Salt metal nitrate

In a back titration, a slight excess of the metal salt solution must sometimes be added to yield the color of the metal-indicator complex. Where metal ions are easily hydrolyzed, the complexing agent is best added at a suitable, low pH and only when the metal is fully complexed is the pH adjusted upward to the value required for the back titration. In back titrations, solutions of the following metal ions are commonly employed Cu(II), Mg, Mn(II), Pb(II), Th(IV), and Zn. These solutions are usually prepared in the approximate strength desired from their nitrate salts (or the solution of the metal or its oxide or carbonate in nitric acid), and a minimum amount of acid is added to repress hydrolysis of the metal ion. The solutions are then standardized against an EDTA solution (or other chelon solution) of known strength. 

Nitric acid is a strong monobasic acid, a powerful oxidising agent, and nitrates many organic compounds. Until the end of the nineteenth century, it was made by heating a metallic nitrate salt with less volatile concentrated sulfuric acid. Removal of the volatile nitric acid permits the reaction to go to completion. This method is still used for laboratory preparation of the acid. 

Purified by recrystn from dioxane (white needles) and sublimes above 120°. It has been distilled, b 132-140°/4-8mm. It forms complexes with metals and gives a sparingly soluble nitrate salt, m 205 (dec), which crystallises from H2O and is dried at 150 . [UV Bosnich et al. Inorg Chem 4 1102 1963, van Alphen Reel Trav Chim Pays-Bas 56 343 1937.]... 

Cathodic deposition of lead sulfide from acidic aqueous solutions of Pb(II) ions (nitrate salts mainly) and Na2S203 on various metallic substrates at room temperature has been reported. Stoichiometric PbS films composed of small crystallites (estimated XRD diameter 13 nm) of RS structure were obtained at constant potential on Ti [204]. Also, single-phase, polycrystalline thin films of RS PbS were electrode-posited potentiostatically on Ti, Al, and stainless steel (SS) [205]. It was found that the Al and Ti substrates promoted growth of PbS with prominent (200) and (111)... 

The presence of Increased eunounts of NDPA in trlfluralin was observed In a matter 6f days In the tin containers stored at ambient temperatures. No corrosion Inhibitors were added to the tin containers. Container manufacturers use a flux In the tinning process, many contain either nitrite or nitrate salts. Thus, the potential for the nltrosatlng agents exists as part of the metallic film In a seemingly clean tin container. In addition. Archer and Wlshnok (1976) demonstrated the formation of nltrosamlnes from constituents of polymeric liners of metal cans. Container specifications are vital for pesticide formulations prone to be nltrosated. 

The addition reactions discussed in Sections 4.1.1 and 4.1.2 are initiated by the interaction of a proton with the alkene. Electron density is drawn toward the proton and this causes nucleophilic attack on the double bond. The role of the electrophile can also be played by metal cations, and the mercuric ion is the electrophile in several synthetically valuable procedures.13 The most commonly used reagent is mercuric acetate, but the trifluoroacetate, trifluoromethanesulfonate, or nitrate salts are more reactive and preferable in some applications. A general mechanism depicts a mercurinium ion as an intermediate.14 Such species can be detected by physical measurements when alkenes react with mercuric ions in nonnucleophilic solvents.15 The cation may be predominantly bridged or open, depending on the structure of the particular alkene. The addition is completed by attack of a nucleophile at the more-substituted carbon. The nucleophilic capture is usually the rate- and product-controlling step.13,16... 

Reactions of nitriles may be promoted by the presence of divalent Co. The conversion of sterically unhindered nitriles RCN (R = Me, Et, n-Pr, w-Bu) into the corresponding amidines RC(NH2) = NH occurs in the presence of Co(N03)2.6H20 and the ketoxime Me2C=NOH. The metal free amidinium ions were crystallized as their nitrate salts.358... 

The NSN donor ligand 5-(3,5-dimethylpyrazol-l-yl)-3-thia-l-pentaneamine forms 1 1 ligand-to-metal monomeric complexes with zinc chloride and nitrate salts.870... 

The catalysts which have been tested for the direct epoxidation include (i) supported metal catalysts, (ii) supported metal oxide catalysts (iii) lithium nitrate salt, and (iv) metal complexes (1-5). Rh/Al203 has been identified to be one of the most active supported metal catalysts for epoxidation (2). Although epoxidation over supported metal catalysts provides a desirable and simple approach for PO synthesis, PO selectivity generally decreases with propylene conversion and yield is generally below 50%. Further improvement of supported metal catalysts for propylene epoxidation relies not only on catalyst screening but also fundamental understanding of the epoxidation mechanism. 

The electrodeposited Bi2Sr2CaiCu2Ox (BSCCO) precursor films were obtained by co-electrodeposition of the constituent metals using nitrate salts dissolved in DMSO solvent. The electrodeposition was performed in a closed-cell configuration at room temperature ( 24°C). The cation ratios of the electrodeposition bath were adjusted systematically to obtain BSCCO precursor compositions. A typical electrolyte-bath composition for the BSCCO films consisted of 2.0-g Bi(N03)3-5H20,1.0-g Sr(N03)2, 0.6-g Ca(N03)2-4H20, and 0.9-g Cu(N03)2-6H20 dissolved in 400 mL of DMSO solvent. The substrates were single-crystal LAO coated with 300 A of Ag. 

METAL OXOHALOGENATES PEROXOACID SALTS METAL NITRITES METAL NITRATES METAL SULFATES METAL AMIDOSULFATES... 

Sonochemical routes also have been used to produce electroactive NPs. For example, metal hydroxides containing Ni(II), Co(II) and mixtures of both have been prepared from the appropriate metal nitrate salts using ammonium hydroxide as the hydrolytic agent [33,34]. This route produces metal-hydroxide NPs with diameters in the range of 2-10 nm. This method has been extensively applied in the synthesis of a wide variety of materials, including nanomaterials [35]. 

The extractabilities of metal-organic complexes depend on whether inner or outer sphere complexes are formed. Case 1, section 4.2.1, the extraction of ura-nyl nitrate by TBP, is a good example. The free uranyl ion is surrounded by water of hydration, forming U02(H20)f, which from nitric acid solutions can be crystallized out as the salt U02(H20)6 (N03), though it commonly is written U02(N03)2(H20)6. Thus, in solution as well as in the solid salt, the UOf is surrounded by 6 HjO in an inner coordination sphere. In the solid nitrate salt, the distance du.o(nitrate) between the closest oxygen atoms of the nitrate anions, (0)2N0, and the U-atom is longer than the corresponding distance, du-o(water), to the water molecules, OH2, i.e., du.o(nitrate) > 4u.o(water) thus the nitrate anions are in an outer coordination sphere. 

As known (Addison and Logan 1964), anhydrons nitrates exhibit oxidizing properties. Their oxidizing activity increases from ionic nitrates with alkali and alkali-earth metal cations to covalent nitrates with transient metal cations. Oxidation reactions result in the formation of nitrogen-containing oxides. Depending on the kind of a nitrate salt and reaction conditions, one of these oxides can be predominant. Organic snbstrates can evidently serve as reductant. 

A number of reagents derived from nitrate salts and acid anhydrides have been reported for the V-nitration of amides and related compounds. Crivello first reported the use of metal nitrates in trifluoroacetic anhydride (TFAA) for the nitration of aromatic systems. Chapman... 

Barium acetate converts to barium carbonate when heated in air at elevated temperatures. Reaction with sulfuric acid gives harium sulfate with hydrochloric acid and nitric acid, the chloride and nitrate salts are obtained after evaporation of the solutions. It undergoes double decomposition reactions with salts of several metals. For example, it forms ferrous acetate when treated with ferrous sulfate solution and mercurous acetate when mixed with mercurous nitrate solution acidified with nitric acid. It reacts with oxahc acid forming barium oxalate. 

The nitrate salt prepared by this method is hydrated. It cannot be dehydrated fully without decomposition. Anhydrous CuNOs may be prepared by dissolving copper metal in a solution of dinitrogen tetroxide, N2O4, in ethyl acetate. Upon crystaUization, an N2O4 adduct of Cu(N03)2 that probably has the composition [NO [Cu(N03)3] is obtained. This adduct, on heating at 90°C, yields blue anhydrous copper(II) nitrate which can be sublimed in vacuum at 150°C and coUected. 

Scandium forms all its compounds in 3+ oxidation state. This is the only valence known for the metal. These compounds include the oxide, SC2O3 hydroxide, Sc(OH)3 chloride, ScCls fluoride, ScFs sulfate, Sc2(S04)3, and the nitrate salt, Sc(N03)s. 

Boric acid (H 3 BO 3) - a solid material that is a weak H donor -is sometimes used as a neutralizer for base-sensitive compositions. Mixtures containing aluminum metal and a nitrate salt are notably sensitive to excess hydroxide ion, and a small percentage of boric acid can be quite effective in stabilizing such compositions. 

---