Interphase design importance

Internal recycle reactors are designed so that the relative velocity between the catalyst and the fluid phase is increased without increasing the overall feed and outlet flow rates. This facilitates the interphase heat and mass transfer rates. A typical internal flow recycle stirred reactor design proposed by Berty (1974, 1979) is shown in Fig. 18. This type of reactor is ideally suited for laboratory kinetic studies. The reactor, however, works better at higher pressure than at lower pressure. The other types of internal recycle reactors that can be effectively used for gas-liquid-solid reactions are those with a fixed bed of catalyst in a basket placed at the wall or at the center. Brown (1969) showed that imperfect mixing and heat and mass transfer effects are absent above a stirrer speed of about 2,000 rpm. Some important features of internal recycle reactors are listed in Table XII. The information on gas-liquid and liquid-solid mass transfer coefficients in these reactors is rather limited, and more work in this area is necessary. 

Consider now the effect of uncompensated iR on the shape of the potentiostatic transients. This was shown in Fig. 6D. The point to remember is that although the potentiostat may put out an excellent step function - one with a rise time that is very short compared to the time of the transient measured - the actual potential applied to the interphase changes during the whole transient, as the current changes with time (cf. Section 10.2). This effect is not taken into account in the boundary conditions used to solve the diffusion equation, and the solution obtained is, therefore, not valid. The resulting error depends on the value of R, and it is very important to minimize this resis-tance, by proper cell design and by electronic iR compensation. 

Reactive distillation (RD) processes are often designed from equilibrium assumptions for chemical reactions and interphase phenomena. Equilibrium-based design leads to important implications for the feasibility of RD. However, most of the chemical reactions carried out in RD columns are kinetically controlled and they can be strongly affected by the limitations of inter- or intraphase mass- and energy-transport resistances. 

Two-phase flow in three-phase fixed-bed reactors makes the reactor design problem complex [12], Interphase mass transfer can be important between gas and liquid as also between liquid and catalyst particle. Also, in the case of trickle-bed reactors, the rivulet-type flow of the liquid falling through the fixed bed may result (particularly at low liquid flow rates) in only part of the catalyst particle surface being covered with the liquid phase. This introduces a third mass transfer process from gas to the so-called gas-covered surface. Also, the reaction rates in three-phase fixed-bed catalytic reactors are highly affected by the heat transfer resistances resistance to radial heat transfer and resistance to fluid-to-particle heat transfer. As a result of these and other factors, predicting the local (global) rate of reaction for a catalyst particle in three-phase fixed-bed reactors requires not only... 

Abstract Multicomponent materials based on synthetic polymers were designed and used in a wide variety of common and hi-tech applications, including the outdoor applications as well. Therefore, their response to the UV radiation and complex weathering conditions (temperature, seasonal or freeze—thaw cycles, humidity, pH, pollutants, ozone, microorganisms) is a matter of utmost importance in terms of operational reliability and lifetime, protection of the environment and health safety. This chapter offers an overview of this subject and a critical assessment of more particular topics related to this issue. Thus, various types of multicomponent systems based on thermoplastic and thermosetting polymer matrices were subjected to natural and/or simulated UV radiation and/or weathering conditions. Their behavior was evaluated in correlation with their complex formulation and taking into consideration that the overall effect is a sum of the individual responses and interactions between components. The nature and type of the matrix, the nature, type and size distribution of the filler, the formation of the interphase and its characteristics, the interfacial adhesion and specific interfacial interactions, they all were considered as factors that influenced the materials behavior, and, at the same time, were used as classification criteria for this review. 

For the polymer scientist, consideration of these Ro distances is one of the most important aspects of experimental design. Emission quenching is the tool of choice for studying problems of int rfaces and interphases. One labels one component with a dye A and the other component with Q. Studying the rate and efficiency whereby Q quenches A provides a powerful measure of molecular intimacy in the overlap region. There are other applications pertinent to studying polymer conformation and dynamics. 

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