Printing ink radiation

Chem. Descrip. Amorphous hydrated siiica CAS 7631-86-9 EINECS/ELINCS 231-545-4 Uses Matting agent in soivent- and water-borne architectural paints, board, coii and can coatings (< 0.75 mii), eiectrocoat primers, general industrial coatings, water-based coatings, printing inks, radiation-cured systems (< 0.75 mii), vinyi topcoats Features Med. porosity... 

Trapped radicals on samples with different storage conditions and reaction conditions are usually determined by ESR. Modification of PVC by radiation-grafting technique is an attractive method to improve the mechanical strength, printing ink adhesion, and adhesive receptance. Wang... 

EB radiation-cured PVC film surface induces a big improvement in tensile strength and excellent printing ink adhesion and adhesive receptance [302]. PVC foams containing plasticizers, thermally activated blowing agents, cross-linkers, and heat stabilizers have been manufactured by EB radiation technology [303]. 

Feller, R. L., "Cross-Linking of Methacrylate Polymers by Ultraviolet Radiation", Preprints of papers presented at the New York Meeting, Division of Paint, Plastics and Printing Ink Chemistry, American Chemical Society, Sept., 1957, 17, No. 2, 465-470. 

Radiation-curable epoxy acrylates, 10 450 Radiation cures, silicone network preparation via, 22 567-569 Radiation curing coatings, 7 133-135 of printing inks, 14 314 Radiation damage, ion implantation and, 14 435-436 Radiation drying coatings, 7 29-30 Radiation effects... 

Carbon black includes several forms of artificially prepared carbon, such as furnace black, channel black, lamp black, and animal charcoal. It is a finely divided form of carbon consisting of particles of extremely fine size. It is obtained by partial combustion (in 50% required air) of vapors of heavy oil fraction of crude oil in a furnace or by thermal cracking of natural gas. Carbon black is used in many abrasion-resistant rubber products including tire treads and belt covers. It also is used in typewriter ribbons, printing inks, carbon paper, and paint pigments. It also can be an absorber for solar energy and UV radiation. 

Glockner, R, Jung, T., Struck, S., and Studer, K., Radiation Curing Coatings and Printing Inks (European Tech Files), Vincentz Network, Hannover (2008). 

Photochromism is a reversible transformation of a single chemical species between two states, the absorption spectra of which are clearly different, the transition in at least one direction being induced by electromagnetic radiation [1], The widest and most important group of the photochromic system is based on electrocyclic reactions [2,3] a few have been commercially successful (polymer-based photochromic eyewear, novelty items and security printing inks). Several other photochromic systems based on E,Z-isomerization, cycloaddition reaction, electron or proton transfer have potential industrial applications [4],... 

Set-off can be avoided by the use of anti-set-off compoimds. These are spray powders that reduce the frictional contact between the sheets. Materials like silica and starch, which have a particle diameter slightly greater than the printed ink film thickness, can be used. Slow setting problems may be reduced by the use of less solvent or by a higher ratio of resin to oil. Varnishing with a formula that utilises polymerisation induced by radiation is another way to avoid set-off. The varnish covers the printed surface and direct contact between the layer of print and the iimer food contact surface of the substrate is avoided. 

In another commercial application of free-radical polymerization, polymerizations may be carried out in industrial coatings in the presence of air to yield a variety of coatings and structures of commercial import. This development is possible. In part, because certain vinyl monomers, particularly the acrylates, are less sensitive to retardation by oxygen compared with other monomers. It is therefore possible to produce radiation-cured coatings. UV-cured printing inks and the photopolymers are important in imaging for printing, photoresist, and related applications. 

Radiation-Curable Polyester Coatings. Radiation-curable polyester paints (see also Section 3.7) are particularly suitable for coating flat surfaces (strips, boards, sheets) and for temperature-sensitive substrates (paper, plastics). Acrylate-modified polyester resins are used for UV printing inks, UV varnishes for paper and plastics, as well as for pigmentable, electron beam-curable gloss and matt paints [2.86]. Radiation-curable polyester paints are also suitable for metal coatings with good elasticity. 

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