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Hydrogen sulfide alcohols

In a recent publication by Holtschmidt and his co-workers the mechanism of the high-temperature chlorination of N-methylpyrrolidone was discussed C ). In this reaction l-chlorocarbonylhexachloropropyl-3-car-bonimidoyl dichloride is formed as a major product (see Chapter 2). Further work related to the nucleophilic substitution reactions of carbonimidoyl dichlorides with water (" ), hydrogen sulfide (" ), alcohols ( ), mercaptans ( ), and amines ( ) has been reported, and a step-wise displacement of the chloro groups was demonstrated by Neidlein and his students ( ). For example, reaction of arenesulfonylcarbonimidoyl dichlorides IV with methylmercaptan yields the 1-chlorothioformimidates V, which, upon further reaction with primary and secondary amines, yield the S,N-acetals VI... [Pg.211]

Several hundred sets of data for hydrocarbons on Nuxit-al charcoal obtained by Szepesy and Hies (Valenzuela and Myers, 1989) can be described well by this equation. Because of its simplicity in form and its correct behaviour at low and high pressures, the Toth equation is recommended as the first choice of isotherm equation for fitting data of many adsorbates such as hydrocarbons, carbon oxides, hydrogen sulfide, alcohols on activated carbon as well as zeolites. Sips equation presented in the last section is also recommended but when the behaviour in the Henry law region is needed, the Toth equation is the better choice. [Pg.66]

Sometimes analyses are required for particular compounds such as sulfur, chlorine and lead, or for specific components such as mercaptans, hydrogen sulfide, ethers and alcohols. [Pg.275]

Other sulfur compounds such as thiourea, ammonium dithiocarbamate, or hydrogen sulfide also lead to 2-mercaptothiazoles. Thus thiourea has been used in the syntheses of 4,5-dimethyl (369) and 4-aryl-2-mercapto-thiazoles (Table 11-30) (519). The reactions were carried out by condensing the ia -thiocyanatoketones with thiourea in alcohol and water acidified with hydrochloric acid. By this procedure, 4-aryl-2-mercaptothiazoles were obtained in yields of 40 to 80% with bis-(4-aryl-2-thiazolyl) sulfides as by-products (519). These latter products (194) have also been observed as a result of the action of thiourea on 2-chloro-4-arylthiazole under the same experimental conditions. They can be separated from 2-mercaptothiazoles because of their different degrees of solubility in sodium hydroxide solution at 5%. In this medium bis-(4-phenyl-2-thiazolyl)sulfide is... [Pg.276]

Miscellaneous Reactions. Sodium bisulfite adds to acetaldehyde to form a white crystalline addition compound, insoluble in ethyl alcohol and ether. This bisulfite addition compound is frequendy used to isolate and purify acetaldehyde, which may be regenerated with dilute acid. Hydrocyanic acid adds to acetaldehyde in the presence of an alkaU catalyst to form cyanohydrin the cyanohydrin may also be prepared from sodium cyanide and the bisulfite addition compound. Acrylonittile [107-13-1] (qv) can be made from acetaldehyde and hydrocyanic acid by heating the cyanohydrin that is formed to 600—700°C (77). Alanine [302-72-7] can be prepared by the reaction of an ammonium salt and an alkaU metal cyanide with acetaldehyde this is a general method for the preparation of a-amino acids called the Strecker amino acids synthesis. Grignard reagents add readily to acetaldehyde, the final product being a secondary alcohol. Thioacetaldehyde [2765-04-0] is formed by reaction of acetaldehyde with hydrogen sulfide thioacetaldehyde polymerizes readily to the trimer. [Pg.51]

The compound can be prepared from 2,4,6-trinitrophenol (picric acid [88-89-1]) by reduction with sodium hydrosulfide (163), with ammonia —hydrogen sulfide followed by acetic acid neutralization of the ammonium salt (164), with ethanolic hydrazine and copper (165), or electrolyticaHy with vanadium sulfate in alcoholic sulfuric acid (159). Heating 4,6-dinitro-2-benzamidophenol in concentrated HQ. at 140°C also yields picramic acid (166). [Pg.314]

Hydrogen Sulfide andMercaptans. Hydrogen sulfide and propylene oxide react to produce l-mercapto-2-propanol and bis(2-hydroxypropyl) sulfide (69,70). Reaction of the epoxide with mercaptans yields 1-aLkylthio- or l-arylthio-2-propanol when basic catalysis is used (71). Acid catalysts produce a mixture of primary and secondary hydroxy products, but ia low yield (72). Suitable catalysts iaclude sodium hydroxide, sodium salts of the mercaptan, tetraaLkylammonium hydroxide, acidic 2eohtes, and sodium salts of an alkoxylated alcohol or mercaptan (26,69,70,73,74). [Pg.135]

Hydrogen sulfide reacts with alcohols under acid-cataly2ed conditions, usually with soHd acidic catalysts at elevated temperatures ... [Pg.135]

Barium hydro sulfide [25417-81-6], Ba(HS)2, is formed by absorption of hydrogen sulfide into barium sulfide solution. On addition of alcohol, barium hydrosulfide tetrahydrate [12230-74-9], Ba(HS)2 4H2O, crystallizes as yellow rhombic crystals that decompose at 50 °C. Sohd barium hydro sulfide is very unstable. Its solubility in water is... [Pg.480]

The decomposition of (536) with hydrogen sulfide yields pyrazole (76T1909). The 1-phosphorylpyrazoles (537) are suitable reagents for the phosphorylation of alcohols, amines, hydrazines and azides (76AG(E)378). [Pg.271]

Sucrose to critic acid Sulfur to hydrogen sulfide Sucrose to glucose and fructose and on to alcohol ... [Pg.855]

Acetic acid, acetone, alcohol, aniline, chromic acid, hydrocynanic acid, hydrogen sulfide, flammable liquids, flammable gases, and mtratable substances, paper, cardboard and rags. [Pg.1033]

Although the polysulfur macrocycles became more interesting to the scientific community after Pedersen s report of the crown compounds (see Chap. 1), examples of such structures may be found in the literature dating back some time. The first report of a macrocyclic polysulfide appears to be that by Ray who found in 1920 that when 1,2-dimercaptoethane and 1,2-dibromoethane were heated with alcoholic potassium hydrogen sulfide as shown in Eq. (6.2), triethylene trisulfide (2) and a substance presumed to be triethylene tetrasulfide (3) could be isolated. [Pg.268]

The cleavage of the intermediate osmate ester has presented problems in the past, and a variety of procedures have been developed, including the use of mannitol and strong aqueous base, refluxing aqueous alcoholic sodium bisulfite,formaldehyde and ascorbic acid. A much milder method involves simply bubbling hydrogen sulfide into a solution of the osmate ester osmium dioxide is precipitated rapidly, and the desired organic... [Pg.183]

Nucleophiles like alcohols [2, S], hydrogen sulfide [2], thiols [2,10], ammonia, amines, hydrazines, hydroxylamines [2 11, 12, 13, 14, 75], azides [2], other pseudohalides [2], phosphonates [2,16,17,18,19, 20], and phosphanes [2,19] add rapidly across the CO or CN double bond to yield stable adducts The phosphonate adduets undergo a subsequent aleohol—lester rearrangement [19, 20] (equation 2)... [Pg.841]

The alkyl chain distribution of the base alcohol in alcohol sulfates is easily determined by gas chromatography. However, alcohol sulfates and alcohol ether sulfates are not volatile and require a previous hydrolysis to yield the free alcohol. The extracted free alcohol can be injected directly [306] or converted to its trimethylsilyl derivative before injection [307]. Alternatively, the alcohol sulfate can be decomposed by hydroiodic acid to yield the alkyl iodides of the starting alcohols [308]. A preferred method forms the alkyl iodides after hydrolysis of the alcohol sulfate which are analyzed after further extraction of the free alcohol, thus avoiding the formation of hydrogen sulfide. This latter method is commonly used to determine the alkyl chain distribution of alcohol ether sulfates. [Pg.285]

The reaction at Eq. (12) allows the preparation of Na2S4 and K2S5 from the alkali metals, hydrogen sulfide and sulfur in anhydrous ethanol (ROH). First the metal is dissolved in the alcohol with formation of ethanolate (MOR) and hydrogen. Bubbling of H2S into this solution produces the hydrogen sulfide (MHS). To obtain the polysulfide the solution is refluxed with the calculated amount of elemental sulfur. After partial evaporation of the solvent and subsequent cooling the product precipitates. [Pg.131]

As discussed in Section 7.4.2.5, the reduction of tetrazolium salts to formazans often results in further reduction products. As seen in Scheme 24, reduction of formazans with ammonium sulfide leads to the hydrazidine 161. The reduction can proceed further eliminating an arylamine, yielding an amidrazone, e.g., 162.364 By contrast, alcoholic hydrogen sulfide attacks... [Pg.267]

There appears to be some evidence that ethanol can increase the effects of hydrogen sulfide. In 6 cases, less hydrogen sulfide was needed for toxic effects to be observed when workers had consumed alcohol 16-24 hours earlier (Poda 1966). [Pg.116]


See other pages where Hydrogen sulfide alcohols is mentioned: [Pg.328]    [Pg.82]    [Pg.373]    [Pg.161]    [Pg.508]    [Pg.516]    [Pg.241]    [Pg.274]    [Pg.365]    [Pg.506]    [Pg.95]    [Pg.368]    [Pg.283]    [Pg.332]    [Pg.136]    [Pg.21]    [Pg.21]    [Pg.83]    [Pg.102]    [Pg.136]    [Pg.29]    [Pg.328]    [Pg.136]    [Pg.129]    [Pg.591]    [Pg.1042]    [Pg.44]    [Pg.89]    [Pg.255]   
See also in sourсe #XX -- [ Pg.12 , Pg.330 ]




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