Polyethylene, HDPE

Ffigh-density polyethylene (HDPE) Thermoplastic elastomers... 

There are three basic types of polyethylene foams of importance (/) extmded foams from low density polyethylene (LPDE) (2) foam products from high density polyethylene (HDPE) and (J) cross-linked polyethylene foams. Other polyolefin foams have an insignificant volume as compared to polyethylene foams and most of their uses are as resia extenders. 

Plastic materials represent less than 10% by weight of all packagiag materials. They have a value of over 7 biUion including composite flexible packagiag about half is for film and half for botties, jars, cups, tubs, and trays. The principal materials used are high density polyethylene (HDPE) for botties, low density polyethylene for film, polypropylene (PP) for film, and polyester for both botties and films. Plastic resias are manufactured by petrochemical companies, eg. Union Carbide and Mobil Chemical for low density polyethylene (LDPE), Solvay for high density polyethylene, Himont for polypropylene, and Shell and Eastman for polyester. 

High density polyethylene (HDPE) is defined by ASTM D1248-84 as a product of ethylene polymerisation with a density of 0.940 g/cm or higher. This range includes both homopolymers of ethylene and its copolymers with small amounts of a-olefins. The first commercial processes for HDPE manufacture were developed in the early 1950s and utilised a variety of transition-metal polymerisation catalysts based on molybdenum (1), chromium (2,3), and titanium (4). Commercial production of HDPE was started in 1956 in the United States by Phillips Petroleum Company and in Europe by Hoechst (5). HDPE is one of the largest volume commodity plastics produced in the world, with a worldwide capacity in 1994 of over 14 x 10 t/yr and a 32% share of the total polyethylene production. 

The chemical iadustry manufactures a large variety of semicrystalline ethylene copolymers containing small amounts of a-olefins. These copolymers are produced ia catalytic polymerisation reactions and have densities lower than those of ethylene homopolymers known as high density polyethylene (HDPE). Ethylene copolymers produced ia catalytic polymerisation reactions are usually described as linear ethylene polymers, to distiaguish them from ethylene polymers containing long branches which are produced ia radical polymerisation reactions at high pressures (see Olefin POLYMERS, LOWDENSITY polyethylene). 

With a simple parison, the large-diameter sections of the botde have a thin wall and the small-diameter sections have a thick wad. Certain modifications of the die can control the thickness of the parison wad along its length, which results in a bottle with improved wad thickness distribution and better strength. High density polyethylene (HDPE) is the most common blow mol ding resin used to produce containers ranging in size from 30 cm to 200 L. 

In 1971 a metal-backed polyethylene acetabular cup was introduced. This cup provided an eccentric socket which was replaceable, leaving the metal and replacing only the polyethylene. Because of the success of this component, metal-backed high density polyethylene (HDPE) liner is standard for prosthetic acetabular components. Research confirms that metal-backing reduces the peak stresses in the bone cement, and that HDPE forms a successfiil articulating surface for the prosthetic joint. 

Nor is it tme that poly(ethylene terephthalate) (PET) and high density polyethylene (HDPE) packaging are hsted as 1 and 2 in the Society of the Plastics Industry (SPI) recycling coding system because they are the most recyclable. The numbers assigned to each plastic in the SPI coding system are purely arbitrary and do not redect the material s recyclabihty. 

Ref. 136. LDPE = low density polyethylene HDPE = high density polyethylene PP = polypropylene PS = polystyrene EPVC = flexible PVC ... 

High Density Polyethylene. High density polyethylene (HDPE), 0.94—0.97 g/cm, is a thermoplastic prepared commercially by two catalytic methods. In one, coordination catalysts are prepared from an aluminum alkyl and titanium tetrachloride in heptane. The other method uses metal oxide catalysts supported on a carrier (see Catalysis). 

Low pressure (0.1 to 20 MPa) and temperatures of 50 to 300°C using heterogeneous catalysts such as molybdenum oxide or chromium oxide supported on inorganic carriers to produce high density polyethylene (HDPE), which is more linear in nature, with densities of 0.94 to 0.97 g/cm. ... 

High Density Polyethylene (HDPE). This material has a density in the range 935-965 kg/m and is more crystalline than LDPE. It is also slightly more... 

Figure 15 Typical gel permeation chromatograms of polyethylenes (HDPEs). (-(—) new generation super flow resin. Source Ref. 116.

High-pressure polymerization of ethylene was introduced in the 1930s. The discovery of a new titanium catalyst hy Karl Ziegler in 1953 revolutionized the production of linear unhranched polyethylene at lower pressures. The two most widely used grades of polyethylene are low-density polyethylene (LDPE) and high-density polyethylene (HDPE). Currently,... 

High-density polyethylene (HDPE) is produced by a low-pressure process in a fluid-bed reactor. Catalysts used for HDPE are either of the Zieglar-type (a complex of A1(C2H5)3 and a-TiCl4) or silica-alumina impregnated with a metal oxide such as chromium oxide or molybdenum oxide. 

Dow ABS Nylon 6/6 Polycarbonate Polyethylene, HDPE, LDPE, LLDPE, ULDPE Polypropylene HPPP, CPPP Polystyrene HIPS, GPPS, Recycled, Advanced Styrenic Resin SAN Polyurethane Elastomers Polyolefin Plastomer PC/ABS Crystalline Polymer ABS/TPU... 

FIGURE 11.22 Variation of melt viscosity with shear rate for GR high-density polyethylene (HDPE). (From Yanez-Flores, G., Ramos De-Valle, F.F., and Rodriguez-Femandez, O.S., Proceedings of the Society of Plastics Engineers Annual Technical Conference, 1997, p. 381.)... 

Low-density polyethylene (LDPE) film for food packaging, etc. High-density polyethylene (HDPE) blow molded into bottles and containers... 

In this study, post-synthetic metal grafting was used to incorporate A1 into MCM-41 (Al-MCM-41-P), which was probably the first attempt at the catalytic degradation of waste plastics. The objective of this study was to investigate the kinetic aspect of high-density polyethylene (HDPE) over Al-MCM-41-P. 

The metal catalyzed production of polyolefins such as high density polyethylene (HDPE), linear low density polyethylene (LLDPE) and polypropylene (PP) has grown into an enormous industry. Heterogeneous transition metal catalysts are used for the vast majority of PE and all of the PP production. These catalysts fall generally within two broad classes. Most commercial PP is isotactic and is produced with a catalyst based on a combination of titanium chloride and alkylaluminum chlorides. HDPE and LLDPE are produced with either a titanium catalyst or one based on chromium supported on silica. Most commercial titanium-based PE catalysts are supported on MgCl2. 

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