Process corrosion monitoring

Corrosion product. Rust, oxide, or other result of corrosion process. Corrosion monitor ... 

Use of Corrosion Probes The major use of corrosion monitoring probes is to measure the corrosion rate in the plant or the field. In addition to corrosion-rate measurements, corrosion probes can be used to detect process upsets that may change the corrosion resistance of the equipment of interest. This is usually equally as important a measurement as corrosion rate since a change in the process conditions can lead to dramatic changes in the corrosion rate. 

A number of corrosion-monitoring techniques based on electrochemical principles are available. These give an indication of the instantaneous corrosion rate, which is of use when changing process conditions create a variety of corrosion effects at different times in a plant. Some... 

A factor which previously limited installation of automatic corrosion monitoring systems was the cost of cabling between sensors and control room instrumentation-this was particularly relevant to the electrical resistance (ER) systems. Developments to overcome this have included transmitter units at the probe location providing the standard 4-20 mA output (allowing use of standard cable) for onward transmission to data systems or the use of radio linkage which has been successfully used for other process-plant instrumentation. 

The ER system has been used successfully in a range of industries for process plant monitoring. As ER can be applied in any liquid or gaseous environment the areas of application are considerable. However, there is a problem with ER if a conductive corrosion product is produced as is the case with sour crude oil or gas due to the deposition of iron sulphide. 

The availability of probes that can be welded to the outer walls of piping or process vessels providing on-line thickness measurement is an interesting development which would seem to bridge the technologies of corrosion monitoring and inspection". 

Anon, On-Line Monitors Attack Process Corrosion , Processing, 34, 34-35, February (1986)... 

Richardson, J. A., Innovations in Techniques for Corrosion Monitoring , Conf. Advances in Materials Technology for Process Industries Needs, Atlanta (1984)... 

Hladky, K. and John, D.G., Corrosion Monitoring Using Electrochemical Noise , 2nd. Int. Conf. on Corrosion Monitoring and Inspection in the Oil, Petrochem. and Process Industries, London, Oyez Scientific and Technical Services Ltd., London (1984)... 

Corrosion Monitoring and Inspection in the Oil, Petrochemical and Process Industries , Proc. 

Conference, February 1984, Oyez Scientific and Technical Services, London Corrosion Monitoring in the Oil, Petrochemical and Process Industries , J. Wanklyn, (ed.), Proc. Conference, Oyez Scientific and Technical Services, London (1982)... 

Electrochemical On-Line Corrosion Monitoring On-line corrosion monitoring is used to evaluate the status of equipment and piping in chemical process industries (CPI) plants. These monitoring methods are based on electrochemical techniques. To use on-line monitoring effectively, the engineer needs to understand the underlying electrochemical test methods to be employed. This section covers many of these test methods and their applications as well as a review of potential problems encountered with such test instruments and how to overcome or avoid these difficulties. 

Some data from corrosion-monitoring probes do not measure corrosion rate, but rather give other useful information about the system. For example, suppose conditions change dramatically during a process upset. An ejq)erienced corrosion engineer can examine the data and correlate it with the upset conditions. Such analysis can provide insight into the process and help to improve performance and extend equipment lifetime. Changes in simple parameters such as pH, ion content, and temperature may lead to detection of a process upset. Without careful analysis, process upsets can reduce the corrosion lifetime of equipment and even cause a system failure. 

It can be concluded that selection of proper material or lining for seawater application is important and depends on the criticality of the system, availability of standby system/equipment and availability of isolation devices for maintenance. For process piping in seawater application the success of proper lining or coating material depends on the suitability for in-situ/field application and the proper corrosion monitoring plan. 

Infrared thermographic techniques can be used to identify hot spots on process equipment The camera works on the theory that the hotter the object, the higher the frequency of radiation. For off-line corrosion monitoring, horoscopes for inspecting tubes, pumps, compressors, and other equipment may be used. Spot chemical testing can indicate the... 

Waterside problems that lead to decreases in efficiency and material deterioration can be caused by a variety of mechanisms, such as electrochemical corrosion and deposition of foulants. These problems can be exacerbated by low flow, poor operational practice, process contamination, or specific stresses. It is also important to try to determine cause and effect relationships in order to provide a logical and practical water treatment solution. Such a solution will usually involve some form of cleaning, plus a combined engineering and chemical action plan. Inspection may be made easier by the use of a Boroscope or similar optical/video recording device. The color, texture, and quantity of all deposits should be noted, measurements of pits taken, and microbiological contaminants analyzed. It may be useful to conduct biocide efficiency tests on bacterial slimes. The period when a heat exchanger is open for inspection may be an opportune time for the permanent installation of ports for corrosion-monitoring probes. 

Metal Samples. Corrosion Monitoring Products for Industrial Processing and Water Treatment. Promotional literature, Metal Samples, USA. 

Using AW devices to monitor dynamic processes such as diffusion and corrosion can dramatically reduce the time required to quantify these processes. For example, as discussed in Section 4.2.2, diffusion equilibration times typically increase with the square of the diffusional length. For a thin film, this length scale, the film thickness (h), is very small. This enables the quantification of diffusion coefficients as low as 10 cm /sec in less than one day, whereas months would be required using many conventional techniques that use thick films or bulk samples. For corrosion monitoring, the dramatic decrease in mass detection limits obtainable using coated AW devices, as compared with conventional balances and sample coupons, allows detectable mass changes to be achieved in minutes or hours rather than days or months (Section 4.4.3). 

These results demonstrate that acoustic wave sensors can be used as real-time corrosion monitors. Their small size enables them to be used in situ in corrosive process environments or as a component to warn of the impending failure of a... 

Systematic waii thickness and corrosion monitoring of storage tanks and process vesseis ... 

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