Permeability impermeability

Unstable Stable, permeable Impermeable B. Influence of bilayer thickness on stability... 

Although this terminology (permeable/impermeable) is frequently used in the field of junction thermodynamics, it will not be used in the remainder of this book. In fact, it is easier to apply a common treatment for electrochemical chains where different kinds of interfaces are involved. This is notably true when treating kinetic phenomena occurring at these interfaces. If you consider all these interfaces to be impermeable interfaces, whether reactive or not, then this unification is made possible (see next example). In the case of a permeable junction, the two exchanging species (e.g., Ag in solid AgCI and Ag in solution) will simply be considered as two different species the first one is transformed into the second one by a reaction at the interface. 

Modification of mechanical properties High aspect ratio glass fibers, mica, nanoclays, carbon nanotubes, carbon/graphite fibers, and aramid/synlhetic/natural fibers Low aspect ratio talc, CaC03, kaolin, wood fiour, wollastonite, and glass spheres Control of permeability Reduced permeability impermeable plate-like fillers mica, talc, nanoclays, glass flakes Enhanced permeability stress concentrators for inducing porosity CaCOj and dispersed polymers... 

The principal packagiag use of PVC film is as a gas-permeable but water-vapor impermeable wrap for red meat, poultry, and produce. Sparkle and transparency, combined with the abiHty to transmit oxygen to maintain red-meat color, offer advantages in these appHcations. 

The guarded hot-plate method can be modified to perform dry and wet heat transfer testing (sweating skin model). Some plates contain simulated sweat glands and use a pumping mechanism to deUver water to the plate surface. Thermal comfort properties that can be deterrnined from this test are do, permeabihty index (/ ), and comfort limits. PermeabiUty index indicates moisture—heat permeabiUty through the fabric on a scale of 0 (completely impermeable) to 1 (completely permeable). This parameter indicates the effect of skin moisture on heat loss. Comfort limits are the predicted metaboHc activity levels that may be sustained while maintaining body thermal comfort in the test environment. 

A more polar comonomer, eg, an AN comonomer, increases the water-vapor transmission more than VC when other factors are constant. For the same reason, AN copolymers are more resistant to penetrants of low cohesive energy density. AH VDC copolymers, however, are very impermeable to ahphatic hydrocarbons. Comonomers that lower T and increase the free volume in the amorphous phase increase permeability more than the polar comonomers higher acrylates are an example. Plasticizers increase permeabiUty for similar reasons. 

The most harmful deposits are those that are water permeable. Truly water-impermeable material is protective, since without water contacting metal surfaces corrosion cannot occur. Innately acidic or alkaline deposits are troublesome on amphoteric alloys (those attacked at high and low pH—e.g., aluminum and zinc). 

Elame Arrester A flame arrester is a device permeable to gas flow but impermeable to any flame. It quenches the flame and cools the products sufficiently to prevent reignition at arrester outlet. Arresters are used to prevent a flame propagating into the system from outside (such as via a tank vent) or one part of the system to another (such as through connected piping). 

Vulcanisation can be effected by diamines, polyamines and lead compounds such as lead oxides and basic lead phosphite. The homopolymer vulcanisate is similar to butyl rubber in such characteristics as low air permeability, low resilience, excellent ozone resistance, good heat resistance and good weathering resistance. In addition the polyepichlorohydrins have good flame resistance. The copolymers have more resilience and lower brittle points but air impermeability and oil resistance are not so good. The inclusion of allyl glycidyl ether in the polymerisation recipe produces a sulphur-curable elastomer primarily of interest because of its better resistance to sour gas than conventional epichlorhydrin rubbers. 

Once applied, the eure rate will depend heavily on the moisture eontent and/or moisture vapor permeability of the substrates between whieh the adhesive is sandwiehed. For wood substrates, typieally full eure oecurs in a day with the faster systems. Misting of the substrates with water is sometimes conducted prior to adhesive applieation to further speed eure, or when the substrates are substantially moisture impermeable. 

The most important factor of a landfill is to build it properly so that the environment is not disturbed in any fashion. There are several components to the design of a environmentally friendly landfill. These components are that the landfill should be placed on a compacted low permeable medium, preferably a clay layer. This layer is then covered by a impermeable membrane which is then covered by a granular substance to act as a secondary drainage system. Layers upon layers are built up, while each layer is separated by a granular membrane. This is done over and over again until the entire... 

Permeation rates are dependent on the ehemieal makeup of the eontamination. This ineludes the size of the eontaminant (how large or small the moleeule or partiele is) and on the pore size of the proteetive material (for instanee, impermeable rubber suits, tyveks, or eotton eoveralls). Chemieal eharaeteristies (i.e., polarity, vapor pressure, pH) of both the eontaminant and the proteetive material also determine permeability. Keep in mind that gases, vapors, and low-viseosity liquids tend to permeate more readily than high-viseosity liquids or solids [2],... 

Most of the above can be made into plastic films - primarily used for wrapping. Film properties vary widely from permeable for food to impermeable to preserve dryness. Paper, treated or untreated, has been used for many years as a covering film, but has low strength when wet and is difficult to make transparent. In the 1920s, the transparency of cellophane revolutionized wrap. It is regenerated cellulose, like viscose rayon, except it is extruded in sheet instead of fiber, unfortunately it is sensitive to water and humidity. 

The singlet-level theories have also been applied to more sophisticated models of the fluid-solid interactions. In particular, the structure of associating fluids near partially permeable surfaces has been studied in Ref. 70. On the other hand, extensive studies of adsorption of associating fluids in a slit-like [71-74] and in spherical pores [75], as well as on the surface of spherical colloidal particles [29], have been undertaken. We proceed with the application of the theory to more sophisticated impermeable surfaces, such as those of crystalline solids. 

A plot of A versus r, the calibration curve of OTHdC, is shown in Fig. 22.2. The value of constant C depends on whether the solvent/polymer is free draining (totally permeable), a solid sphere (totally nonpermeable), or in between. In the free-draining model by DiMarzio and Guttman (DG model) (3,4), C has a value of approximately 2.7, whereas in the impermeable hard sphere model by Brenner and Gaydos (BG model) (8), its value is approximately 4.89. 

Gas-dichte, /. gas(eous) density, -dichtigkeit, /. impermeability to gas. -druck, m. gas pressure, gaseous pressure, -dnickmesser, m. manometer, pressure gage (MU.) accelerometer. -durchlassigkeit, /. permeability for gas. 

A trap provides an impermeable barrier to the migration of hydrocarbons moving through a porous and permeable sedimentary bed. The trap allows the hydrocarbons to accumulate within the trap. The trap is a prerequisite for the formation of an accumulation of hydrocarbons and, therefore, for a reservoir [26]. 

Paint films exposed to condensation often fail unexpectedly by very early blistering between primer and finishing coat, usually associated with soluble salts trapped under the relatively impermeable finishing coat. Relatively more permeable latex-based paints are less prone to this failure. 

Impermeable timbers have a good resistance to polluted atmospheres where acid fumes rapidly attack steel. Wood has given excellent service in the buildings of chemical works and railway stations. Permeable wood species and sapwood can suffer defibration problems caused by the sulphur dioxide of industrial atmospheres. Tile battens are particularly vulnerable. The heartwood of Douglas fir, pitch pine, larch, Scots pine/European redwood and many tropical hardwoods give good service in these conditions. 

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