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Phenolic compounds chemical structures

Various analyzers have been used to analyze phenolic compounds. The choice of the MS analyzer is influenced by the main objective of the study. The triple quadrupole (QqQ) has been used to quantify, applying multiple reaction monitoring experiments, whereas the ion trap has been used for both identification and structure elucidation of phenolic compounds. Moreover, time-of-flight (TOF) and Fourier-transform ion cyclotron resonance (FT-ICR) are mainly recommended for studies focused on obtaining accurate mass measurements with errors below 5 ppm and sub-ppm errors, respectively (Werner and others 2008). Nowadays, hybrid equipment also exists, including different ionization sources with different analyzers, for instance electrospray or atmospheric pressure chemical ionization with triple quadrupole and time-of-flight (Waridel and others 2001). [Pg.60]

Until recently, most of the chemical research on the contents of these structures was directed at the identification of the constituents of castoreum. In the late 1940s Lederer [72, 73] identified 36 compounds and some other incompletely characterized constituents in castoreum of uncertain origin. Other constituents were subsequently identified in the material [74-77]. In a reinvestigation aimed specifically at the phenol content of the material, Tang et al [69] identified 10 previously unreported phenols in the castoreum from the North American beaver, Castor canadensis. Of the 15 phenols reported elsewhere, only five were confirmed in this analysis, in addition to 10 phenolic compounds that were not reported elsewhere. It was concluded that the 10 previously identified phenols that were not found in the study by Tang et al. were either absent or were not volatile enough to be detected by the methods employed. This was most probably because a relatively low maximum column temperature of only 210 °C was employed in the GC-MS analyses. The compounds identified by Lederer,... [Pg.255]

It should be noted that phenol is the simplest form, or parent compound, of the class of chemicals commonly referred to as phenols or phenolics, many of which are natural substances widely distributed throughout the environment. There is some confusion in the literature as to the use of the term phenol in some cases it has been used to refer to a particular phenolic compound that is more highly substituted than the parent compound (Doan et al. 1979), whereas in other cases it has been used to refer to the class of phenolic compounds (Beveridge 1997). This chapter, however, addresses only those health effects which can be directly attributable to the parent compound, monohydroxybenzene, or phenol. As Deichmann and Keplinger (1981) note It cannot be overemphasized that the structure-activity relationships of phenol and phenol derivatives vary widely, and that to accept the properties of individual phenolic compounds as being those of phenol is a misconception and leads to error and confusion. ... [Pg.33]

Polyphenols constitute one of the most and widely distributed groups of substances in the plant kingdom, with more than 8000 phenolic structures currently known. They can be divided into at least 10 different classes based upon their chemical structure, ranging from simple molecules, such as phenolic acids, to highly polymerized compounds, such as tannins. [Pg.257]

Solanaceae), acts as competitive inhibitor for ubiquinone in Complex I. Methyl capsaicin is more potent than capsaicin, indicating that the phenolic OH is not essential for the activity [297]. Other natural inhibitors of Complex I are annonaceous acetogenins. These compounds belong to a wide group of natural products isolated from several species of the Annonaceae family, which include more than 250 molecules with diverse chemical structures. Among the various classes, it seems that monotetrahydrofuranic derivatives are less potent than other acetogenins [296, 299]. [Pg.437]

We conclude our short discussion of relationships between chemical structure and light absorbance by considering some cases in which an acid or base function forms part of a chromophore. Important examples of compounds exhibiting such chro-mophores are phenols and anilines. As is evident from the spectra shown in Fig. 15.5, deprotonation of a phenolic group results in a substantial bathochromic shift... [Pg.622]

Many excellent discussions of natural occurrence, structure, characterization, and analysis of phenolic compounds are available in the literature, and a series of books devoted to flavonoid chemistry has also been published. Detailed discussions on various chromatographic modes, including HPLC, GC, column chromatography (CC), capillary electrophoresis (CE), PC, and TLC, of simple phenolics and polyphenols are also presented in the recent book, Handbook of Food Analysis, volume 1, edited by Nollet (1). Due to their diversity and the chemical complexity of phenolic compounds, this chapter is limited to phenolic compounds that are considered to be important to foods and the food industry. [Pg.775]

Recent advances in electrospray ionization (ESI), atmospheric-pressure chemical ionization (APCI), thermospray, and particle beam LC-MS have advanced the analyst toward the universal HPLC detector, but price and complexity are still the primary stumbling blocks. Thus, HPLC-MS remains expensive and the technology has only recently been described. Early commercial LC-MS uses particle beam and thermospray sources, but ESI and APCI interfaces now dominate. Liquid chromatography MS can represent a fast and reliable method for structural analyses of nonvolatile compounds such as phenolic compounds (36,37), especially for low-molecular-weight plant phenolics (38), but the limited resolving power of LC hinders the widespread use of its application for phenolics as compared to GC-MS. [Pg.786]

The focus of this book is centered on structure, nomenclature and occurrence of phenolic compounds (Chapter 1), and their chemical properties (Chapter 2). Chapter 3 describes the biosynthetic pathways leading to the major classes of phenolics. This chapter presents an up-to-date overview of the genetic approaches that have been used to elucidate these pathways. Chapter 4 presents an overview of methods for the isolation and identification of plant phenolic compounds. Given that much of the recent... [Pg.285]

Breaking of complex structures Production of energy products or simple chemicals for example, lignin can be used for the synthesis of phenolic compounds upon hydrolytic treatment... [Pg.338]

There is growing evidence from human feeding studies that the absorption and bioavailability and thus bioactivity of phenolic compounds and flavonoids are very much dependent on the nature of their chemical structure. Their chemical classification and dietary occurrence is briefly discussed in the following section. [Pg.5]

Despite the wide distribution of phenolic compounds in edible plants and the high dietary intake, the health effects of plant phenolic compounds had not been extensively studied until the mid-1990s due to their diversity of species and chemical structures. Epidemiological studies have revealed that dietary consumption of fruits, vegetables, and other plant-based foods and beverages is inversely correlated with the incidences of many diseases such as cancer, cardiovascular disease, and neurodegenerative diseases [Stevenson and Hurst, 2007]. The evidences from clinical and laboratory studies strongly support... [Pg.402]

Figure 18.1 Chemical structures of phenolic compounds with neuroprotective activity. Figure 18.1 Chemical structures of phenolic compounds with neuroprotective activity.
Eugenol, like other phenolic compounds, is a structurally non-specific drug. The pharmacological action is not directly subordinated to chemical structure, except to the extent that structure affects physicochemical properties, as adsorption, solubility, pKa, and oxidation-reduction potential, factors which influence permeability, depolarization of the membrane and protein coagulation [34],... [Pg.173]

The safety limit of temperature depends on the chemical structure of the compound being nitrated. For exMnple, in the nitration of dinitrotoluene to trinitrotoluene or of phenol to picric acid, temperatures neM 120°C Mid over are considered dangerous. In the nitration of dimethylaniline to tetiyl, a temperature higher than 80°C must be considered dangerous. Esterification with nitric acid should be carried out at a temperature close to room temperature or lower. [Pg.151]

All the reactants are individual compounds of high chemical purity with epoxy equivalent close to theoretical values. It has been shown 6,7,16,17) that, at Tcure iS 110-120 °C and especially with diglycidyl ether of resorcinol (DGER) or Bis-phenol-A (DGEBA) and w-phenylenediamine (w-PhDA) as reactants, Eq. (I) proceeds practically without side reactions and yields a polymer with a chemical structure very close to that shown in above. Using different initial ratios of reactants (P = [NH]0/[EP]0 molar ratio), one can prepare a family of polymers with rather broad variations of crosslink concentration per unit volume or number of unreacted groups of different type and properties of the final products. [Pg.53]


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See also in sourсe #XX -- [ Pg.429 ]




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