Lanthanum conductivity

Reduction of sulfur dioxide by methane is the basis of an Allied process for converting by-product sulfur dioxide to sulfur (232). The reaction is carried out in the gas phase over a catalyst. Reduction of sulfur dioxide to sulfur by carbon in the form of coal has been developed as the Resox process (233). The reduction, which is conducted at 550—800°C, appears to be promoted by the simultaneous reaction of the coal with steam. The reduction of sulfur dioxide by carbon monoxide tends to give carbonyl sulfide [463-58-1] rather than sulfur over cobalt molybdate, but special catalysts, eg, lanthanum titanate, have the abiUty to direct the reaction toward producing sulfur (234). 

The anode material in SOF(7s is a cermet (rnetal/cerarnic composite material) of 30 to 40 percent nickel in zirconia, and the cathode is lanthanum rnanganite doped with calcium oxide or strontium oxide. Both of these materials are porous and mixed ionic/electronic conductors. The bipolar separator typically is doped lanthanum chromite, but a metal can be used in cells operating below 1073 K (1472°F). The bipolar plate materials are dense and electronically conductive. 

In the next step of the sequence, the authors sought to introduce a hydroxy-methylene substituent at the unsubstituted 7-position of the enone. This bond construction can be carried out by conducting a Baylis-Hillman reaction with formaldehyde. In this instance, the authors used a modification of the Baylis-Hillman reaction which involves the use of a Lewis acid to activate the enone [26]. Under these conditions, the enone 42 is treated with excess paraformaldehyde in the presence of triethylphosphine (1 equiv), lanthanum triflate (5 mol%), and triethanolamine (50 mol%). It is proposed that the lanthanum triflate forms a complex with the triethanolamine. This complex is able to activate the enone toward 1,4-addition of the nucleophilic catalysts (here, triethylphosphine). In the absence of triethanolamine, the Lewis acid catalyst undergoes nonproductive complexation with the nucleophilic catalyst, leading to diminution of catalysis. Under these conditions, the hydroxymethylene derivative 37 was formed in 70 % yield. In the next step of the sequence, the authors sought to conduct a stereoselective epoxidation of the allylic... 

At the other end of the conduction spectrum, many oxides have conductivities dominated by electron and positive hole contributions to the extent that some, such as Re03, SnC>2 and the perovskite LaCrCb have conductivities at the level of metallic conduction. High levels of p-type semiconduction are found in some transition metal perovskites especially those containing alio-valent ions. Thus the lanthanum-based perovskites containing transition metal ions, e.g. LaM03 (M-Cr, Mn, Fe, Co, Ni) have enhanced p-type semiconduction due to the dependence of the transition metal ion valencies on the ambient... 

The superconducting oxides include both perovskites and Ruddlesden-Popper compounds which have an orthorhombic arrangement of cubic cells, alternatively of the perovskite and sodium chloride structures. The common feature of all of these is the presence of copper as a major component. The first ceramic superconductor was a lanthanum-strontium substituted cuprate (Lai Sr Cu04 z), which is a perovskite, but subsequently the inter-oxide compound Y203 2BaO 3CuO, commonly referred to as a 123 compound, was shown to have superior performance. The speculation concerning the conduction mechanism is that this involves either Cu3+-Cu2+ positive hole... 

These incorporate membranes fabricated from insoluble crystalline materials. They can be in the form of a single crystal, a compressed disc of micro-crystalline material or an agglomerate of micro-crystals embedded in a silicone rubber or paraffin matrix which is moulded in the form of a thin disc. The materials used are highly insoluble salts such as lanthanum fluoride, barium sulphate, silver halides and metal sulphides. These types of membrane show a selective and Nemstian response to solutions containing either the cation or the anion of the salt used. Factors to be considered in the fabrication of a suitable membrane include solubility, mechanical strength, conductivity and resistance to abrasion or corrosion. 

Nelson Relating to the proximity, we have probed this area by looking at sparks and the communication in the large conductance Ca2+-activated K+ (BK) channels. The measurements are consistent with close apposition of the RyRs and spark sites to the BK channels. This would be consistent with a proximity of 10—20 nm seen by electron microscopy. Also, mobile buffers are unable to compete with Ca2+ at the BK channel, which is also consistent with this idea. As a probe of what happens to local Ca2+ we have looked at the decay of a spark. Nothing we could do, such as zero Na+ or lanthanum, had any effect on the decay, suggesting that diffusion was responsible. 

Oxygen Tracer Diffusion Coefficient (D ), Oxygen Surface Exchange Coefficient (Ar) and Oxygen Ionic Conductivity (a, in air) of Doped Lanthanum Cobalt Ferrite-Based Perovskites... 

The suitability of lanthanum nickelate as an SOFC cathode has been examined by Virkar s group [138], They showed that LN performed poorly as a single-phase cathode in an anode-supported YSZ cell. However, with an SDC/LN composite interlayer the performance of the LN cathode increased substantially and the maximum power density of the cell with a YSZ thin electrolyte (-8 pm) was -2.2 Wear2 at 800°C, considerably higher than 0.3 to 0.4 Wcm-2 of similar cells with only LN or SDC interlayer. The results are significant as it shows that the composite MIEC cathodes perform much better than single-phase MIEC in the case of LN despite its mixed ionic and electronic conductivity. 

Lanthanum chromite is a p-type conductor so divalent ions, which act as electron acceptors on the trivalent (La3+ or Cr3+) sites, are used to increase the conductivity. As discussed above, the most common dopants are calcium and strontium on the lanthanum site. Although there is considerable scatter in the conductivities reported by different researchers due to differences in microstrucure and morpohology, the increase in conductivity with calcium doping is typically higher than that with strontium doping [4], The increase in conductivity at 700°C in air with calcium additions is shown in Figure 4.1 [1, 2, 28-44], One of the advantages of the perovskite structure is that it... 

Lanthanum chromite is the most common base for SOFC interconnects, but chromites of other lanthanide elements have also been used [43, 45, 46, 48, 54, 55], Although the conductivity of calcium-doped gadolinium chromite for low calcium contents is in the upper range of conductivities for lanthanum chromite, other nonlanthanum chromites typically have lower conductivities. However, the use of other lanthanides provides benefits in controlling the phase transformation temperature and in potential cost savings [48],... 

Webb JB, Sayer M, and Mansingh A. Polaronic conduction in lanthanum strontium chromite. Can. J. Phys. 1977 55 1725-1731. 

Sakai N, Kawada T, Yokokawa H, Dokiya M, and Iwata T. Sinterability and electrical conductivity of calcium-doped lanthanum chromites. J. Mater. Sci. 1990 25-,4531-4534. 

Yasuda I and Hikita T. Electrical conductivity and defect structure of calcium-doped lanthanum chromites. 7. Electrochem. Soc. 1993 140 1699-1704. 

Tanasescu S, Orasanu A, Berger D, Jitaru I, and Shoonman J. Electrical conductivity and thermodynamic properties of some alkaline earth-doped lanthanum chromites. Int. J. Thermophysics 2005 26 543-557. 

Kumar A, Devi PS, and Maiti HS. A novel approach to develop dense lanthanum calcium chromate sintered ceramics with very high conductivity. Mater. Chem. 2004 16 5562-5563. 

Yasuda I and Hishinuma M. Electrical conductivity and chemical diffusion coefficient of Sr-doped lanthanum chromites. Solid State Ionics 1995 80 141-150. 

Bansal KP, Kumari S, Das BK, and Jain BC. Electrical conduction in titania-doped lanthanum chromite ceramics. J. Mater. Sci. 1981 16 1994—1998. 

Suzuki M, Sasaki H, and Kajimura A. Oxide ion conductivity of doped lanthanum chromite thin film interconnects. Solid State Ionics 1997 96 83-88. 

To meet the requirements for electronic conductivity in both the SOFC anode and cathode, a metallic electronic conductor, usually nickel, is typically used in the anode, and a conductive perovskite, such as lanthanum strontium manganite (LSM), is typically used in the cathode. Because the electrochemical reactions in fuel cell electrodes can only occur at surfaces where electronic and ionically conductive phases and the gas phase are in contact with each other (Figure 6.1), it is common... 

To introduce a barrier layer when utilizing doped ceria electrolytes (SDC, GDC, or lanthanum-doped ceria, LDC) to prevent the reduction of Ce4+ to Ce3+. Reduction of cerium cations results in unwanted electronic conductivity that lowers fuel efficiency [34], and mechanical degradation that results from the volume expansion of cerium ions upon reduction [35],... 

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