Sulfonated 2-dodecylbenzene

It is apparent from the Xm values listed in Table V that capacities for adsorption of the organic pesticides on active carbon are quite large, greater on a molar basis than phenol and sulfonated 2-dodecylbenzene, and greater on a weight basis than any of the three other compounds. On the other hand, the fo"1 values, except for parathion, indicate approach to saturation adsorption only at relatively high residual concentrations. 

Product color is important in sulfonating dodecylbenzene detergent alkylate. In Table 7-9, it is own that, when 22 per cent oleum is used, it is possible to employ less sulfonating agent at a higher temperature, but a darker product is obtained. 

The major route to colloidal (effectively "water-soluble") PAn has been through the chemical oxidation (S20g ) of the monomer in the presence of polymeric steric stabilizers and electrosteric stabilizers (polyelectrolytes), such as poly(vinylalcohol), poly(N-vinyl pyrrolidone), poly(ethylene oxide), poly(styrene sulfonate), dodecylbenzene sulfonate and dextran sulfonate. It has been found that the stabilizer can act simultaneously as a dopant, imparting new functionality to the polymer or additional compatibility for the final application. 

The surfactant most commonly used is the anionic detergent sodium lauryl sulfate. Other surfactants that have been used include sodium dodecylbenzene sulfonate [25155-30-0] sodium A/-lauroyl sarcosinate or Gardol [137-16-6] and sodium cocomonoglyceride sulfonate [3694-90-4]. Cationic and nonionic surfactants are not used for several reasons, including incompatibiUty with the abrasive system and lack of high foaming capabiUty. 

Microbes could not break down branch-chain detergents, so they left foam in river water. They were replaced by straight-chain alkyl benzene sulfonates, such as sodium dodecylbenzene-sulfonate and sodium xylenesulfonate. 

Example 4. Glycolysis of Polyurethanes with Propylene Oxide after Pretreatment with a Mixture of Diethanolamine and Potassium Hydroxide.57 Polyurethane scrap was treated with a mixture of diethanolamine and potassium hydroxide at a temperature between about 80 and 140° C with stirring to form an intermediate product. The weight ratio of the scrap PUR polymer to the mixture of diethanolamine and potassium hydroxide was from about 15 1 to 30 1. The intermediate product was reacted with propylene oxide at a temperature of from about 100 to 120°C in a closed reaction vessel to form a polyol. The propylene oxide was added at a rate to maintain a pressure of from about 2 to 5 atm (29-73 psi). The progress of the reaction was followed by following the change of pressure with time. When the pressure remained constant, the reaction of the intermediate product with propylene oxide was considered to be complete. The crude polyol obtained was treated with 10 mol % excess of dodecylbenzene sulfonic acid to remove the potassium hydroxide. 

PP-g-MA) silicate nanocomposites and intercalated thermoset silicate nanocomposites for flame-retardant applications were characterised by XRD and TEM [333], XRD, TEM and FTIR were also used in the study of ID CdS nanoparticle-poly(vinyl acetate) nanorod composites prepared by hydrothermal polymerisation and simultaneous sulfidation [334], The CdS nanoparticles were well dispersed in the polymer nanorods. The intercalation of polyaniline (PANI)-DDBSA (dodecylbenzene-sulfonate) into the galleries of organo-montmorillonite (MMT) was confirmed by XRD, and significantly large 4-spacing expansions (13.3-29.6A) were observed for the nanocomposites [335],... 

Hydroxy apatite (tricalcium phosphate) (tech grade) Dodecylbenzene sulfonate (tech grade)... 

Raw Material Obtained in the Following Size Containers Styrene by barge in 2,200,000 lb shipments Hydroxyl apatite in 50 lb bags Dodecylbenzene sulfonate in 5 gal cans Benzoyl peroxide in 300 lb drums Polybutadiene in 50 lb bales Hydrochloric acid in tank truck shipments... 

Water 0.12 Polybutadiene 0.005 Tricalcium Phosphate 0.00006 f Dodecylbenzene Sulfonate 0.0025 Benzoyl Peroxide 0.004 Misc. 

The additive feed tank must be large enough to handle all additives plus a carrier solution of styrene. The pounds of dodecylbenzene sulfonate, tricalcium phosphate, and benzoyl peroxide (50% water) used per batch are... 

Sodium dodecylsulfonate Sodium dodecylbenzene-sulfonate Cationic... 

From an analytical point of view, the use of anionic surfactants as enhancers of CL reactions is most limited. One of the most recent examples is the use of sodium dodecylbenzene sulfonate (SDBS) as a CL enhancer of the system Ru(hpy) - SO - KBr03 (bpy = 2,2 -bipyridyl) [60], The authors of this work propose the following mechanism for the chemiluminescent system ... 

The general procedure for dispersion involves use of sonication, which causes an unzipping mechanism of dispersion as proposed by Smalley and co-workers [51]. Typical surfactants used for this purpose are sodium dodecylsulfate (SDS) or sodium dodecylbenzene sulfonate (SDBS). The latter shows a stronger interaction as a result of the presence of the aromatic ring. It also appears that longer and more branched hydrocarbon chains interact more efficiently [52],... 

Uses Manufacture of ethylbenzene (preparation of styrene monomer), dodecylbenzene (for detergents), cyclohexane (for nylon), nitrobenzene, aniline, maleic anhydride, biphenyl, benzene hexachloride, benzene sulfonic acid, phenol, dichlorobenzenes, insecticides, pesticides, fumigants, explosives, aviation fuel, flavors, perfume, medicine, dyes, and many other organic chemicals paints, coatings, plastics and resins food processing photographic chemicals nylon intermediates paint removers rubber cement antiknock gasoline solvent for fats, waxes, resins, inks, oils, paints, plastics, and rubber. 

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