P-Dodecylbenzenesulfonic acids

Preparative Method prepared by addition of granular sodium azide (1.3 equiv) to a mixture of isomeric sulfonyl chlorides (from a commercial mixture of isomers of p-dodecylbenzenesulfonic acid) in acetone solution. ... 

Source Adapted with permission from S. Ikkeoka et aL, Bull. Chem. Soc. 28 p-Dodecylbenzenesulfonic acid 25 0.25 5... 

BigdeU MA, Gholami G, Sheikhhosseini E (2011) P-dodecylbenzenesulfonic acid (DBSA), a Bronsted acid-surfactant catalyst for Biginelli reaction in water and under solvent free conditions. Chinese Chem Lett 22 903-906... 

However, when it comes to the more important 2,2-diaryl derivatives (1.25), the routes illustrated in Figure 1.7 are not very useful. For these derivatives the almost universally adopted synthetic method involves the reaction of a l,l-diarylprop-2-yn-l-ol (1.24) with a substituted phenol or naphthol in the presence of an acid catalyst. The acid catalyst can be alumina, an acidic clay or Nafion for heterogeneous reactions, or trifluoroacetic acid, p-toluenesulfonic acid and dodecylbenzenesulfonic acid for reactions carried out in solution. The alkynols are prepared by reaction of a benzophenone (1.22) with a Na or Li derivative of an alkynide, such as the trimethylsilyl acetylide (1.23), (Figure 1.8). ... 

Effective catalysts for preparing the polyformals were p-toluenesulfonic acid, camphorsulfonic acid, methanedisulfonic acid, and perchloric acid. Various other acidic compounds were evaluated as catalysts with tetramethylcyclobutanediol. In these experiments, 0.5 to 1.0 gram of acidic compound per mole of tetramethylcyclobutanediol was normally added. If insufficient water was obtained, more catalyst was added. If the prepolymer was obtained but an appreciable amount of brown color was present, less catalyst was then used. Compounds which did not catalyze the reaction (no water obtained) were phosphoric acid, zinc chloride, trifluoroacetic acid, and heptafluorobutyric acid. Incomplete reactions (insufficient water) took place with concentrated hydrochloric acid, concentrated nitric acid, zinc fluoroborate, or Amberlite IRC-50 ion exchange resin as catalyst. A prepolymer was obtained when boron trifluoride etherate was used, but buildup did not take place in the solid phase (catalyst probably too volatile). Brown or speckled-brown polymers (after solid-phase buildup) were obtained with catalysts containing sulfonic acid groups (benzenesulfonic, dodecylbenzenesulfonic, sulfo-acetic, methanetrisulfonic, sulfuric, p-toluenesulfonic, camphorsulfonic, and methanedisulfonic acids). To obtain white polymers from tetramethylcyclobutanediol it was necessary to treat the solvent and prepolymer reaction mixture as previously described. (White polyformals were obtained from the other diols without this treatment.)... 

Arylan PWS Abas G 3300 Abas G 711 Benzenesulfbnic acid, dodecyl-, compd. with isopropylamlne Dodecylbenzenesulfonic acid, isopropylamine salt Dodecylbenzenesulfonic acid monoisopropanolamine salt Dodecylbenzenesulphonic acid, compound with isopropylamine EINECS 247-556-2 G 3300 G 711 Isopropylamlne dodecylbenzenesulfonate Nansa YS 94 P 10-59 Polystep All Rhodacal 330 Siponate 330 Witconate P10-59. 

PTS p-Toluenesulfonic acid, sodium salt DBS Dodecylbenzenesulfonic acid, sodium salt BS 1,3-Benzenedisulfonic acid, disodium salt... 

Jiao, H., Goh, S. H., and Valiyaveettil, S. 2001. Mesomorphic interpolymer complexes and blends based on poly(4-vinylpyridine)-dodecylbenzenesulfonic acid complex and polyjacrylic acid) or poly(p-vinylphenol). Macromolecules 34 7162-7165. 

Alanine, phenyl-, D-. See,D-Phenylalanine l-Alanine, phenyl-. See L-Phenylalanine P-Alanine, N-tetradecyl-. See Myristaminopropionic acid P-Alanine, N-tetradecyl-, compd. with 2,2. 2"-nitrilotris (ethanol) (1 1). See TEA-myristaminopropionate Alaren Rennet Casein. See Casein Alarsol AL. See Dodecylbenzenesulfonic acid Alatac 100-10. See Rosin Alathon 7320-, Alathon 9304, Alathon DL 5440, Alathon DL 5840, Alathon H 5050, Alathon H 5112, Alathon H 5234] Alathon H 5244] Alathon H 5252] Alathon H 5257] Alathon H 5520] Alathon H 5618] Alathon H 6017] Alathon H 6018] Alathon L 3530] Alathon L 4427] Alathon L 4505] Alathon L 4907] Alathon L 5005] Alathon L 5012] Alathon L 5045] Alathon L 5440] Alathon L 5440AS] Alathon L 5440CS] Alathon L 5800-I] Alathon L 584(7, Alathon L 5840AS] Alathon L 5845] Alathon L 5845-1] Alathon L 585(7, Alathon L 5850AS] Alathon L 5850ASW] Alathon L 5885] Alathon LM... 

DADPM. See 4,4 -Methylenedianiline DADPS. See 4,4 -Diaminodiphenyl sulfone DADTDG. See Diammonium dithiodiglycolate Dag 3, Dag 91, Dag 137] Dag 138. See Graphite Dahlia B. See Basic violet 1 DAHQ. See Diamylhydroquinone Daiamid. See Nylon 12 Dai CariXBN. See Butyl benzoate Daicel-Styrol. See Polystyrene Daimac S-300K. See Epoxidized soybean oil Dainol 25] Dainol 25(P). See Sodium dodecylbenzenesulfonate Dainol C Cone.. See Dodecylbenzenesulfonic acid... 

Lumisorb SMP. See Sorbitan palmitate Lumisorb SMS. See Sorbitan stearate Lumisorb SSO. See Sorbitan sesquioleate Lumisorb STO. See Sorbitan trioleate Lumisorb STS. See Sorbitan tristearate Lumisorb STT. See Sorbitan tritallate Lumitac . See Polyethylene, very low-density Lumiten P-F, Lumiten P-T. See EO/PO block polymer or copolymer LumoWW75. See Sodium dodecylbenzenesulfonate LumosSure A. See Dodecylbenzenesulfonic acid... 

Nanospheres 100 Vitamine E Acetate. See Tocopheryl acetate Nanox 2(H), NanoX. See Zinc oxide Nansa 1042, Nansa 1042/P. See Dodecylbenzenesulfonic acid Nansa 1106/P-, Nansa 1169/P. See Sodium dodecylbenzenesulfonate Nansa 1853] Nansa 1909. See Dodecylbenzenesulfonic acid Nansa AS 40. See Ammonium dodecylbenzene sulfonate Mansa EVM50. See Calcium dodecylbenzene sulfonate... 

Reworyl B 70. See Benzenesulfonic acid Reworyl C 65. See Cumene sulfonic acid Reworyl K. See Dodecylbenzenesulfonic acid Reworyl NKS 50, Reworyl NKS 100. See Sodium dodecylbenzenesulfonate Reworyl NXS 40. See Sodium xylenesulfonate Reworyl T 65. See p-Toluene sulfonic acid Reworyl TKS 90/L. See TEA-dodecylbenzenesulfonate Reworyl X 65. See Xylene sulfonic acid Rewotein CPK. See Potassium cocoyl hydrolyzed collagen... 

Sodium N-dodecyl-p-alaninate. See Sodium lauraminopropionate Sodium dodecylbenzenesulfonate CAS 25155-30-0 68081-81-2 68608-89-9 85117-50-6 EINECS/ELINCS 246-680-4 Synonyms Benzenesulfonic acid, dodecyl-, sodium salt Dodecylbenzene sodium sulfonate Dodecylbenzenesulfonate, sodium salt Dodecylbenzenesulfonic acid sodium salt NaDBS... 

Sulfonax. See Dodecylbenzenesulfonic acid o-Sulfonbenzoic acid imide sodium salt. See Saccharin sodium anhydrous p-Sulfondichloramidobenzoic acid p-Sulfondichloraminobenzoic acid. See Halazone... 

Wftco SCS 40. See Sodium cumenesulfonate Witco STS 40. See Sodium toluenesulfonate Witco SXS 40. See Sodium xylenesulfonate Witco TX Acid. See p-Toluene sulfonic acid Witco Acid B. See Dodecylbenzenesulfonic acid... 

Methanesulfonic acid Phosphoric acid catalyst, acid catalyzed reactions Dodecylbenzenesulfonic acid catalyst, acid chlorination Acetyl chloride catalyst, acid coatings o-Toluene sulfonic acid catalyst, acid foundry core resins o-Toluene sulfonic acid p-Toluene sulfonic acid... 

Cl 2-13 pareth-7 Cl 3-15 pareth-5 Cl4-15 pareth-7 m-Cresol p-Cresol Dodecylbenzenesulfonic acid Hydrochloric acid Laureth Nonoxynol Nonoxynol-70 Oleth-3 Oleth-5 PEG-8 isolauryl thioether Perchloroethylene PPG-3 myristyl ether Sodium C14-16 olefin sulfonate Sodium nonoxynol-6 sulfate Sodium nonylbenzene... 

Dodecylbenzenesulfonic acid Sulframin Acide TPB Witconate Acide TPB 68411-46-1 Agerite Stalite S p,p -Dioctyldiphenylamine Vanlube 81 Vanlube SS Vanox 12 68411-57-4... 

Cationic polymerization can also be performed in direct miniemulsion in the presence of water. p-Methoxystyrene (p-MOS) was polymerized using the inisurf (= initiator - - surfactant) dodecylbenzenesulfonic acid with a monomer [91]. In the presence of ytterbium triflate, inverse systems were formed [92]. Although the rate of polymerization was found to be slower than for direct systems, the molecular weights obtained were shown to be larger. The polymerization was initiated by l-chloro-l-(p-methoxyphenyl)ethane (p-MOS-HCl), and catalyzed by trisdodecyl sulfate ytterbium, which served simultaneously as a surfactant and as a Lewis acid [93]. The Lewis acid surfactant did not play the expected role, however, as the p-MOS-HCl was hydrolyzed. The resulting hydronium protonated the SDS surfactant, which then served as an inisurf in the interfacial cationic polymerization process. 

Toluene, tetrahydrofurane, chloroform, 2-(4-hydroxyphen-ylazo)benzoic acid (HABA), potassium trifluoroacetate, aflyl alcohol, succinic anhydride, naphthaline, potassium, and (l-ethyl-3-(3-dimethylaminopropyl)carbodiimid hydrochloride (EDC) were purchased from Sigma-Aldrich, Germany, in highest quality. Diethoxydimethylsilane (D), methyltrimethoxysilane (T), triethoxysilane (T-H) and tetramethyldisiloxane (M-H) were obtained from Wacker Chemie, Germany. Dodecylbenzenesulfonic acid (DBS), p-chloromethylphenyltrimethoxysilane (ClBz-T) and the Karstedt-Catalyst were purchased from ABCR, Germany. 

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