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Metal ligand complex

Corey and Ishihara29 report the synthesis of a new bis(oxazoline). This catalyst effects Diels-Alder reaction via a tetracoordinated metal complex. Ligand (.S )-8I is synthesized from (iS )-phenylglycine, as depicted in Scheme 5-25. Treatment of 81 with Mgl2 L gives a dark solution of complex 82, which can be utilized as a Diels-Alder reaction catalyst. Thus, reaction of cyclopentadiene with 71 in the presence of 82 yields product 72a with an enantiomeric ratio of over 20 1 (Scheme 5-26). [Pg.287]

Hering, J. G. and Morel, F. M. M. (1990). Kinetics of trace metal complexation ligand-exchange reactions, Environ. Sci. Technol., 24, 242-252. [Pg.524]

The chelate effect is a celebrated feature of the chemistry of transition metal complexes. Ligands containing an increasing number of rings show several such ring order effects. [Pg.50]

Due to the particle size of Deloxan THP II and MP, these resins can be used in either batch or fixed bed mode to scavenge transition metals from contaminated process solutions. In this work both modes of operation were investigated. In addition to mode of use, many other variables can influence the effectiveness of a metal scavenger. Oxidation state of the metal, solvent characteristics (polar or nonpolar) and nature of the metal complex (ligands) are just a few of these variables and these were chosen for investigation in this body of work. [Pg.494]

Metal Complexation/Ligand Exchange Type CSPs... [Pg.214]

VII. Simple Metal, Simple Ligand Ga(III) Hydroxamates VIII. Simple Metal, Complex Ligand Mn(II) Carboxylates... [Pg.1]

VIII. Simple Metal, Complex Ligand Mn(ll) Carboxylates... [Pg.13]

Polyamino polyalkyl phosphonic acids have been investigated as potential complexors for alkaline earth metal complexes. Ligands investigated include nitrilotrimethylphosphonates (70),360 phosphoryl derivatives of polyamines (71)361 and monoalkylphosphonic acids.362 They show complexing capability towards Be2+, Mg24-, Ca2+, Sr24" and Ba, but are not as efficient... [Pg.33]

Electron densiity, in lead triacetate arylations, 9, 397 Electron donor number, transition metal complex ligands and unchanging coordination number, 1, 12 and variable coordination number, 1, 12 Electron energy loss spectroscopy, dihydrogen binding on surfaces, 1, 682 Electronic effects... [Pg.101]

Octahedral Metal Complexes Ligand-to-Metal Charge Transfer... [Pg.203]

Baham, J. and Sposito, G., Chemistry of water-soluble, metal-complexing ligands extracted from an anaerobically digested sewage sludge, J. Environ. Qual., 12, 96, 1983. Berggren, D. et al., Metal solubility and pathways in acidified forest ecosystems of South Sweden, Sci. Total Environ., 96, 103, 1990. [Pg.274]

Other SO types and selectivity principles used in CE are related to polysaccharides (e.g. heparin, chondroitin sulphate, dextrin, etc.) (reviewed by Nishi 475 ). chiral crown-ethers, e.g. 18-crown-6 tetracarboxylic acid 293,476 and chiral metal complexes (ligand-exchange electrophoresis) 477. ... [Pg.435]

Chiral Separation Where the Leading Interaction Is Established Through Metal Complexes (Ligand Exchange)... [Pg.373]

Metal-complexing ligands, including humic and fulvic acids, by preferentially com-plexing with Fe or Fe " actually shift the redox potential of soil solutions. This fact can be illustrated simply by considering the Nernst equation for the Fe /Fe redox couple (see Table 7.1) ... [Pg.262]

The subject of heterolytic activation of Hj by transition metal complexes has been critically reviewed. Equation (a) illustrates the heterolytic splitting of Hj by a divalent metal complex. Ligand X is typically anionic, and the reaction involves a net substitution... [Pg.121]


See other pages where Metal ligand complex is mentioned: [Pg.62]    [Pg.76]    [Pg.615]    [Pg.707]    [Pg.439]    [Pg.70]    [Pg.316]    [Pg.933]    [Pg.306]    [Pg.1]    [Pg.78]    [Pg.459]    [Pg.99]    [Pg.294]    [Pg.189]    [Pg.240]    [Pg.365]    [Pg.366]    [Pg.182]    [Pg.4]    [Pg.3]    [Pg.11]    [Pg.96]    [Pg.28]    [Pg.122]    [Pg.156]    [Pg.204]    [Pg.654]   
See also in sourсe #XX -- [ Pg.72 , Pg.73 ]




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1,1-Dithiolato metal complexes ligands

About C Ligands in Transition Metal Complexes

Acyclic unsaturated ligands metal complexes

Bipyridine ligands metal complexes

Bis(pentadienyl)metal Complexes with Additional Ligands

Catalysts from metal complexes with organic ligands

Chelating ligands metallic complexes

Chiral metal complexes ligand transformation

Chromium complexes metal-ligand multiple bonds

Complex Formation involving Unsubstituted Metal Ions ultidentate Ligands

Complexes, metal, ligand, hydroxo

Diketonate ligands, polymeric metal complexes

Disulfido ligands metal complexes

Dithiolene metal complexes ligands

Dynamic Behavior of d Transition Metal Complexes with n-Donor Two-Center Ligands

Ferrocenes as Ligands in Metal Complexes

Fullerenes as Ligands in Metal Complexes

Germanium ligands transition metal complexes

Hague 1 Complex Formation involving Unsubstituted Metal Ions Unidentate Ligands and Solvent Exchange

Imido ligands transition metal complexes with

Inert metal complexes ligand

Inorganic Diazo Compounds and Metal Complexes with Dinitrogen as Ligand

Interaction of ancillary ligand with fluorescent metal complexes within the MIP

Isocyanide ligands insertion reactions with metal complexes

Lanthanide complexes ligand-metal energy-transfer efficiency

Less Known Redox-active Ligands in Metal Complexes

Ligand Substitution in Transition Metal ir-Complexes

Ligand Substitution in Transition Metal w-Complexes

Ligand metal complexes, adsorption

Ligand substitution reactions transition metal complexes

Ligand substitution, metals/metal complexes

Ligand synthesis metal ligands, palladium complexes

Ligand-metal charge transfer complexes

Ligand-metal complexation equilibria

Ligand-to-metal charge transfer d complexes

Ligands and Metal Complexes for Large-Scale Applications

Ligands in transition metal complexes

Ligands metal complexing

Ligands mixed-metal complexation

Macrocyclic ligands alkali metal complexes

Macrocyclic ligands alkaline earth metal complexes

Macrocyclic ligands metal complexes

Macrocyclic ligands metal ion complexes

Macrocyclic ligands transition metal complexes

Macrocyclic ligands, complexation hard metal ions

Macrocyclic ligands, complexation soft metal ions

Macropolycyclic ligands metal complexes

Mercury complexes metal ligands

Mercury complexes transition metal ligands

Metal Complexes of Chiral Ligands

Metal Complexes with Ligands Bearing a Non-coordinating Organoazide Unit

Metal Complexes with Reducible Ligands

Metal Complexes with an Intact, Coordinating and Linear Organoazide Ligand

Metal Complexes with an Intact, Coordinating but Bent Organoazide Ligand

Metal complexation different ligands variety

Metal complexes coordinated ligand reactions

Metal complexes ligand substitution mechanisms

Metal complexes organoazide ligands

Metal complexes with organic ligands

Metal diimine-dithiolene complexes mixed-ligand

Metal groups ligands, palladium complexes

Metal ligand complex, acting

Metal ligand complex, acting nucleophile

Metal-carbene complexes ligand substitution reactions

Metal-ligand bonds carbene complexes

Metal-ligand bonds silylene complexes

Metal-ligand complex, stoichiometry

Metal-ligand complexation

Metal-ligand complexation reactions

Metal-ligand complexes 18-electron rule

Metal-ligand complexes electron counting

Metal-ligand complexes geometries

Metal-ligand complexes molecular orbitals

Metal-ligand complexes stability constants

Metal-ligand complexes, oxidation potentials

Metal-ligand cooperation complex

Metal—ligand bonds complex hydrides

Mixed-ligand complexes, transition metal

Mixed-ligand complexes, transition metal chromium

Mixed-ligand complexes, transition metal group

Mixed-ligand complexes, transition metal structural studies

Molybdenum complexes metal-ligand multiple bonds

Monodentate ligand-metal complexes

Nickel complexes metal-sulfur ligand structures

Nitro ligands metal complex catalysts

Nitrogen complexes metal-ligand multiple bonds

Nitrogen ligands, transition metal dithiocarbamate complexes

Organic ligands metal complexes

Organoazides metal complexes with ligands

Organometallic Compounds and Metal-Ligand Complexes

Organometallic and Metal-Ligand Complexes

Organometallic complexes, ligand metal interaction

Organometallics and Metal-Ligand Complexes

Palladium Complexes Containing Metal Ligands

Phosphine-metal complexes ligands

Polydentate ligands mixed-metal complexation

Polymer-supported ligand-metal complexes

Polymeric ligands, transition metal polymer complexes

Polymeric metal complexes with cyclic ligands

Polypyridyl ligands metal complexes

Polysulfide ligands metal complexes

Porphyrins (and Tetraazaporphyrins) as Ligands in Metal Complexes

Preparation of Olefin Complexes from Hydrocarbon Ligands Coordinated to the Metal

Properties of Metal Ion-Ligand Complexes

Pseudobases of Metal Complexes Containing Heterocyclic Ligands

Quenching of the fluorescence from metal ligand complexes

Rare earth metal complexes ligands

Reactivity of metallic complexes deriving from ambiphilic ligands

Silicon ligands transition metal complexes

Solubilized metal-ligand complexes

Square-planar /8 metal dithiolenes mixed-ligand complexes

Stabilization of Metal d-Electrons in Mixed-Ligand Complexes

Structure of Metal Complexes Containing Arenediazonium Ions as Ligands

Sulfur ligand, metal complexes

Supramolecular Construction of Chelating Bidentate Ligand Libraries through Hydrogen Bonding Concept and Applications in Homogeneous Metal Complex Catalysis

Surface-metal-ligand complexes

Synthesis of Carbene Ligands and Their Metal Complexes

Synthesis of Metal Complexes Containing Chelated Allyl Ligands

Tetraazatetraenato Ligands and Their Metal Complexes

Tetranuclear d-block metal complexes ligands

Thiolate ligands metal complex formation

Thiometalate ligands metal complexes

Transition Metal Complexes Containing Anionic or Cationic Ligands

Transition Metal Complexes Containing Bidentate Phosphine Ligands

Transition Metal Complexes of Cyclopentadienyl Ligands

Transition Metal Complexes of Polydentate Amido Ligands

Transition Metal Complexes with CO, N2, NO and O2 Ligands

Transition Metal Ions and their Complexes Ligand Field Theory

Transition metal alkoxide complexes ligands

Transition metal complexes bearing a phosphenium ligand

Transition metal complexes bridging ligands

Transition metal complexes carbonyl ligands stretching modes

Transition metal complexes containing all-carbon ligands

Transition metal complexes ligand electronic structure

Transition metal complexes ligand electrons

Transition metal complexes ligand site preferences

Transition metal-ligand complex

Transition metal-ligand complex formation

Uncharged Metal-Ligand Complexes

Unsaturated organic ligands, complexed with more metals

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