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Spectroscopy at Electrochemical Interfaces

The excitation of a SPP is also a valuable tool for the study of an electrochemical interface. It can be used in situ in an electrochemical cell and can provide information on the structure and electronic properties of the electrodeelectrolyte interface in the region of transparency of the solution ( 1 eV to 6 eV). This method is especially useful for the investigation of adsorption isotherms because the chemical potential of an adsorbate and, therefore. [Pg.132]

Iwasita T and Mart F C 1997 In situ infrared spectroscopy at electrochemical interfaces Prog. Surf. Sc/. 55 271... [Pg.320]

Iwasita T, Nart FC. 1997. In situ infrared spectroscopy at electrochemical interfaces. Prog Surf Sci 55 271-340. [Pg.267]

Adsorbed carbon monoxide is a matter of special interest in ultrahigh vacuum as well as in electrochemical systems. CO has been used as probe molecule in surface vibrational spectroscopy. For important reviews of CO adsorbed from the gas phase, see [21, 42, 45, 46]. The rather large dynamic dipole moment (9///0Q) of adsorbed CO is particulary suited for infrared spectroscopy at electrochemical interfaces, where submonolayer amounts of species must be observed in the presence of IR-active solution compontents. [Pg.147]

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