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Potential Contributions

Intra-atomic matrix elements, or on-site tenns, with / = m.. Traditionally, the potential contributions... [Pg.2204]

Another troublesome aspect of the reactivity ratios is the fact that they must be determined and reported as a pair. It would clearly simplify things if it were possible to specify one or two general parameters for each monomer which would correctly represent its contribution to all reactivity ratios. Combined with the analogous parameters for its comonomer, the values rj and t2 could then be evaluated. This situation parallels the standard potential of electrochemical cells which we are able to describe as the sum of potential contributions from each of the electrodes that comprise the cell. With x possible electrodes, there are x(x - l)/2 possible electrode combinations. If x = 50, there are 1225 possible cells, but these can be described by only 50 electrode potentials. A dramatic data reduction is accomplished by this device. Precisely the same proliferation of combinations exists for monomer combinations. It would simplify things if a method were available for data reduction such as that used in electrochemistry. [Pg.444]

In Figure 5, the heat of adsorption of CO2 increases slightly at the higher adsorbate loadings. This increase is due to the increasing self-potential contribution at the higher loadings. [Pg.273]

The use of flame retardants came about because of concern over the flammabiUty of synthetic polymers (plastics). A simple method of assessing the potential contribution of polymers to a fire is to examine the heats of combustion, which for common polymers vary by only about a factor of two (1). Heats of combustion correlate with the chemical nature of a polymer whether the polymer is synthetic or natural. Concern over flammabiUty should arise via a proper risk assessment which takes into account not only the flammabiUty of the material, but also the environment in which it is used. [Pg.465]

U.S. capacity for producing biofuels manufactured by biological or thermal conversion of biomass must be dramatically increased to approach the potential contributions based on biomass availabiUty. For example, an incremental EJ per year of methane requires about 210 times the biological methane production capacity that now exists, and an incremental EJ per year of fuel ethanol requires about 14 times existing ethanol fermentation plant capacity. [Pg.13]

Soot. Emitted smoke from clean (ash-free) fuels consists of unoxidized and aggregated particles of soot, sometimes referred to as carbon though it is actually a hydrocarbon. Typically, the particles are of submicrometer size and are initially formed by pyrolysis or partial oxidation of hydrocarbons in very rich but hot regions of hydrocarbon flames conditions that cause smoke will usually also tend to produce unbumed hydrocarbons with thek potential contribution to smog formation. Both maybe objectionable, though for different reasons, at concentrations equivalent to only 0.01—0.1% of the initial fuel. Although thek effect on combustion efficiency would be negligible at these levels, it is nevertheless important to reduce such emissions. [Pg.530]

Skin" Notation-. The designation "skin" refers to the potential contribution to the overall exposure by the cutaneous route, including mucous membranes and eyes, either by airborne, or more particularly by direct, contact with the substance. Examples of such substances are phenol (cresol and cumene), hydrogen cyanide, and mercury. The "skin" notation is intended to make known the need to prevent cutaneous absorption so that the TLV is not violated. [Pg.258]

Discuss the potential contributions to hydrophobic and van der Waals interactions and ionic and hydrogen bonds for the side chains of Asp, Leu, Tyr, and His in a protein. [Pg.207]

In chloroplasts, the value of AT is typically —50 to —100 mV, and the pH gradient is equivalent to about 3 pH units, so that — (2.3 i T/S ) ApH = —200 mV. This situation contrasts with the mitochondrial proton-motive force, where the membrane potential contributes relatively more to bsp than does the pH gradient. [Pg.727]

Moreover, there are COX-independent effects of NSAIDs potentially contributing to the activity of NSAIDs [2]. [Pg.872]

The potential contribution of water reuse to the integrated management of water resources still remains considerably undeveloped, though a wide range of rehable, efficient and cost effective technical solutions are available for each t3q>e of reuse application. [Pg.104]

Releases to the atmosphere from production facilities and disposal sites have also been reported. Studies have shown that releases of methyl parathion to the atmosphere occur in the vicinity of pesticide-producing factories. At two predominately downwind sites located 1 mile from a plant producing methyl parathion, average monthly concentrations were <0.57 and <0.64 ng/m (Foster 1974). Air emissions from methyl parathion production facilities have been reported to contain 1.0 kg/1,000 kg pesticide produced. In addition, evaporation from holding ponds for pesticide waste potentially contributes 7.4 mg/1,000 kg pesticide produced to the atmosphere (EPA 1978d). [Pg.147]

Research Management Views on Improvement, Organizational Learning, and the Potential Contribution of IT Support... [Pg.247]

RESEARCH MANAGEMENT VIEWS ON IMPROVEMENT, ORGANIZATIONAL LEARNING, AND THE POTENTIAL CONTRIBUTION OF IT SUPPORT... [Pg.259]

Larrue V, von Kummer R, del Zoppo G, Bluhmki E. Hemorrhagic transformation in acute ischemic stroke. Potential contributing factors in the European Cooperative Acute Stroke Study. Stroke. 1997 28 957-960. [Pg.57]

When the Dixie site is compared to the reference area, proximity to the smelter (within 0.5 mile) contributed 1.85 pg/dl to the mean blood-lead level. The potential contribution of traffic density could not be determined because of the configuration of the roadway and the distance of the roadway from the smelter site. Although an elevated mean blood-lead level was found for children living close to the Dixie site, the increase was not as great as observed in the RSR site and the few children found to have lead toxicity, as defined previously, appear to have lead exposure due to occupation of parents. [Pg.66]

This chapter addresses (1) the mechanisms, antioxidant defences and consequences in relation to free-radical production in the inflamed rheumatoid joint (2) lipid abnormalities in RA (3) the potential contribution of ox-LDL to RA (the role of ox-LDL in coronary heart disease is discussed in Chapters 2 and 3 and will not be fully discussed here) and (4) the therapeutic aspects of chain-breaking antioxidant interventions in RA. [Pg.98]

Replacing an a-alkyl snbstituent by an a-aryl group is expected to stabilize the cationic center by the p-Jt resonance that characterizes the benzyl carbocations. In order to analyze such interaction in detail, the cumyl cation was crystallized with hexafluoroantimonate by Laube et al. (Fig. 13) A simple analysis of cumyl cation suggests the potential contributions of aromatic delocalization (Scheme 7.3), which should be manifested in the X-ray structure in terms of a shortened cationic carbon—aromatic carbon bond distance (C Cat). Similarly, one should also consider the potential role of o-CH hyperconjugation, primarily observable in terms of shortened CH3 distances. Notably, it was found experimentally that the Cai distance is indeed shortened to a value of 1.41 A, which is between those of typical sp -sp single bonds (1.51 A) and sp -sp double bonds (1.32 A). In the meantime, a C -CH3 distance of 1.49 A is longer than that observed in the tert-butyl cation 1 (1.44 A), and very close to the normal value for an sp -sp single bond. [Pg.279]

Where does nonproliferation stand in the myriad of institutional, regulatory, public acceptance, economic and, at times, even technical problems now affecting the future of the nuclear option Is the potential contribution of nuclear power activities to further proliferation seen by policy makers and, of equal importance, the public as a significant obstacle to its revival Or is it viewed as a potential benefit capable of reducing proliferation risks. [Pg.116]

Doses of chlorpyrifos in human volunteers were also estimated using physical measurements. Air sampling was conducted in order to estimate the inhalation dose to each volunteer. Dislodgeable residues were also measured throughout the study to estimate the dermal contribution to total dose. Finally, hand rinses were conducted on each volunteer immediately following the 4-hr activity period to assess the potential contribution to total dose from hand exposure and to estimate an oral dose to a crawling child. [Pg.51]


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See also in sourсe #XX -- [ Pg.256 ]




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