Gloves skin protection

Skin redness and from slight to corrosive irritation is caused by direct contact. Acryhc acid is more corrosive than esters. The monomers not only irritate the skin, but may also be absorbed through the skin. Therefore, gloves and protective clothing and shoes or boots should be used in addition to eye (or hiU face) protective equipment. Upon contact, the skin should be flushed with copious amounts of water foUow-up medical attention should be sought. Medical attention should also be obtained if any of the earlier mentioned symptoms appear. 

Oxahc acid is not flammable but its decomposition products, both formic acid and carbon monoxide, are toxic and flammable. Its dust and mist are irritating, especially under prolonged contact. Personnel who handle oxahc acid should wear mbber gloves, aprons, protection masks or goggles, etc, to avoid skin contact and inhalation. Adequate ventilation also should be provided in areas in which oxahc acid dust fumes are present. 

Alkylamiaes are toxic. Both the Hquids and vapors can cause severe irritations to mucous membranes, eyes, and skin. Protective butyl mbber gloves, aprons, chemical face shields, and self-contained breathing apparatus should be used by aH personnel handling alkylamiaes. Amines are flammable and the lower mol wt alkylamiaes with high vapor pressures at ordiaary temperatures have low flash poiats. Amines should be handled ia weH-veatilated areas only after eliminating potential sources of ignition. 

NIOSH/MSHA-approved respiratory protection devices should be used. For skin protection, use of protective garments and gloves of Viton, Nitrile, or PVA constmction should be made. The acute effects of overexposure to styrene are shown in Table 6 (74). 

Health and Safety Factors. MSC has a vapor toxicity on mice of LD q 4.7 mg/L. It is a lachrymator and in order to prevent contact with eyes, goggles should be worn. It is also corrosive to skin and therefore chemically resistant gloves and protective clothing should be worn to prevent contact with skin. Containers should only be opened where there is adequate ventilation. 

Barium metal and most barium compounds are highly poisonous. A notable exception is barium sulfate which is nontoxic because of its extreme iasolubihty ia water. Barium ion acts as a muscle stimulant and can cause death through ventricular fibrillation of the heart. Therefore, care must be taken to avoid contact with open areas of the skin. Workers must wear respirators (of type approved for toxic airborne particles), goggles, gloves, and protective clothing at all times. The toxic barium aluminate residue obtained from barium production is detoxified by reaction with a solution of ferrous sulfate and converted iato nontoxic barium sulfate. According to OSHA standards, the TWA value for Ba and Ba compounds ia air is 0.5 mg/m. ... 

Skin Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap. 

The exposure value thus yielded provides a measure of the skin exposure with and without consideration of a protective garment and gloves (personal protective equipment = PPE), and may be taken directly for comparison with appropriate data from relevant toxicity studies for assessment of the risk via the dermal route. 

Caution This preparation should be carried out in a good hood to avoid exposure to ammonia. The operator should wear rubber gloves and protective goggles because 2-haloaUylamines and ethyl-enimines can cause severe skin and eye irritation. 

Tosyl chloride may irritate the skin protective gloves should be worn. 

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