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Industrial preparation acetaldehyde

Not so for synthesis in the chemical industry where a compound must be prepared not only on a large scale but at low cost There is a pronounced bias toward reactants and reagents that are both abundant and inexpensive The oxidizing agent of choice for example in the chemical industry is O2 and extensive research has been devoted to develop mg catalysts for preparing various compounds by air oxidation of readily available starting materials To illustrate air and ethylene are the reactants for the industrial preparation of both acetaldehyde and ethylene oxide Which of the two products is ob tamed depends on the catalyst employed... [Pg.644]

Key intermediates in the industrial preparation of both nicotinamide and nicotinic acid are alkyl pyridines (Fig. 1). 2-Meth5l-5-ethylpyridine (6) is prepared in ahquid-phase process from acetaldehyde. Also, a synthesis starting from ethylene has been reported. Alternatively, 3-methylpyridine (7) can be used as starting material for the synthesis of nicotinamide and nicotinic acid and it is derived industrially from acetaldehyde, formaldehyde (qv), and ammonia. Pyridine is the principal product from this route and 3-methylpyridine is obtained as a by-product. Despite this and largely due to the large amount of pyridine produced by this technology, the majority of the 3-methylpyridine feedstock is prepared in this fashion. [Pg.48]

Monosubstituted and 1,2-disubstituted olefins can be oxidized to aldehydes and ketones by palladium chloride and similar salts of noble metals.367 1,1-Disubstituted olefins generally give poor results. The reaction is used industrially to prepare acetaldehyde from ethylene... [Pg.1196]

Ethanol (industrial solvent Acetaldehyde (used in used in preparation of ethyl preparation of acetic acid) acetate unleaded gasoline additive)... [Pg.276]

Acetic acid is the main impurity in acetic anhydride, which is prepared industrially from acetaldehyde or from acetic acid and ketene. The acid can be removed by fractionation, and residual amounts thereof by prolonged boiling with magnesium turnings.33... [Pg.1101]

Ethyl acetate, prepared industrially from acetaldehyde and catalytic amounts of aluminum ethoxide, contains acetic acid, ethanol, and water as impurities. 100 g of ethyl acetate dissolves 3.3 g of water at 25° the azeotrope contains 8.5% of water. [Pg.1101]

There are three important industrial preparations of acetic acid ethene oxidation through acetaldehyde (Section 12-16) air oxidation of butane and carbonylation of methanol. The mechanisms of these reactions are complex. [Pg.844]

At one time acetaldehyde was prepared on an industrial scale by this method Modern methods involve direct oxidation of ethylene and are more economical... [Pg.381]

An alkyne is a hydrocarbon that contains a carbon-carbon triple bond. Acetylene.. H—C= C—H, the simplest alkyne, was once widely used in industry as the starting material for the preparation of acetaldehyde, acetic acid, vinyl chloride, and other high-volume chemicals, but more efficient routes to these substances using ethylene as starting material are now available. Acetylene is still used in the preparation of acrylic polymers but is probably best known as the gas burned in high-temperature oxy-acetylene welding torches. [Pg.259]

Approximately 2.5 million tons of acetic acid is produced each year in the United States for a variety of purposes, including preparation of the vinyl acetate polymer used in paints and adhesives. About 20% of the acetic acid synthesized industrially is obtained by oxidation of acetaldehyde. Much of the remaining 80% is prepared by the rhodium-catalyzed reaction of methanol with carbon monoxide. [Pg.752]

Enol esters are distinct from other esters not because of a particular stability or lability toward hydrolases, but due to their hydrolysis releasing a ghost alcohol (an enol), which may immediately tautomerize to the corresponding aldehyde or ketone. A well-studied example is that of vinyl acetate (CH3-C0-0-CH=CH2), a xenobiotic of great industrial importance that, upon hydrolysis, liberates acetic acid (CH3-CO-OH) and acetaldehyde (CH3-CHO), the stable tautomer of vinyl alcohol [25], The results of two studies are compiled in Table 7.1, and demonstrate that vinyl acetate is a very good substrate of carboxylesterase (EC 3.1.1.1) but not of acetylcholinesterase (EC 3.1.1.7) or cholinesterase (EC 3.1.1.8). The presence of carboxylesterase in rat plasma but not in human plasma explains the difference between these two preparations, although the different experimental conditions in the two studies make further interpretation difficult. [Pg.391]

On an industrial scale, cinnamaldehyde is prepared almost exclusively by alkaline condensation of benzaldehyde and acetaldehyde. Self-condensation of acetaldehyde can be avoided by using an excess of benzaldehyde and by slowly adding acetaldehyde [154]. [Pg.110]

In order to investigate the deactivation of DERA by the reactants that are involved in this reaction, the enzyme was incubated with varying concentrations of acetaldehyde and ClAA, simulating the range of starting concentrahons relevant for industrial applications. Aqueous solutions of the first aldol product (monoaldol) 7 and the final lactol 1 were also prepared according to [24] to investigate the stability of DERA. [Pg.136]

The principle of this method has been utilised on the industrial scale, and with success for the preparation of acetone. The acetic acid may be prepared from acetylene via acetaldehyde (see p. 433), thus providing a commercial synthesis of acetone from coke. [Pg.94]

The iV-alkylation was considered to occur by the reaction of the carbonyl compounds, formed by the dehydrogenation of alcohols over the catalyst, with the hydrogenation products of pyridine,25 as suggested by Schwoegler and Adkins, who obtained good yields of /V-alkylpiperidines by the reaction of piperidine with alcohols.26 Maruoka et al. obtained a higher maximal yield of the iV-ethylated product in ethanol over Raney Co than over Raney Ni in the hydrogenation of 5-ethyl-2-methylpyridine (eq. 12.16),23 an alkylated pyridine prepared industrially by the reaction of acetaldehyde with ammonia. [Pg.507]


See other pages where Industrial preparation acetaldehyde is mentioned: [Pg.787]    [Pg.1538]    [Pg.76]    [Pg.794]    [Pg.1774]    [Pg.732]    [Pg.732]    [Pg.1229]    [Pg.918]    [Pg.163]    [Pg.470]    [Pg.306]    [Pg.227]    [Pg.96]    [Pg.136]    [Pg.504]    [Pg.2]    [Pg.335]    [Pg.358]    [Pg.470]    [Pg.645]   
See also in sourсe #XX -- [ Pg.644 , Pg.711 ]

See also in sourсe #XX -- [ Pg.644 , Pg.711 ]

See also in sourсe #XX -- [ Pg.644 , Pg.711 ]

See also in sourсe #XX -- [ Pg.667 , Pg.732 ]

See also in sourсe #XX -- [ Pg.693 ]




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