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Multiple functionalization

Several studies have demonstrated the successful incoriDoration of [60]fullerene into polymeric stmctures by following two general concepts (i) in-chain addition, so called pearl necklace type polymers or (ii) on-chain addition pendant polymers. Pendant copolymers emerge predominantly from the controlled mono- and multiple functionalization of the fullerene core with different amine-, azide-, ethylene propylene terjDolymer, polystyrene, poly(oxyethylene) and poly(oxypropylene) precursors [63,64,65,66,62 and 66]. On the other hand, (-CggPd-) polymers of the pearl necklace type were fonned via the periodic linkage of [60]fullerene and Pd monomer units after their initial reaction with thep-xy y ene diradical [69,70 and 71]. [Pg.2416]

AG and AH can be expressed as a multiplicative function of hydrogen bonding in different polar and nonpolar solvents by means of enthalpy acceptor factors E - enthalpy donor factors free energy acceptor factors Q, and free energy donor factors Q (Eqs. (32) and (33), where kj, 2- 3 [kcal/mol] are regression coefficients). [Pg.429]

Because the Multiflow had multiple functional units, it would simultaneously perform both A = B + C and D = E + F storing both results in registers. If the result of the comparison turned out to be false, then it would not store the result D back into memory, and the calculation would be discarded. Because the two operations were done in parallel, this method took no extra time. The integer operation, 7 = 7 -H 1, as well as four other operations, could also be performed simultaneously. [Pg.94]

Loops that could not be vectorized on conventional vector computers often performed very well under the Multiflow architecture and, unlike vector machines, for which a person could spend a great deal of time optimizing programs, substantially less could be done on the Multiflow, as most of the work fell to the compiler anyway. All the usual optimizations for memory utilization and cache usage also appHed to the Microflow. There were, of course, programs for which the compiler could not make good use of the multiple functional units, and the computer would mn at the speed of just one or two iadividually quite slow functional units. [Pg.94]

Silicone acrylates (Fig. 5) are again lower molecular weight base polymers that contain multiple functional groups. As in epoxy systems, the ratio of PDMS to functional material governs properties of release, anchorage, transfer, cure speed, etc. Radiation induced radical cure can be initiated with either exposure of photo initiators and sensitizers to UV light [22,46,71 ] or by electron beam irradiation of the sample. [Pg.546]

System event trees use the information on the effects of loss of various safety functions identified in the function event trees. However, the sequences in the system event trees are likely to differ somewhat from the function event trees because system faults may fail multiple functions. [Pg.116]

Energy systems in space technology are devices that convert one kind of energy into another to ensure the functioning of automated and piloted satellites, interplanetary probes, and other kinds of spacecraft. Multiple functions of any spacecraft require two distinctly different energy sources propulsion for launch and maneuvers, and electricity supply to power the onboard equipment. [Pg.1069]

Valves are classified by their intended use flow control, pressure control, and direction control. Some valves have multiple functions that fall into more than one classification. [Pg.612]

Ca2+-pumps. After entering the cell, Ca2+ is reversibly complexed to specific Ca2+-binding proteins that fiilfil multiple functions, including Ca2+-buffering and transport, activation of enzymes, regulation of contraction,... [Pg.1103]

Where multiple functions are required, units contain double or triple media beds employing, for example, acrylic beads, ceramic beads, and catalysts. Water Wizard, Inc. offers a multifunctional unit triple bed under the name TRION-3 . ... [Pg.332]

ThUgen C, Sergeyev S, Diederich F (2004) Spacer-Controlled Multiple Functionalization of Fullerenes. 248 1-61... [Pg.268]

By using monomers with different substituents, multiple functionalities could be introduced into the phenylacetylene oligomer at any desired position along the sequence backbone, resulting in macrocycles with a wide variety of symmetries (e.g. 47-53). In principle, this versatile synthetic method should allow construction of PAMs in which anyparticular group couldbe placed at any particular site. Judicious choice of the type and placement of functionalities has... [Pg.95]

Coughlan CM, McManus CM, Sharron M et al (2000) Expression of multiple functional chemokine receptors and monocyte chemoattractant protein-1 in human neurons. Neuroscience 97 591-600 Cunha FQ, Lorenzetti BB, Poole S, Ferreira SH (1991) lnterleukin-8 as a mediator of sympathetic pain. Br J Pharmacol 104 765-767... [Pg.186]

Figure 8.1 shows the number and proportion of professional and administrative staff responsible for registration, and the equivalent number of full-time personnel. For part-timers, if there are no data on the amount of work-time, it has been assumed that they work half-time (0.5). For Cypms and Zimbabwe, where staff perform multiple functions, the total numbers of staff have been used. [Pg.79]

Job enlargement and job enrichment methods may also be employed. The multiskilling approach used in Zimbabwe is one such strategy. The MCAZ streamlines its procedures and uses teamwork in the performance of dmg regulatory functions. Staff are trained to handle multiple functions. [Pg.133]

Figure 1.27 Standardized fluidic backbone for connecting micro-reactor components from different suppliers, yielding a small, compact micro-plant with multiple functions. Figure 1.27 Standardized fluidic backbone for connecting micro-reactor components from different suppliers, yielding a small, compact micro-plant with multiple functions.
The aim given above refers to the possibility of integration of multiple functions in a micro device here, this refers to the combination of flow processing and sensing [22]. [Pg.559]


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