Aluminum poisoning

Lead—antimony or lead—arsenic ahoys must not be mixed with lead—calcium (aluminum) ahoys in the molten state. Addition of lead—calcium—aluminum ahoys to lead—antimony ahoys results in reaction of calcium or aluminum with the antimony and arsenic to form arsenides and antimonides. The dross containing the arsenides and antimonides floats to the surface of the molten lead ahoy and may generate poisonous arsine or stibine if it becomes wet. Care must be taken to prevent mixing of calcium and antimony ahoys and to ensure proper handling of drosses. 

The third control is by use of a fixed burnable poison. This consists of rods containing a mixture of aluminum oxide and boron carbide, included in the initial fuel loading using the vacant spaces in some of the fuel assembhes that do not have control clusters. The burnable poison is consumed during operation, causing a reactivity increase that helps counteract the drop owing to fuel consumption. It also reduces the need for excessive initial soluble boron. Other reactors use gadolinium as burnable poison, sometimes mixed with the fuel. 

These are made of boron carbide ia a matrix of aluminum oxide clad with Zircaloy. As the uranium is depleted, ie, burned up, the boron is also burned up to maintain the chain reaction. This is another intrinsic control feature. The chemical shim and burnable poison controls reduce the number of control rods needed and provide more uniform power distributions. 

Shipment nd Stora.ge, Sulfur monochloride is minimally corrosive to carbon steel and iron when dry. If it is necessary to avoid discoloration caused by iron sulfide formation or chloride stress cracking, 310 stainless steel should be used. Sulfur monochloride is shipped in tank cars, tank tmcks, and steel dmms. When wet, it behaves like hydrochloric acid and attacks steel, cast iron, aluminum, stainless steels, copper and copper alloys, and many nickel-based materials. Alloys of 62 Ni—28 Mo and 54 Ni—15 Cr—16 Mo are useful under these conditions. Under DOT HM-181 sulfur monochloride is classified as a Poison Inhalation Hazard (PIH) Zone B, as well as a Corrosive Material (DOT Hazard Class B). Shipment information is available (140). 

Uses. In spite of unique properties, there are few commercial appUcations for monolithic shapes of borides. They are used for resistance-heated boats (with boron nitride), for aluminum evaporation, and for sliding electrical contacts. There are a number of potential uses ia the control and handling of molten metals and slags where corrosion and erosion resistance are important. Titanium diboride and zirconium diboride are potential cathodes for the aluminum Hall cells (see Aluminum and aluminum alloys). Lanthanum hexaboride and cerium hexaboride are particularly useful as cathodes ia electronic devices because of their high thermal emissivities, low work functions, and resistance to poisoning. 

The predominate role of the 2inc and aluminum oxides in the ICI catalyst is to reduce the rate of sintering and loss of metallic copper surface area, which, in addition to poisoning, is one of the modes of activity loss with time for this catalyst. 

Figure 8 X-ray elemental imaging in a field-emission STEM (a) EDS data of Pd /Ce /alumina catalyst particle poisoned with SO2 and (b) 128 X 128 digital STEM images formed using X-ray counts collected at each image pixel for aluminum, palladium, cerium, and sulfur. (Courtesy of North-Holland Publishers) ...

Fluorides are used in many materials processes, and can poison the environment when they are discarded. Examples are ciyolite (sodium aluminofluo-ride, Na,AlF ) used to dissolve aluminum oxides for electrolysis, and hydrofluoric acid (HE) used in etching lamp bulbs and semi-conducting circuits. Today lamp bulbs are etched much less than they used to be to reduce fluoride disposal not much has been done to reduce the amount of cryolite for aluminum production. 

The goal of Haber s research was to find a catalyst to synthesize ammonia at a reasonable rate without going to very high temperatures. These days two different catalysts are used. One consists of a mixture of iron, potassium oxide. K20, and aluminum oxide. Al203. The other, which uses finely divided ruthenium, Ru. metal on a graphite surface, is less susceptible to poisoning by impurities. Reaction takes place at 450°C and a pressure of 200 to 600 atm. The ammonia... 

The catalytic system used in the Pacol process is either platinum or platinum/ rhenium-doped aluminum oxide which is partially poisoned with tin or sulfur and alkalinized with an alkali base. The latter modification of the catalyst system hinders the formation of large quantities of diolefins and aromatics. The activities of the UOP in the area of catalyst development led to the documentation of 29 patents between 1970 and 1987 (Table 6). Contact DeH-5, used between 1970 and 1982, already produced good results. The reaction product consisted of about 90% /z-monoolefins. On account of the not inconsiderable content of byproducts (4% diolefins and 3% aromatics) and the relatively short lifetime, the economics of the contact had to be improved. Each diolefin molecule binds in the alkylation two benzene molecules to form di-phenylalkanes or rearranges with the benzene to indane and tetralin derivatives the aromatics, formed during the dehydrogenation, also rearrange to form undesirable byproducts. 

Elkins, H.B, and J.P.Fahy. 1967. Arsine poisoning from aluminum tank cleaning. Ind. Med. Surg. 36 747-749. 

The microcalorimetry of NH3 adsorption coupled with infrared spectroscopy was used to study the effect of the synthesis medium (OH or F ) on the nature and amount of acid sites present in Al,Si-MFl zeolites [103]. Both techniques revealed that H-MFl (F ) with Si/Al < 30 contained extra-framework aluminum species. Such species were responsible for the presence of Lewis acid sites and poisoning of the Brpnsted acidity. In contrast, MFl (F ) characterized by Si/Al > 30 presented the same behavior as H-MFl (OH ). 

Mix 100 g. of granulated aluminum with 90 g. of clean line sand and 90 g. of sulfur. Place the mixture in a fire-clay crucible embedded in sand in a safe place and ignite with fuse powder and a magnesium ribbon, as described in Exercise 85. After the reaction is completed, allow the crucible to cool. Break the crucible, put the contents in an evaporating dish, and treat with water to decompose the aluminum sulfide. This should be done under the hood so that the copious fumes of poisonous H2S will be carried off. Wash away the slimy lumps of melted aluminum from such foreign matter as pieces of crucible. Place these pieces of metal in a beaker, gradually treat with commercial hydrochloric acid until the action has quieted down, then cover with the acid and let stand on the hot plate for several days,... 

Sodium cyanide solution dissolves certain metals (I) with absorption of oxygen, e.g.. gold, silver, mercury, lead, and (2) with evolution of hydrogen, e.g.. copper, nickel, iron. zinc, aluminum, magnesium and solid sodium cyanide, when heated with certain oxides, e.g.. lead monoxide PhO. stannic oxide SnO.. yields the metal of the oxide, e.g.. lead. tin. respectively. and sodium cyanate NaCNO. Two classes of esters arc known, cyanides or nitriles, and isocyanides, isonitriles or carbylatnincs. the latter being very poisonous and of marked nauseating odor... 

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