Temperature pitch

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Figure 2,6 Scheme of the carbonization process of a pitch (temperature increases from left to right). (Reproduced from Ref. [40] with permission from Taylor and Francis Group.)... 

Fig. 4.23 Adsorption isotherms of butane vapour at difTerent temperatures on a sample of carbon (prepared by heating a mixture of coke and pitch at 600°C), burnt off by 0.27%.

Variable Air Flow Fans. Variable air flow fans are needed ia the process iadustry for steam or vapor condensing or other temperature critical duties. These also produce significant power saviags. Variable air flow is accompHshed by (/) variable speed motors (most commonly variable frequency drives (VFDs) (2) variable pitch fan hubs (J) two-speed motors (4) selectively turning off fans ia multiple fan iastaHations or (5) variable exit louvers or dampers. Of these methods, VFDs and variable pitch fans are the most efficient. Variable louvers, which throttle the airflow, are the least efficient. The various means of controlling air flow are summarized ia Table 3. 

An axial fan is a constant volume device. That is, a fan at a certain pitch moves a constant volume of air or gas at a constant speed and resistance (static pressure). If the density changes, the static pressure and wattage change, but the volume remains constant, ie, if the density (temperature) decreases, the static pressure and kW go up, but air flow remains the same. 

In petrochemical plants, fans are most commonly used ia air-cooled heat exchangers that can be described as overgrown automobile radiators (see HeaT-EXCHANGEtechnology). Process fluid ia the finned tubes is cooled usually by two fans, either forced draft (fans below the bundle) or iaduced draft (fans above the bundles). Normally, one fan is a fixed pitch and one is variable pitch to control the process outlet temperature within a closely controlled set poiat. A temperature iadicating controller (TIC) measures the outlet fluid temperature and controls the variable pitch fan to maintain the set poiat temperature to within a few degrees. 

The unit Kureha operated at Nakoso to process 120,000 metric tons per year of naphtha produces a mix of acetylene and ethylene at a 1 1 ratio. Kureha s development work was directed toward producing ethylene from cmde oil. Their work showed that at extreme operating conditions, 2000°C and short residence time, appreciable acetylene production was possible. In the process, cmde oil or naphtha is sprayed with superheated steam into the specially designed reactor. The steam is superheated to 2000°C in refractory lined, pebble bed regenerative-type heaters. A pair of the heaters are used with countercurrent flows of combustion gas and steam to alternately heat the refractory and produce the superheated steam. In addition to the acetylene and ethylene products, the process produces a variety of by-products including pitch, tars, and oils rich in naphthalene. One of the important attributes of this type of reactor is its abiUty to produce variable quantities of ethylene as a coproduct by dropping the reaction temperature (20—22). 

When the recycle soot in the feedstock is too viscous to be pumped at temperatures below 93°C, the water—carbon slurry is first contacted with naphtha carbon—naphtha agglomerates are removed from the water slurry and mixed with additional naphtha. The resultant carbon—naphtha mixture is combined with the hot gasification feedstock which may be as viscous as deasphalter pitch. The feedstock carbon—naphtha mixture is heated and flashed, and then fed to a naphtha stripper where naphtha is recovered for recycle to the carbon—water separation step. The carbon remains dispersed in the hot feedstock leaving the bottom of the naphtha stripper column and is recycled to the gasification reactor. 

The conditions of pyrolysis either as low or high temperature carbonization, and the type of coal, determine the composition of Hquids produced, known as tars. Humic coals give greater yields of phenol (qv) [108-95-2] (up to 50%), whereas hydrogen-rich coals give more hydrocarbons (qv). The whole tar and distillation fractions are used as fuels and as sources of phenols, or as an additive ia carbonized briquettes. Pitch can be used as a biader for briquettes, for electrode carbon after coking, or for blending with road asphalt (qv). 

A residuum, often shortened to resid, is the residue obtained from petroleum after nondestmctive distillation has removed all the volatile materials. The temperature of the distillation is usually below 345°C because the rate of thermal decomposition of petroleum constituents is substantial above 350°C. Temperatures as high as 425°C can be employed in vacuum distillation. When such temperatures are employed and thermal decomposition occurs, the residuum is usually referred to as pitch. By inference, the name is used in the same manner as when it refers to the nonvolatile residue from the thermal decomposition of coal tar (3). 

Carbon—Carbon Composites. Above 300°C, even such polymers as phenoHcs and polyimides are not stable as binders for carbon-fiber composites. Carbon—carbon composites are used at elevated temperatures and are prepared by impregnating the fibers with pitch or synthetic resin, foUowed by carbonization, further impregnation, and pyrolysis (91). 

Ultramarine blues are prepared by a high temperature reaction of intimate mixtures of china clay, sodium carbonate, sulfur, siHca, sodium sulfate, and a carbonaceous reducing agent, eg, charcoal, pitch, or rosin. 

A plasticizer is a substance the addition of which to another material makes that material softer and more flexible. This broad definition encompasses the use of water to plasticize clay for the production of pottery, and oils to plasticize pitch for caulking boats. A more precise definition of plasticizers is that they are materials which, when added to a polymer, cause an increase in the flexibiUty and workabiUty, brought about by a decrease in the glass-transition temperature, T, of the polymer. The most widely plasticized polymer is poly(vinyl chloride) (PVC) due to its excellent plasticizer compatibility characteristics, and the development of plasticizers closely follows the development of this commodity polymer. However, plasticizers have also been used and remain in use with other polymer types. 

Bricks may be extmded or dry-pressed on mechanical or hydraulic presses. Formed shapes may be burned before use, or in the case of pitch or resin/chemically bonded bricks, may be cured (tempered) at a low temperature. 

Coal tar is the condensation product obtained by cooling to approximately ambient temperature, the gas evolved in the destmctive distillation of coal. It is a black viscous Hquid denser than water and composed primarily of a complex mixture of condensed ring aromatic hydrocarbons. It may contain phenoHc compounds, aromatic nitrogen bases and their alkyl derivatives, and paraffinic and olefinic hydrocarbons. Coal-tar pitch is the residue from the distillation of coal tar. It is a black soHd having a softening point of 30—180°C (86—359°F). 

The higher boiling phenols, present in considerable amounts in CVR and low temperature tars, are corrosive to mild steel, especially above 300°C. Cast iron, chrome steel, and stainless steel are more resistant. Furnace tubes, the insides of fractionating columns, and the rotors of pumps handling hot pitch and base tar are generally constmcted of these metals. Nevertheless, to ensure satisfactory furnace tube life, particularly in plants processing CVR or low temperature tars, the tube temperature should be kept to a minimum. 

Viscosity of Coal- Tar Pitch and Change with Temperature. Because pitch is mainly used as a hot-appHed binder or adhesive, the viscosity and its change with temperature are important in industrial practice. Some useful correlations, by which the viscosity of pitch at any temperature can be predicted, have been developed. The data on which such correlations are based may be from one of the fixed equiviscous points that characterize a pitch (Table 5). 

When a pitch is tested for ductility, the sample either suffers britde fracture without elongation or elongates to the maximum distance without breaking. When tested at increased temperatures at a particular point, ie, the ductility point, the behaviour changes from the first type to the second. 

The general equation for the temperature function of coal-tar pitch takes the foUowiag form (43) ... 

Using equation 3, the viscosity of any pitch can be calculated from two measurements in the range of 10 —10 mPa-s(=cP), exhibiting a precision similar to what may be expected of direct measuremeat. By employing equatioas 3, 4 or 5, and 6, the viscosity of pitch at any temperature can be calculated, with an accuracy adequate for most engineering purposes, from the R-and-B softening poiat and the Tl content. 

Low temperature tars contain 30—35 wt % non aromatic hydrocarbons, ca 30% of caustic-extractable phenols in the distillate oils, and 40—50% of aromatic hydrocarbons. The latter usually contain one or more alkyl substituent groups. On atmospheric distillation, coke-oven tars yield 55—60% pitch, whereas CVR tars give 40—50% pitch. The pitch yield from low temperature tars is in the 26—30% range. 

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