Overfill, liquid

Caution If overfilled ( liquid full ), liquefied gas cylinders can rupture due to hydrostatic pressure. Never exceed the legal fill weight. 

Second, when filling a pipet or volumetric flask, set the liquid s level exactly at the calibration mark. The liquid s top surface is curved into a meniscus, the bottom of which should be exactly even with the glassware s calibration mark (Figure 2.6). The meniscus should be adjusted with the calibration mark at eye level to avoid parallax errors. If your eye level is above the calibration mark the pipet or volumetric flask will be overfilled. The pipet or volumetric flask will be underfilled if your eye level is below the calibration mark. 

Location of Vacuum Relief Device (Carl Schiappa, Michigan Engineering, The Dow Chemical Company, Midland, Mich., personal communication, March 20, 1992.) If a vacuum relief device is used, locate the device at the highest point on the top of the tank. If the vacuum relief device is not installed in this location and the tank is overfilled with liquid, the relief device will be sealed in liquid and will be ineffec tive in protecting the tank. This is especially true for the part of the tank above the vacuum relief device if it is sealed in liquid, tne liquid level is lowered, and the tank goes into a partial vacuum. 

Thermal expan- Drum at proper temperature sion due to liquid, Keep drum away from heat source overfill leading to loss of reaction is complete before drumming containment. Allow adequate freeboard for each material CCPS G-3 CCPS G-14 CCPS G-22 CCPS G-29... 

Overfill drum due Calibrate weighing devices and maintain equip-to operator error ment in good working order or valve failure,. metering pumps can lead to opera- tor exposure, slip- fill operation with weighing device pery floors, spread of flammable liquids. CCPS G-3 CCPS G-15 CCPS G-22 CCPS G-29... 

Historical releases during transfer of materials into or out of storage Discharges of wash water or other liquids during operation or maintenance Overfills... 

Liquid is sometimes transferred from one tank to another b gravity. Overfilling has occurred when liquid flowed from a tall tank to a shorter one. On one occasion, an overflow occurred when liquid was transferred from one tank to another of the same height several hundred meters away. The operators did not realize that a slight slope in the ground was sufficient to cause the lower tank to overflow. 

Suppose a tank is designed to be filled at a rate of x mMrr. Many tanks, particularly those built some years ago, are provided with a vent big enough to pass v m /hr of air but not x m /hr of liquid. If the tank is overfilled, the delivery pump pressure will almost certainly be large enough to cause the tank to fail. 

In automatic systems the filler sets the quantity to be filled on a meter, which closes a valve when this required quantity has been delivered. Overfilling has occurred because the wrong quantity was set on the meter, because there was already some liquid in the tank (left over from the previous load), and because the filling equipment failed. For these reasons many companies now fit their tank trucks with high-level trips, which automatically close a valve in the filling line [8]. 

When a mechanical seal is specified, it shall be located at the cover plate to seal the vapor in the supply tank or vessel. Mechanical seals normally seal vapor however, they shall be designed to operate in liquid in the event of tank or vessel overfilling. With purchaser approval, the vendor may supply a seal pressurized by flush from the pump discharge or from an external source. External seal flush must be compatible with the liquid being pumped. The seal chamber shall have provisions for a high point vent. 

Fixed (cone) roof tanks Vent fire Overfill ground fire Unobstructed full liquid surface area Obstructed full liquid surface fire if frangible roof remains partially in tank For volatile liquids, the rich vapor space typically prevents ignition within the tank. Environmental regulations typically prevent storage of Class 1 flammable liquids in larger fixed roof tanks. 

Internal (or covered) floating-roof tanks Vent fire Overfill ground fire Obstructed rim seal fire Obstructed full liquid surface fire Many fires in this type of tank occur as a result of overfilling. Tank will be extremely difficult to extinguish if entire liquid surface becomes involved. Fires in tanks with pan type covers can be expected to develop into obstructed full liquid surface fires. 

Open floating-roof tanks Rim seal fire Overfill ground fire Obstructed full liquid surface fire Unobstructed full surface fire Application of fire water to the roof area should be carefully controlled to prevent overloading and sinking the roof when fighting a rim seal fire. 

In the spray regime, flooding (usually called jet flooding) is caused by excessive entrainment of liquid from an active area to the tray above. It increases the tray pressure-drop, and the entrained liquid recirculates to the tray below. The larger liquid load in the downcomer and the increased tray-pressure-drop together cause the downcomer to overfill so the tray floods. 

In the emulsion regime, there is little entrainment of liquid by the vapour. Instead, the high liquid load causes the downcomer to overfill and the tray to flood. 

When the baseline is stable, inject 15/iL of column standards. (Lab note Inj ect by overfilling the syringe, point the needle up, pull the barrel back until you can see the meniscus, tap out visible bubbles in the liquid, push the plunger to the 15- L mark, wipe outside the barrel with a lab wipe with a pulling motion. Insert into injector. Load the injector loop slowly, and leave the needle in place.) Thrn the injection handle quickly. Remove the injection needle, and flush three times with solvent. 

An automated solvent controller is available in the latest ASE system. It allows up to four solvents to be mixed and delivered to the extraction cells. This can reduce the time for measuring and mixing solvents and decrease users exposure to toxic solvents. The solvent controller can be programmed to change solvents between sequential extractions of multiple samples. The same sample can also be reextracted using different solvents. The ASE system has many built-in safety features, which include vapor sensors, liquid-leak detectors, vial overfill monitors, electronic and mechanical overpressurization prevention systems, solvent flow monitors, and pneumatic source pressure monitors. 

The fiberglass acid tank was out-of-service because it had just been washed. If the level in the acid tank was ever overfilled, the 4-inch (10 cm) overflow line would relieve into the adjacent chemical collection sewer. The sewer was scheduled for maintenance. As a precaution to protect the individuals assigned to repair the chemical collection sewer, an operations supervisor authorized the maintenance crew to blind the 4-inch (10 cm) overflow line. The operations supervisor provided instructions to the operators to limit the liquid level within the acid tank to a well-defined maximum. 

Unless a burette is automatic and one wishes to fill to the 0.00 mL mark, overfill the burette about 10 mm past the zero line. Let the liquid settle a minute, then release some of the liquid into a beaker or some other receptacle by slightly opening the stopcock. Let the fluid lower to the zero line. Wait another minute to allow the fluid to settle to the new level, and re-check the level of the meniscus at the zero line. Release or add more liquid as necessary. 

Limit the Amount of Moisture Near the Top of Your Cold Trap. A common error when first starting up a vacuum system is pouring liquid nitrogen too high into a Dewar. People often overfill Dewars in the early startup process... 

It is still necessary to have a small relief system to allow for thermal expansion of a liquid-full system. This relief system is also necessary for handling hydraulic overfill and fire conditions, but the system is usually relatively simple. 

How do we prevent overfilling any liquid vessels and overpressuring any units ... 

If any means of gaging is provided, it is a dip tube that blows off vapor until the liquid level reaches it. The possibility of error is significant. Overfilling frequently occurs. 

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