extruded, or calendered by means of conventional thermoplastic processing equipment (13). Films of poly (ethylene oxide) can be produced by the blown-film extrusion process and, in addition to complete water solubility, have the typical physical properties shown in Table 3. Films of poly(ethylene oxide) tend to orient under stress, resulting in high strength in the draw direction. The physical properties, melting behavior, and crystallinity of drawn films have been studied by several researchers (14—17). 

THV Fluoroplastic can be processed by virtually any method used generally for thermoplastics, including extrusion, coextrusion, tandem extrusion, blown film extrusion, blow molding, injection molding, vacuum forming, and as skived film and solvent casting (only THV-220). 

Film blowing (blown-film extrusion). The process of forming thermoplastic film wherein an extruded plastic tube is continuously inflated by internal air pressure, cooled, collapsed by rolls, and subsequently wound into rolls on thick cardboard cores. The tube is usually extruded vertically upward, and air is admitted through a passage in the center of the die as the molten tube emerges from the die. An air... 

The serendipitous discovery of polytetrafluoroethylene (PTFE) in 1938 by Roy J. Plunkett [82] and his co-workers at DuPont research laboratories has spurred the development of a variety of fluorine containing polymers, which include fluorosilicones, fluorinated polyurethanes, fluorinated thermoplastic elastomers, etc.. Many of the commercial fluoropolymers are suitable for melt processing via conventional injection molding, screw extrusion and blown film extrusion techniques. 

PLA and PHB may be processed because of their thermoplastic properties in the usual thermoplastic processing systems by using extrusion, injection molding, melt spinning, blowing film, and melt-blown techniques. 

Coextrusion is the process of forming an extru-date composed of more than one thermoplastic melt stream. The process came about because some service demands, particularly from the packaging industry, could not be satisfied by a single polymer although they could be met by a combination of polymers. Coextrusion was first practiced in the production of cast film and is now also used in blown film and sheet extrusion. The intention is normally to produce a laminar structure in which each layer contributes a key property to the overall product performance. Coextruded films may be very complex structures composed of many different functional layers, including tie layers whose purpose is to bond neighboring layers of limited compatibility. Five layers are not uncommon. However, side-by-side coextrusion is also possible. Fluoroplastics can be coextmded with other polymers such as ETFE and nylon. 

In particular the NMMO technology has inspired new developments, recognizing that the cellulose/NMMO/water solution can be considered in many aspects as a melt. As an example, cellulose has been shaped by a blown-film process similar to conventional thermoplastics [33,34]. A schematic of the blow-extrusion process is shown in Figure 3.8. 

TPE sheet can be produced (e.g., from TPVs) by extrusion processing. Sheet extrusion of TPEs can produce thicknesses from about 0.2 to 4 mm and widths of 2 m or more. Very thin TPE sheeting can be produced by the blown film process used for many thermoplastics. This technique allows hard TPE sheet to be made down to a thickness as low as 0.05 mm, and even soft TPEs can yield sheets 0.2 mm thick. 

Films made from LCP and LCP-thermoplastic blends have been made using the blown film process [6,10,11,15-17], combined with a counter-rotating die. This process provides for multiaxial orientation of the LCP through controlled shear forces in the die prior to extrusion from the lips. Then, after extrusion from the die, the semi-molten LCP film tube is simultaneously stretched in the longitudinal (machine) direction and the circumferential (transverse) direction. The die shear and stretching were discussed previously in section 3. 

Virtually every polymer can be used in film form. Most thermoplastic polymer films are prepared by conventional extrusion techniques based on calendering, casting, and blown-film, or tenter-film systems. Other polymers, which cannot be easily melted, are formed into films by solvent casting. In the selection of a film for a particular application, the properties of the poljuneric materials must be considered in view of the application. Thermal properties, molecular characteristics, and crystallinity of the polymer affect processing and film properties. Additives influence extrusion and orientation processes and improve film properties. 

Poly(butylene succinate) can be molded on conventional thermoplastic processing equipment, including blown film, mono-filament extrusion, blow molding, and injection molding. PBS pellets should be dried to a water content of less than 0.1% to prevent hydrolysis (Xu and Guo... 

An early description of the cast film process was published in Modem Plastics in 1952 [26] which was very similar to the cast-film scheme shown in Figure 6.19 which represents the process used today. The cast film process involves the extrusion of polyethylene through a die to form a thin molten layer of material that is drawn down to a thinner gauge based on the difference between the rate the molten polymer exits the extruder and the rate that the molten polymer is cooled onto a chill roll. The film cools very rapidly on the chill roll and film orientation is only in the machine direction. Optical properties are usually better with cast film as compared to blown film and line rates may be higher with the cast film process. A cast film line may also involve coextrusion of several layers of different types of thermoplastics to fabricate specialty films with improved properties. A... 

PBS is a typical thermoplastic and can be processed via various methods, such as extrusion, injection molding, film blowing, fiber spinning, and thermoforming. It has been reported that PBS can be processed into melt-blown, multifilament, monofilament, nonwoven, flat and split yarn, injection-molded products, film, paper laminate, sheet, and tape for applications in the textile and plastic industries. 

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