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Imide carboxylate

Fourier transform infrared (FTIR) spectroscopy is the most popular method for determining the imidization process in the solid state and identifying specific substituents on the macromolecular backbone (e.g., CN, SO3H, CO, SO2).131 A method for calculating the diermal imidization extent based on FTIR data has been reported by Pride.132 Raman spectroscopy was used on the model study of PMDA-ODA condensation, and the possible formation of an inline bond by reaction of an amino group with an imide carboxyle was evidenced.133... [Pg.300]

In comparison, no structural modification of model B was seen before 120 h of aging (80 °C). However, after 120 h two small doublets appeared in the NMR spectrum and several additional peaks became noticeable in the NMR spectrum. It was determined by NMR and IR spectroscopy that the hydrolysis products were an imide/carboxylic acid and an imide/anhydride. Model B was then aged for 1200 h at 80 °C to quantitatively determine the amount of hydrolysis products as a function of time. The relative intensity of the peaks due to carboxylic acid is constant after some time. The authors suggest that an equilibrium occurs between model B and the products formed during hydrolysis, and therefore, the conversion to hydrolysis products is limited to about 12%. This critical fraction is probably enough to cause some degradation of polymeric materials, but research on six-membered polyimides has remained active. [Pg.359]

Blaschke et al. [54—56] synthesized polyacrylamide and polymethacrylamide containing chiral side chains. In order to make CSPs, these polymers were bonded to silica gel chemically [54-56]. The CSP obtained by /V-acrylol-(.S)-phenylalanine ethyl ester was commercialized by Merck Chemical Company by the trade name ChiraSpher. The racemic compounds resolved are those capable of forming hydrogen-bondings (i.e., amides, imides, carboxylic acids, and alcohols). It has been reported that nonpolar solvents like benzene and toluene individually or their mixtures were the best mobile phases. In addition to these CSPs, other amide CSPs were prepared and tested for the chiral resolution [57,58]. [Pg.332]

Unsymmetrical U-shaped molecules with two different hydrogen-bonding groups that give homodimers have also been reported. Specifically, a molecular cleft known as Rebek s imide has been shown to self-assemble in the solid state via two N-H -O and two O-H -O hydrogen bonds of two imide-carboxylic acid synthons (Fig. 4).11... [Pg.18]

Dilute sodium hydroxide solution. Carboxylic acids (RCOOH), sulphonic acids (RSO3H), phenols (ArOH), thiophenols (ArSH), mer-captans (RSH), imides (RCONHCOR), aryl sulphonamides (AxSOjNHj), arylsulphonyl derivatives of primary amines (AxSOjNHR), oximes (RCH=NOH), primary and secondary nitro compounds (RCH=NOOH and RjC=NOOH-oci forms), and some enols (e.g., of 1 3-diketones... [Pg.1048]

Heating Kemp s acid with appropriate aromatic diamines yields bis-imides with two convergently oriented carboxylic acid groups on the edges of a hydrophobic pocket. Dozens of interesting molecular complexes have been obtained from such compounds and can be traced in the Journal of the American Chemical Society under the authorship of J. Rebek, Jr., (1985 and later e.g. T. Tjivikua, 1990 B). [Pg.347]

Hydrogenolysis of the diallyl alkylmalonate 757 with formic acid in boiling dioxane affords the monocarboxylic acid 758. Allyl ethyl malonates are converted into ethyl carboxylates[471]. The malonic allyl ester TV-allylimide 759 undergoes smooth deallylation in refluxing dioxane to give the simple imide 760(472]. The allyl cyanoacetate 761 undergoes smooth decarboxylation to give... [Pg.394]

Icosanoids (Section 26 6) A group of naturally occurring com pounds derived from unsaturated C20 carboxylic acids Imide (Section 20 16) Compound of the type... [Pg.1286]

AijAT-dicyclohexylcarhodiimide (DCC) also leads to essentially quantitative conversion of amic acids to isoimides, rather than imides (30,31). Combinations of trifluoroacetic anhydride—triethjlarnine and ethyl chi oroform a te—triethyl amine also result in high yields of isoimides (30). A kinetic study on model compounds has revealed that isoimides and imides are formed via a mixed anhydride intermediate (12) that is formed by the acylation of the carboxylic group of amic acid (8). [Pg.400]

A variety of nucleophiles can be employed—e.g. carboxylic acids, phenols, imides, thiols, thioamides, and even /3-ketoesters as carbon nucleophiles. Of major importance however is the esterification as outlined above, and its use for the clean inversion of configuration of a chiral alcohol. [Pg.206]

Peptide synthesis requires the use of selective protecting groups. An N-protected amino acid with a free carboxyl group is coupled to an O-protected amino acid with a free amino group in the presence of dicydohexvlcarbodi-imide (DCC). Amide formation occurs, the protecting groups are removed, and the sequence is repeated. Amines are usually protected as their teit-butoxy-carbonyl (Boc) derivatives, and acids are protected as esters. This synthetic sequence is often carried out by the Merrifield solid-phase method, in which the peptide is esterified to an insoluble polymeric support. [Pg.1050]

A similar irradiation of imide 9 in acetonitrile gives a mixture of ethyl 4,5-bis(ethoxy-carbonylamino)-l//-l,2-diazepine-l-carboxylate (10) and the isomeric ethyl 5,6-bis(ethoxycar-bonylamino)-l/f-l,2-diazepine-l-carboxylate (11) in the ratio 6 1. In contrast, when the irradiation is carried out in dichloromethane, the ratio is reversed to 1 2.5.81... [Pg.339]

For less hindered carboxylic acids acylation of the imidate requires only 5 minutes. With this modification the /V-(a-methoxybenzyl)amides are prepared according to the above-mentioned procedure [R = CH3, CH(CH,)2. CH(CH, )OAc, CH(C H2)OAc yield 85-88%]. [Pg.812]

Rhenium(VI) complexes, 4,194 alkoxides, 4,196 amides, 4,194 amines, 4,199 carboxylates, 4,199 dimethylformamide, 4,199 dioxane, 4,198 halides, 4,195,199 2-hydroxypyridine, 4,199 imides, 4,194 magnetic behavior, 1,271 mixed sulfur-nitrogen compounds, 4,196 N heterocycles, 4,199 nitrides, 4,194 oxide halides, 4, 195 oxoanions,4,196 pyridine, 4,199 sulfates, 4,198 sulfur compounds, 4,196 tellurates, 4,198... [Pg.210]

C for 6 h afforded the alkylated imides in 60-84% yields. The last approach was extended to unsaturated carboxylic amides. The diene 0,N-acetal 86 was prepared from the amide 85 in high yields and subsequently treated with azoinitiator V-70 to afford the desired products (Scheme 13). ... [Pg.151]

As in 10-55 hydrazides and hydroxamic acids can be prepared from carboxylic esters, with hydrazine and hydroxylamine, respectively. Both hydrazine and hydroxylamine react more rapidly than ammonia or primary amines (the alpha effect, p. 445). Imidates, RC(=NH)OR, give amidines, RC(=NH)NH2. Lactones, when treated with ammonia or primary amines, give lactams. Lactams are also produced from y- and 5-amino esters in an internal example of this reaction. [Pg.510]

Imides can be prepared by the attack of amides or their salts on acyl halides, anhydrides, and carboxylic acids or esters. The best synthetic method for the preparation of acyclic imides is the reaction between an amide and an anhydride at 100°C catalyzed by H2S04. When acyl chlorides are treated with amides in a2 l molar ratio at low temperatures in the presence of pyridine, the products are N,N-diacylamides, (RCO)3N. ... [Pg.514]

The addition of dry HCl to a mixture of a nitrile and an alcohol in the absence of water leads to the hydrochloride salt of an imino ester (imino esters are also called imidates and imino ethers). This reaction is called the Pinner synthesisThe salt can be converted to the free imino ester by treatment with a weak base such as sodium bicarbonate, or it can be hydrolyzed with water and an acid catalyst to the corresponding carboxylic ester. If the latter is desired, water may be present from the beginning, in which case aqueous HCl can be used and the need for gaseous HCl is eliminated. Imino esters can also be prepared from nitriles with basic catalysts. ... [Pg.1183]

C20H27NO4 58115-88-1) see Butorphanol hexahy dro-1 -methyMH-azepin-4-one (C7H13NO 1859-33-2) see Azelastine (3S-trflns)-hexahydro-2-phenyl-l /-pyrroloLl,2-c]imid-azoIe-3-carboxylic acid methyl ester (C14H1KN2O2) see Troglitazone hexahydro-l-(2-propenyl)<4i/-azepin-4-one (CyHi NO) see Talipcxole... [Pg.2392]


See other pages where Imide carboxylate is mentioned: [Pg.732]    [Pg.190]    [Pg.33]    [Pg.218]    [Pg.732]    [Pg.190]    [Pg.33]    [Pg.218]    [Pg.233]    [Pg.160]    [Pg.312]    [Pg.530]    [Pg.497]    [Pg.284]    [Pg.117]    [Pg.117]    [Pg.46]    [Pg.130]    [Pg.572]    [Pg.78]    [Pg.855]    [Pg.146]    [Pg.81]    [Pg.151]    [Pg.1205]    [Pg.1290]    [Pg.161]    [Pg.1]    [Pg.39]   
See also in sourсe #XX -- [ Pg.142 ]




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Acyl imidates carboxylic acid amides

Alkylation carboxylic imide

Carboxylic acid imides

Carboxylic acid imides hydrogenolysis

Carboxylic acid imides methyl esters

Carboxylic acid imides peptides

Carboxylic acids to imides

Carboxylic imides

Carboxylic imides

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