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Infrared spectroscopy FTIR spectra

The Fourier transform infrared spectroscopy (FTIR) spectra in Figure 7.15 are for BT-08 before and after chemical treatment for different durations. The... [Pg.675]

Fourier transform infrared spectroscopy (FTIR) spectra of zirconia powder ... [Pg.377]

Figure 7.6 Fourier Transform Infrared Spectroscopy (FTIR) spectra of pristine and functionalized CNTs. From [47]. Figure 7.6 Fourier Transform Infrared Spectroscopy (FTIR) spectra of pristine and functionalized CNTs. From [47].
In recent years, infrared spectroscopy has been enhanced by the possibility of applying Fourier transform techniques to it. This improved spectroscopic technique, known as Fourier transform infrared spectroscopy (FTIR), is of much greater sensitivity than conventional dispersive IR spectroscopy (Skoog West, 1980). Moreover, use of the Fourier transform technique enables spectra to be recorded extremely rapidly, with scan times of only 0-2 s. Thus it is possible to record spectra of AB cements as they set. By comparison, conventional dispersive IR spectroscopy requires long scan times for each spectrum, and hence is essentially restricted to examining fully-set cements. [Pg.364]

Fourier transform infrared spectroscopy (FTIR) and proton nuclear magnetic resonance spectroscopy ( ll NMR) have become standards for verifying the chemistry of polyanhydrides. The reader is referred to the synthesis literature in the previous section for spectra of specific polymers. The FTIR spectrum for PSA is shown in Fig. 2. In FTIR the absorption... [Pg.189]

The secondary structure of proteins may also be assessed using vibrational spectroscopy, fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy both provide information on the secondary structure of proteins. The bulk of the literature using vibrational spectroscopy to study protein structure has involved the use of FTIR. Water produces vibrational bands that interfere with the bands associated with proteins. For this reason, most of the FTIR literature focuses on the use of this technique to assess structure in the solid state or in the presence of non-aqueous environments. Recently, differential FTIR has been used in which a water background is subtracted from the FTIR spectrum. This workaround is limited to solutions containing relatively high protein concentrations. [Pg.305]

Fourier transform infrared spectroscopy (FTIR) is the most widely used vibrational spectroscopic technique. FTIR is an infrared spectroscopy in which the Fourier transform method is used to obtain an infrared spectrum in a whole range of wavenumbers simultaneously. It differs from the dispersive method, which entails creating a spectrum by collecting signals at each wavenumber separately. Currently, FTIR has almost totally replaced the dispersive method because FTIR has a much higher signal-to-noise ratio than that of dispersive method. [Pg.267]

A method of horizontal attenuated total reflectance (HATR) by Fourier transform infrared spectroscopy (FTIR) is considered more useful for infrared spectroscopic analysis of leather samples. By this method, the sample is simply put on the flat plate of ZnSe crystal or KRS-5 crystal of the HATR accessory. The Fourier transformation of the interferogram is converted by the computer into a plot of absorption against wave number that resembles the usual IR spectrum (William and Fleming, 1998). [Pg.49]

Figures 8.2 and 8.3 show stacked curves obtained by TG-Fourier transform infrared spectroscopy (FTIR) of KL measured in air and nitrogen. TG-FTIR measurements were carried out using a Seiko TG 220 themogravimeter equipped with a JASCO FTIR7000 spectrometer [44,45,49,50]. Sample mass was 10 mg and heating rate was 200°C/min. Airflow rate was controlled at 100 mL/min. The gases evolved during the thermal degradation of KL were simultaneously analyzed by FTIR. Spectra were recorded at 30-second intervals each spectrum is the average of 10 one-second scans. The spectral resolution was 1 cm... Figures 8.2 and 8.3 show stacked curves obtained by TG-Fourier transform infrared spectroscopy (FTIR) of KL measured in air and nitrogen. TG-FTIR measurements were carried out using a Seiko TG 220 themogravimeter equipped with a JASCO FTIR7000 spectrometer [44,45,49,50]. Sample mass was 10 mg and heating rate was 200°C/min. Airflow rate was controlled at 100 mL/min. The gases evolved during the thermal degradation of KL were simultaneously analyzed by FTIR. Spectra were recorded at 30-second intervals each spectrum is the average of 10 one-second scans. The spectral resolution was 1 cm...
Fourier transform infrared spectroscopy (FTIR) - A technique for obtaining an infrared spectrum by use of an interferometer in which the path length of one of the beams is varied. A Fourier transformation of the resulting interferogram yields the actual spectrum. The technique is also used for NMR and other types of spectroscopy. [Pg.104]

Fourier transform infrared spectroscopy (FTIR) is a common identification test. Chapter 11 also discusses FTIR applications supporting stability. The Fourier transform enhances sensitivity and greatly reduces the time of the spectroscopic measurement. FTIR is commonly used as an identification test, but has been used qualitatively (e.g., dimethicone). Spectra are compared with a reference spectrum for identification purposes. As an identification test, FTIR is used as a release test rather than a stability test. Additional testing information can be found in USP/NF, General Chapter <851 >. [Pg.207]

Fourier transform infrared spectroscopy (FTIR) had its origins in the interferometer developed by Michelson in 1880 and experiments by astrophysicists some seventy years later. A commercial FTIR instrument required development of the laser (1960, by Theodore H. Maiman [1927- ], Hughes Aircraft), refined optics, and computer hardware and software. The Fourier transform takes data collected in time domain and converts them to frequency domain, the normal infrared (IR) spectrum. FTIR provided vasdy improved signal-to-noise ratios allowing routine analyses of microgram samples. [Pg.233]

Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy have also been used for analyses of complexes. Upon complexation of the guest, shifts or changes in the spectrum occur. There are interferences in the spectra from the CD, and some of the changes are very subtle, requiring careful interpretation of... [Pg.17]

Fourier-transform infrared spectroscopy (FTIR) monitors changes in the IR vibrational absorption spectrum as a molecule diffuses from a terrace site to a step or other smface defect [92Heil]. The temporal change in the vibrational mode of interest can be used to deduce the diffusivity. [Pg.460]

The primary components and the chemical structure of the raw peat and the solid product were further analyzed by Fourier transform infrared spectroscopy (FTIR) 0ASCO 670 Plus) using the Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) technique and the JASCO IR Mentor Pro 6.5 software for spectral analysis. The cross polarization/magic angle spinning (CP/MAS) NMR spectrum of raw peat and the solid... [Pg.182]

Fourier Transform Infrared Spectroscopy (FTIR) provided a convenient tool by which reaction success was qualitatively evaluated. The spectrum of unfunctionalized PVBC on the polyethylene support is included in Figure 6a. Because of the intense absorbances of the PA, MPE, and IPE species, FTIR proved to be a convenient tool to investigate the progression of the syntheses. Note the changes in the spectra as the membranes were functionalized especially in the range of 900-1250 wavenumber for the MPE and IPE functional groups The PA functionalized membranes have several other very broad characteristic absorbances Figures 6b, 6c, and 6d contain the FTIR spectra of the membranes functionalized with the phosphorous species. Note that the intense absorbances around 3000 wavenumber are derived from the polyethylene support. [Pg.103]

Fourier transform infrared spectroscopy (FTIR) was carried out in a Spectrum 100 FTIR Spectrometer Perkin Elmer (Japan). Spectra were recorded in range of 4000-550cm with 4cm resolution by using an attenuated total reflectance (ATR) technique [61]. [Pg.197]

Infrared spectroscopy (FTIR) was used to identify the chemical bonding states within the material. The FTIR spectrum shown in Figure 4.5 indicates the presence of all chemical bonds which are expected The Si-O-Si linkages of the silica network are represented by a strong and broad Si-0 vibrational mode at 1,100 cm The presence of Si-CH3... [Pg.84]


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FTIR spectroscopy, Infrared

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