Polyolefin plastomers

Dow ABS Nylon 6/6 Polycarbonate Polyethylene, HDPE, LDPE, LLDPE, ULDPE Polypropylene HPPP, CPPP Polystyrene HIPS, GPPS, Recycled, Advanced Styrenic Resin SAN Polyurethane Elastomers Polyolefin Plastomer PC/ABS Crystalline Polymer ABS/TPU... 

In addition to the two-phase TPEs, two new technologies have emerged. They are the metallocene-catalyzed polyolefin plastomers (POPs, the name given to Exxon s EXACT product line) and polyolefin elastomers (POEs, DuPont Dow Elastomer s ENGAGE), and reactor-made thermoplastic polyolefin elastomers (R-TPOs). These new types of TPEs are often called metallocene elastomers-TPEs (MEs-TPEs) [87]. The new POPs and POEs are essentially very low-molecular-weight-Unear low-density PEs (VLMW-LLDPE). These new-generation TPEs exhibit mbber-like properties and can be processed on... 

Woods, S. S. and Pocius, A. V., The Influence of Polymer Processing Additives (PPAS) on the Surface and Optical Properties of Polyolefin Plastomer Blown Eilm, SPEANTEC Tech. Papers, 46, 191 (2000)... 

Eaves (92) distinguished between polyolefin plastomers (POP) with density >910 kg m and polyolefin (POE) elastomers with densities <910 kg m-3. The density of a polyethylene at 20 °C is a linear function of the crystallinity, with limiting values of 854 kg m 2 for zero crystallinity and 1000 kg m for 100% crystallinity. The polyolefin elastomer foams compete with EVA copolymer foams. Metallocene chemistry also allows the production of copolymers with a larger comonomer content in the high molecular weight part than in the low molecular weight part this... 

POE and polyolefin plastomers (POP) are ethylene alpha olefin copolymers produced using constrained geometry and metallocene catalyst. They differ from traditional polyolefins in that they have narrow molecular weight distribution and a regular placement of the octene co-monomer on the ethylene backbone. This highly uniform distribution allows for some unique plastic characteristics. 

The new single-site metallocene technology can be employed to yield new polyolefin materials (polyolefin plastomers (POP) and polyolefin elastomers (POE)) as noted by Schwank in the above noted reference. POP and POE materials are based on ethylene-octene copolymers and should show promise in various future blend combinations. 

Two important types of elastomeric polyolefin blends are reactor-made iPP/ EPR blends and postreactor blend iPP/EPDM. The latter is called thermoplastic vulcanizates (TPVs), produced by dynamic vulcanization of blends containing a thermoplastic and an elastomer. To make iPP/EPDM TPV, the two polymers PP and EPDM are mixed with curatives, such as peroxides, phenolic resins, or sulfur with accelerators, and dynamically cured in an extmder resulting in a blend consisting of micrometer-sized elastomer particles dispersed in the PP matrix (20-24). Paraffinic oils are added in the melt mixing process for viscosity control and cost. In iPP/ EPDM TPV, the crystalline iPP resin is normally the minor phase. Recently, polyolefin plastomers have been added to the class of elastomeric polyolefin blends. Polyolefin plastomers are ultralow molecular weight linear low density polyethylenes (ULMW-LLDPE). Nonelastomeric polyolefin blends are blends of polyolefins with mostly nonpolyolefin (other thermoplastic) matrices as mentioned earlier. 

The CG catalysts produce highly processable polyolefins with a unique combination of narrow MWD and long chain branches. Ethylene-octene copolymers produced with CG catalysts have useful properties across a range of densities and melting indexes. These novel copolymer families are called polyolefin plastomers (POP) and polyolefin elastomers (POE). POPs possess plastic and elastic properties while POEs containing greater than 20 wt% octene comonomer units have higher elasticity. 

MAP See polyolefin plastomer plastic, marbleizing See screw marbleizing. 

ACRONYMS, ALTERNATIVE NAMES mLLDPE, metallocene PE, single site catalyzed LLDPE (SSC), polyolefin plastomers (POP), homogeneous ethylene copolymers... 

General Description Dow Chemicals Affinity resins, homogenous ethylene alpha-olefin copolymers, contain up to 20% octene comonomer. Affinity polyolefin plastomers (POPs) can be used in any of the extrusion technologies as a sealant, to deliver an unparalleled combination of low seal-initiation temperature, hot-tack strength, toughness, tear resistance, and transparency.f ... 

Polyolefin Plastomers Polyolefin Plastomers are elas-tomerie polymers made of polypropylene and ethylene-propylene diene rubber. In general, a plastomer provides an exeellent combination of mechanical, thermal, and chemical properties expected of conventional thermoset rubber. 

Affinity Polyolefin Plastomers, supplier marketing literature (305-01953-893 SMG) - Dow Chemical Company, 1993. (http //www.dow.com/polyethyl-ene/na/products/affin. htm)... 

---