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Hydrolysis, enzymic

Macrocyclic complexes of zinc have inspired interest in varied areas such as supramolecular and biomimetic chemistry including hydrolysis enzymes, such as phosphatases and esterases, and also for the fluorescent detection of zinc. The polyaza macrocycles and their A--functionalized derivatives are particularly well represented. An important aspect of macrocycle synthesis is the use of metal templates to form the ligand. Examples of zinc as a template ion will be discussed where relevant. [Pg.1204]

As anhydrides, such compounds are subject to spontaneous hydrolysis, which may contribute to detoxification [160]. Thus, soman hydrolysis at pH 7.5 and 37° occurs with a rate constant of 0.003 - 0.004 min-1 and an activation energy of ca. 55 kJ mol 1 [161]. However, most of the published data refer to enzymatic hydrolysis. Enzymes hydrolyzing P-X anhydride bonds are now known as organophosphorus acid anhydrolases (OPA anhydrolases) classified as EC 3.1.8.2 (also known as diisopropyl-fluorophosphatase, DFPase, tabunase, somanase), an activity related to EC 3.1.8.1 (aryldialkyl-phosphatase, paraoxonase, A-esterase) and formerly classified as EC 3.8.2.1 [64] [65] [69], Much public information on these enzymes can be found in [106],... [Pg.593]

To biosynthesize fats (triacylglycerols), the phosphate residue is again removed by hydrolysis (enzyme phosphatidate phosphatase 3.1.3.4). This produces diacylglycerols (DAG). [Pg.170]

Acid may be used to hydrolyze urinary pregnanediol conjugates in a reproducible manner with approximately 90% recovery. The overall advantage to this method is the amount of time saved. Acid hydrolysis normally takes about 15 min enzyme hydrolysis takes 24 hr. Since many steroid molecules can be broken by acid hydrolysis, enzyme hydrolysis is the preferred method. [Pg.508]

The use of electrochemical techniques combined with biological molecules has been extensively reviewed [17] and will not be discussed in detail here. The most widely used method for the AChE-containing electrodes is via the simple amperometric detection of the product of the ester hydrolysis enzyme catalysed reaction [17]. [Pg.313]

It should be possible to improve the efficiency of the cellulose enzyme complex for hydrolyzing cellulose to glucose. The enzyme complex apparently contains decrystallizing and hydrolysis enzymes that work together to convert cellulose to glucose. Isolation of the specific enzymes and genetic engineering could provide a more efficient complex. [Pg.1290]

Next we explore the question of how the apparent thermodynamic variables change as a reaction progresses from a non-equilibrium initial condition toward equilibrium in a closed system. Imagine a closed system initially contains ATP, ADP, and PI, at concentrations of 10 mM, 1 mM, and 1 mM, respectively, at neutral pH of 7. To see how pH and related thermodynamic properties change as the reaction progresses toward equilibrium, imagine that an ATP hydrolysis enzyme is present in our system, and the reference reaction of Equation (2.13) moves in... [Pg.30]

In addition to the widely reported techniques of amide bond formation, transesterification, and hydrolysis, enzymic enantioselective oxidation is also used in the synthesis of single isomer drugs. Patel described the elficient oxidation of benzopyran (75), an intermediate in thesynthesisof potassium channel openers (123). The transformationwas ef-fected w i t h a cell suspension of MortiereUa raman-niana with glucose over a 48-h period, the isolated product (77) was obtained in a 76%yield with an optical purity of 97%and a chemical purity of 98%, as shown in Pig. 18.32. [Pg.806]

It is the heteropoiysaccharides of plants that bestow cellulosic composites with the ability to absorb impact, the ability to absorb moisture, and the ability to create pores in the form of free volume in amorphous (disordered or para-crystalline) materials [58,59]. Modification by reducing molecular regularity has the additional benefit of creating a transition from a focus on mechanical (structural) functions to an emphasis on energy storage and gel formation. Reduction in order translates into ease of hydrolysis, enzyme accessibility, rate of nutrient release for decay organisms, water absorption and swelling. Reduction in order is achieved by the introduction of monosaccharide units, and of bond types, which differ from those of cellulose. The principal monosaccharides involved in the heteropoiysaccharides of plants are shown in O Fig. 12. [Pg.1489]


See other pages where Hydrolysis, enzymic is mentioned: [Pg.446]    [Pg.409]    [Pg.194]    [Pg.194]    [Pg.261]    [Pg.117]    [Pg.241]    [Pg.280]    [Pg.713]    [Pg.139]    [Pg.212]    [Pg.325]    [Pg.446]    [Pg.590]    [Pg.645]    [Pg.703]    [Pg.753]    [Pg.320]    [Pg.409]    [Pg.814]    [Pg.21]    [Pg.5189]    [Pg.127]    [Pg.312]    [Pg.260]    [Pg.271]    [Pg.190]    [Pg.513]    [Pg.108]    [Pg.782]    [Pg.420]    [Pg.5188]    [Pg.409]    [Pg.787]    [Pg.192]   
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See also in sourсe #XX -- [ Pg.45 ]

See also in sourсe #XX -- [ Pg.373 ]

See also in sourсe #XX -- [ Pg.15 , Pg.16 , Pg.17 ]




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2- acetyl group, enzymic hydrolysis

Acetylcholine enzymic hydrolysis

Acetylthiocholine enzymic hydrolysis

Amino acids enzymic hydrolysis

Amylose acetate enzymic hydrolysis

An Assay for Enzyme-Catalyzed Polyanion Hydrolysis Based on Template-Directed Excimer Formation

Arabinoxylans enzymic hydrolysis

Assay for enzyme-catalyzed polyanion hydrolysis

Bioethanol enzyme hydrolysis

Carbamoylase hydrolysis enzymes

Cellulolytic enzymes hydrolysis

Cellulose enzyme hydrolysis

Cellulose enzymic hydrolysis

Disaccharides enzymic hydrolysis

Enzyme Enzymic hydrolysis

Enzyme Enzymic hydrolysis

Enzyme Ester hydrolysis

Enzyme hydrolysis

Enzyme hydrolysis of cellulose

Enzyme hydrolysis of proteins

Enzyme hydrolysis, glycosides

Enzyme increased hydrolysis rate

Enzyme mimic catalysis hydrolysis

Enzyme stereoselective hydrolysis

Enzyme-Catalyzed Hydrolysis of Peptides (Amide Bonds)

Enzyme-aided enantioselective hydrolysis

Enzyme-assisted hydrolysis

Enzyme-catalysed Hydrolysis of Amides

Enzyme-catalyzed hydrolysis kinetic resolution

Enzyme-catalyzed hydrolysis protease

Enzyme-catalyzed polyanion hydrolysis

Enzyme-catalyzed reactions hydrolysis

Enzyme-mediated hydrolysis

Enzymes carboxypeptidase, hydrolysis

Enzymes hemicellulose hydrolysis

Enzymes hydrolysis and

Enzymes hydrolysis process

Enzymes in hydrolysis

Enzymes nucleic acid hydrolysis

Enzymes polysaccharide hydrolysis

Enzymes protein hydrolysis with

Enzymes, cell-wall hydrolysis with

Enzymic hydrolysis of lecithin

Enzymic hydrolysis, analysis

Enzymic hydrolysis, dietary fiber

Enzymic hydrolysis, protein activators

Enzymic synthesis hydrolysis

Extracellular Enzyme Hydrolysis

Glycosides hydrolysis, enzymic

Glycosidic linkages enzymic hydrolysis

Hyaluronic acid hydrolysis, enzymic

Hydrolysis by enzymes

Hydrolysis enzyme-catalyzed

Hydrolysis enzymes, 74 increased by heavy

Hydrolysis enzymic, glucosides

Hydrolysis enzymic, selective

Hydrolysis with Proteolytic Enzymes

Hydrolysis, enzyme catalysis

Inulin hydrolysis, enzymic

Laminarin enzymic hydrolysis

Linkages enzymic hydrolysis

Lipolysis enzymic hydrolysis

Nitrile hydratases hydrolysis with enzymes

Nitrile hydrolysis enzymes

Non-enzymic hydrolysis

Of enzymic hydrolysis

Pectic acid, enzymic hydrolysis

Peptide bond enzyme-catalyzed hydrolysis

Phosphate ester hydrolysis enzymic

Polysaccharides enzymic hydrolysis

Protein precipitation and enzyme hydrolysis

Proteolytic enzymes, hydrolysis

Raffinose enzymic hydrolysis

Reactions enzyme hydrolysis

Resolution, classical using enzymic hydrolysis

Stachyose enzymic hydrolysis

Starch enzyme hydrolysis

Substituent-cleaving enzymes hydrolysis

Sucrose hydrolysis, enzymic

Syrup acid-enzyme hydrolysis

Triacylglycerols enzymic hydrolysis

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