Particulates, industrial

This paper examines the influence of adding a fine-particulate industrial by-product namely fly ash as reinforcing filler into a rotomolding-grade polyethylene. The compormds of various filler contents were added either by dry-blended or by-melt-compoimded, and their rotomolded parts were analyzed to check fro their appearances, processabilities, and mechanical properties. 

With respect to fuels utilized as heating fuels for industrial furnaces, or as motor fuels for large diesel engines such as those in ships or power generation sets, the characteristics of primary importance are viscosity, sulfur content and the content of extremely heavy materials (asphaltenes) whose combustion can cause high emissions of particulates which are incompatible with antipollution legislation. 

Typical examples of gaseous samples include automobile exhaust, emissions from industrial smokestacks, atmospheric gases, and compressed gases. Also included with gaseous samples are solid aerosol particulates. 

There has been considerable improvement, especially in industrial areas, in U.S. air quaUty since the adoption of the Clean Air Act of 1972. Appreciable reductions in particulate emissions and in SO2 levels ate especially evident. In 1990, however, almost every metropoUtan area was in nonattainment status on o2one air quaUty standards 50 metropoUtan areas exceeded the CO standard and between 50 and 100 exceeded the PM q standard for particulate level (29). 

E. Bakke, "The AppHcation of Wet Electrostatic Precipitators for Control of Eiue Particulate Matter," Preprint, Symposium on Control of Tine Particulate Emissions from Industrial Sources, Joint U.S.-USSR Working Group, Stationay Source Air Pollution ControlTechnology, San Francisco, Calif, Jan. 15—18, 1974. 

W. Strauss, "Particulate Collection by Liquid Sembbing," in Industrial Gas Cleaning 2nd ed., Pergamon Press, Oxford, 1975, Chapt. 9, pp. 367—408. 

Plastics. In the plastics industry, the term filler refers to particulate materials that are added to plastic resins in relatively large, ie, over 5%, volume loadings. Except in certain specialty or engineering plastics appHcations, plastics compounders tend to formulate with the objective of optimizing properties at minimum cost rather than maximizing properties at optimum cost. Table 2 fists typical plastic fillers and their uses. 

Methanol, a clean burning fuel relative to conventional industrial fuels other than natural gas, can be used advantageously in stationary turbines and boilers because of its low flame luminosity and combustion temperature. Low NO emissions and virtually no sulfur or particulate emissions have been observed (83). Methanol is also considered for dual fuel (methanol plus oil or natural gas) combustion power boilers (84) as well as to fuel gas turbines in combined methanol / electric power production plants using coal gasification (85) (see Power generation). 

RCRA incinerator regulations include adrninistrative as weU as performance standards. Administrative standards include procedures for waste analysis, inspection of equipment, monitoring, and facihty security. Steps needed to meet adrninistrative standards are outlined ia the permit apphcation performance standards are demonstrated during a trial bum. Trial bum operating conditions are included in the permit to assure ongoing compliance with the performance standards. Performance standards include destmction and removal efficiency (DRE), particulate emissions limits, products of incomplete combustion emission limits, metal emission limits, and HCl and Cl emission limits (see Exhaust CONTROL, INDUSTRIAL). 

Binders. Latices are used as fiber binders by the paper and textile industries. The two principal methods of appHcation are (/) wet-end addition, wherein the ionic latex is added to a fiber slurry and then coagulated in the slurry prior to sheet formation, and (2) saturation of the latex into a formed fiber web wherein the latex is coagulated by dehydration. Latices are also used as binders for particulate matter such as mbber scrap. 

The toxicity of a metal in powder form may vary from that of the massive metals in that fine particles can be ingested or inhaled more readily (41). The metal powder producing or consuming industries must conform to OSHA requirements. The limits of airborne particulates are set by NIOSH. 

R. M. German and R. G. lacocca, "Powder Metallurgy Processing and AppHcations for IntermetaUics," Mdvances in Powder Metallurgy (N Particulate Materials, Vol. 6, Metal Powder Industries federation, Princeton, N.J., 1993. 

Phthalates in Air. Atmospheric levels of phthalates in general are very low. They vary, for DEHP, from nondetectable to 132 ng/m (50). The latter value, measured in 1977, is the concentration found in an urban area adsorbed on airborne particulate matter and hence the biological avaUabUity is uncertain. More recent measurements (52) in both industrial and remote areas of Sweden showed DEHP concentrations varying from 0.3 to 77 ng/m with a median value of 2 ng/m. ... 

Occupational Safety and Health. OSHA has set no specific limits for sodium and potassium sibcates (88). A pmdent industrial exposure standard could range from the permissible exposure limit (PEL) for inert or nuisance particulates to the PEL for sodium hydroxide, depending on the rate of dissolution and the concentration of airborne material. Material safety data sheets issued by siUcate producers should be consulted for specific handling precautions, recommended personal protective equipment, and other important safety information. 

Calcium metal is produced in the United States by Pfizer Inc., Canaan, Coimecticut, and in Canada by Timminco Metals, Toronto, Ontario. In France it is produced by Pechiney ElectrometaHurgie. It is also produced in the Commonwealth of Independent States (CIS) and the People s RepubHc of China. Both Pfizer and Timminco supply the various grades in a variety of sizes and forms. In addition, Pfizer suppHes an 80% Ca—20% Mg alloy and a steel-clad calcium wire for use in deoxidation of steel and other metals. Timminco and Pfizer both supply ca 75% Ca—25% Al alloy for use in lead alloying. Timminco also suppHes a 70% Mg—30% Ca alloy for use in lead debismuthizing (18), and calcium particulate products, which are purchased by several companies for the manufacture of cored wire for use in the steel industry. 

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