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Synthesis of Metal Complexes Containing Chelated Allyl Ligands

Diolefins, monoolefins, and transition metal compounds give l-a-alkyl-4, 5, 6-allyl chelated complexes during irradiation with ultraviolet light [equation (7.42)]. [Pg.447]

Similar compounds are formed as a result of ring opening of cyclopropane in bicyclic compounds during their reactions with metal carbonyls [equation (7.43)]. In [Pg.447]

Allenes may react with PdClj to furnish jt-allyl derivatives (see allene complexes) [equations (7.45) and (7.46)]. [Pg.448]

The complex [RhCl2(2-MeC3H4)] may be prepared by heating a saturated solution of rhodium(III) chloride in rert-butyl alcohol.  [Pg.448]

Metal allyl halogen compounds may be synthesized by reactions of M(allyl) with hydrogen halides, allyl halides, halogens, etc. for instance. [Pg.449]


See other pages where Synthesis of Metal Complexes Containing Chelated Allyl Ligands is mentioned: [Pg.447]   


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1.1- allyl metals

Allyl complexes synthesis

Allyl ligand

Allyl synthesis

Allylation complexes

Allylic ligand

Allylic metalation

Allylic synthesis

Chelat complex

Chelate complexes

Chelate ligands

Chelated ligand

Chelates metalation

Chelates of metals

Chelating complexes

Chelating ligands metallic complexes

Chelation synthesis

Chelator, synthesis

Complex allyl

Complexation/chelation

Complexes Containing

Complexes of Ligands

Complexity of ligands

Ligand containing

Ligand synthesis

Ligands chelation

Ligands, metal-containing

Metal chelate complexes

Metal chelates

Metal chelating

Metal chelation

Metal chelator

Metal chelators

Metal complexes ligand

Metal complexes, synthesis

Synthesis of metal complexes

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