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Complexation reactions ligand exchange

Cleavage of tetraaminoethylenes has been most frequently used in the preparation of imidazolidin-2-ylidene complexes. The ligand exchange reaction. [Pg.30]

The direct approach to heterocarbonyl complexes by ligand exchange reactions is usually restricted to heteroketone complexes, as suitable and... [Pg.146]

Thio- and Selenocarbonyl Complexes by Ligand-Exchange Reactions with Metal Complexes. [Pg.253]

Stability of Metal Complex. - The stability of the metal complex towards ligand exchange reaction plays a major role in determining the mechanism by which the metal complex becomes anchored to the surface. The ligand exchange mechanism for anchoring the metal complex to the surface proceeds as... [Pg.84]

Mimoun has given an alternative possibility, suggesting the formation of peroxo metallacyclic adducts following complexafion of the olefin to the metal [171,475]. The reaction sequence (Fig. 1.13) involves a reactive species denoted as Ln-Mo, a Mo(VI) ion with a set of alkoxy ligands. The reaction starts by formation of an alkylperoxo Mo complex by ligand exchange of an alkylperoxide with an alcohol. This is followed by complexafion of the olefin by a coordination bond. A subsequent peroxy metallation of the olefin produces a five-membered... [Pg.50]

Carbamoyl complexes from metal carbonyls and amines 5.8.2.12.4 Carbanions reactions with alkene complexes 5.8.2.3,4 metal carbonyls 5.8.2.S.5 Carbene complexes by alkene metathesis 5.8.2.3.11 formation 5.8.2.8.5 Carbides alkali metal formation 5.10.2.1 bonding 5.10.2 formation 5.10.2 industrial uses 5.10.2 interstitial formation 5.10.2 Carbometallacycle formation 5.S.2.2.2 Carbometallacycles from n-allyl complexes 5.S.2.3.9 Carbon reaction with alkali metals 5.10.2.1 Carbon dioxide complexes formation 5.8.2.14.1 Carbon monoxide displacement by alkenes 5.8.2.3.1 Carbonyl complexes by ligand exchange 5.8.2.12.2 from carbon monoxide 5.8.2.12.1, 5.8.2.12.2... [Pg.449]

Examples include studies of enzyme-substrate complexes [38], mixed complexes in ligand exchange reactions [39], and flash photolysis [40] or electrochemical reactions [41]. [Pg.189]

Reactions of cupric inner complex salts—Ligand exchange s. 17,464... [Pg.148]

Without additional reagents Reactions of cupric inner complex salts Ligand exchange Transamination... [Pg.106]


See other pages where Complexation reactions ligand exchange is mentioned: [Pg.50]    [Pg.107]    [Pg.807]    [Pg.391]    [Pg.521]    [Pg.15]    [Pg.34]    [Pg.927]    [Pg.1077]    [Pg.207]    [Pg.261]    [Pg.278]    [Pg.278]    [Pg.15]    [Pg.1990]    [Pg.3302]    [Pg.5470]    [Pg.233]    [Pg.234]    [Pg.262]    [Pg.87]    [Pg.1439]    [Pg.318]    [Pg.86]    [Pg.207]    [Pg.324]    [Pg.166]    [Pg.307]    [Pg.104]    [Pg.1989]    [Pg.3301]    [Pg.5469]    [Pg.1723]    [Pg.21]    [Pg.44]    [Pg.154]    [Pg.807]   


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Ligand exchange

Ligand exchange reactions

Ligands ligand exchange

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