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Chromium complexes metal-ligand multiple bonds

The bond order in complexes with very short metal-metal bonds has been controversial. Various calculations have given bond orders as low as 3.3 for fivefold bonded chromium(I) complexes. Factors such as the influence of bridging ligands on metal-metal distances, nonlinearity in Power s original complex that may reduce orbital interactions, and more complex interactions beyond the scope of this text are factors that merit consideration. The reader is encouraged to cousult the sources cited for discussions of the numerous factors involved in Cr—Cr multiple bonds in these dimers. Explorations of the reactivity of these new bonds are underway, with a particular emphasis on small molecule activation chemistry. " ... [Pg.596]

See other pages where Chromium complexes metal-ligand multiple bonds is mentioned: [Pg.57]    [Pg.191]    [Pg.21]    [Pg.24]    [Pg.126]    [Pg.330]    [Pg.31]    [Pg.90]    [Pg.610]    [Pg.281]    [Pg.259]    [Pg.705]    [Pg.17]    [Pg.735]    [Pg.148]    [Pg.40]   
See also in sourсe #XX -- [ Pg.303 , Pg.304 ]

See also in sourсe #XX -- [ Pg.303 , Pg.304 ]



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Chromium complexes, metalation

Ligand Multiple Bonds

Ligands metal-ligand bonds

Metal Chromium Complexes

Metal complexes ligand

Metal multiple

Metal multiple bonds

Metal multiple-bonded complexes

Metal-ligand bonding

Metal-ligand bonds

Metal-ligand bonds multiple

Metallic Chromium

Metals chromium

Metals metal-ligand bond

Multiple ligand

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