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Electrochemical interface.

Describe clearly the challenges of interfacing electrochemical detectors to capillary electrophoresis separation systems. How can these challenges be overcome ... [Pg.99]

The flow of an anodic current oxidizes the conducting polymer and the film swells. At the polypyrrole/tape interface, electrochemically stimulated conformational changes in the polymer promote an expansion that... [Pg.344]

Stradins, J., Turovska, B Glezer, V., Markava, E Gustina, D J. Elec-troanal. Chem. Interfac. Electrochem. 1991, 317, 243. [Pg.369]

We carried out some measurements some years ago in order to measure the transfer coefficient in DMF for this couple at a mercury electrode [Hush, N. S. Dyke, J. M. J. Electroanal. Interfac. Electrochem. 1974, 53, 253]. The deviation from one-half for the value so obtained was consistent with reasonable values for the free energy of activation of ligand exchange in the inner-coordination spheres. [Pg.212]

Harten, I960] H. U. Harten, J. Phys. Chem. Solids, 14,22(K1960). [McEvoy-Etman-Memming, 1985] A. J. McEvoy, M. Etman and R. Memming, J. Electroanal. Interface. Electrochem., 190,225(1985). [Pg.371]

Angerstein-Kozlowska H., Conway B.E., Sharp W.B.A., Electroanal. Chem. Interfac. Electrochem, 43 (1973) 9. [Pg.35]

Fenton, J. M. Electrochemistry Energy, Environment, Efficiency, and Economics, Interface, Electrochem. Soc. 1994, 3, 38-44. [Pg.274]

The Continuous Flow of Electrons across an Interface Electrochemical Reactions... [Pg.8]

Memming R, Neumann G (1969) J Electroanal Chem Interfac Electrochem 21 295... [Pg.177]

Understanding chemical reactivity at liquid interfaces is important because in many systems the interesting and relevant chemistry occurs at the interface between two immiscible liquids, at the liquid/solid interface and at the free liquid (liquid/vapor) interface. Examples are reactions of atmospheric pollutants at the surface of water droplets[6], phase transfer catalysis[7] at the organic liquid/water interface, electrochemical electron and ion transfer reactions at liquidAiquid interfaces[8] and liquid/metal and liquid/semiconductor Interfaces. Interfacial chemical reactions give rise to changes in the concentration of surface species, but so do adsorption and desorption. Thus, understanding the dynamics and thermodynamics of adsorption and desorption is an important subject as well. [Pg.661]


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See also in sourсe #XX -- [ Pg.267 , Pg.273 , Pg.375 , Pg.382 , Pg.393 , Pg.397 ]




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