Fission, nuclear waste from

Waste Products and Recycling Pu and Np are two of the most critical long-term components of nuclear waste from fission power reactors. The former is... 

Usually atoms resulting from nuclear fission arc radioactive. There are also radioactive atoms produced from neutron capture by both U and U. Both types of radioactive atoms remain in the nuclear fuel. It is these radioactive atoms that comprise the nuclear wastes that require disposal in an environmentally acceptable manner. 

The main drawback to nuclear power is the production of radioactive waste. Spent fuel from a nuclear reactor is considered a high-level radioactive waste, and remains radioactive for a veiy long time. Spent fuel consists of fission products from the U-235 and Pu-239 fission process, and also from unspent U-238, Pu-240, and other heavy metals produced during the fuel cycle. That is why special programs exist for the handling and disposal of nuclear waste. 

HLW comprises most of the radioactivity associated with nuclear waste. Because that designation can cover radioactive waste from more than one source, the term spent nuclear fuel (SNF) will be used to discuss HLW originating from commercial nuclear reactors. LLW comprises nearly 90 percent of the volume of nuclear waste but little of the radioactivity. Nuclear power reactors produce SNF and most of the nation s LLW, although there are approximately 20,000 different sources of LLW. The name SNF is a bit of a misnomer because it implies that there is no useful material left in the fuel, when in fact some fissionable material is left in it. 

What are the opportunities for using forms of energy that do not lead to CO2 formation Nuclear power from fission reactors presents problems with the handling and deposition of nuclear waste. Fusion reactors are more appealing, but may need several decades of further development. However, solar and wind energy offer realistic alternatives. 

After the separation of the actinides from the high-level waste, it is desirable to remove certain other fission products from the nuclear wastes. Some Cs and Sr are low-charged cations that react well with macro-cyclic ligands (e.g., crown ethers, calixarenes). Research to synthesize and investigate the properties of macrocyclic ligands for application in nuclear waste treatment has been an active effort internationally. Some of the results obtained are discussed in section 12.7. 

Knowledge of fission and its consequences is important for the nuclear power industry and the related fields of nuclear waste management and environmental cleanup. From the point of view of basic research, fission is interesting in its own right as a large-scale collective motion of the nucleus, as an important exit channel for many nuclear reactions, and as a source of neutron-rich nuclei for nuclear structure studies and use as radioactive beams. 

The third fact is that spent nuclear fuel is not waste. Spent nuclear fuel contains 2% to 3% waste, but is about 97% recoverable uranium and plutonium. Each bundle has the potential electric energy equivalent of more than 10 million barrels of oil. High-level nuclear wastes consist of fission products and actinides that are extracted from spent fuel, but not saved for commercial use or research. Spent fuel may be temporarily stored until it is reprocessed to separate the waste from the valuable plutonium and uranium. The remaining glassified waste will then be permanently entombed. 

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