Failure, stress-corrosion

The changes in the anode composition and morphology are also responsible for the erratic response of the current density vs. potential difference tendency and the decrease in the electrocatalytic activity. Thermo-corrosion and thermal stress failure, stress corrosion cracking during gas evolution, and overcritical local pressure conditions can cause extensive pitting and large ohmic voltage drops. 

Film Adhesion. The adhesion of an inorganic thin film to a surface depends on the deformation and fracture modes associated with the failure (4). The strength of the adhesion depends on the mechanical properties of the substrate surface, fracture toughness of the interfacial material, and the appHed stress. Adhesion failure can occur owiag to mechanical stressing, corrosion, or diffusion of interfacial species away from the interface. The failure can be exacerbated by residual stresses in the film, a low fracture toughness of the interfacial material, or the chemical and thermal environment or species in the substrate, such as gases, that can diffuse to the interface. 

Stress Corrosion Crocking. Stress corrosion cracking occurs from the combined action of corrosion and stress. The corrosion may be initiated by improper chemical cleaning, high dissolved oxygen levels, pH excursions in the boiler water, the presence of free hydroxide, and high levels of chlorides. Stresses are either residual in the metal or caused by thermal excursions. Rapid startup or shutdown can cause or further aggravate stresses. Tube failures occur near stressed areas such as welds, supports, or cold worked areas. 

Corrosion control requires a change in either the metal or the environment. The first approach, changing the metal, is expensive. Also, highly alloyed materials, which are resistant to general corrosion, are more prone to failure by localized corrosion mechanisms such as stress corrosion cracking. 

Virtuallv evety alloy system has its specific environment conditions which will prodiice stress-corrosion cracking, and the time of exposure required to produce failure will vary from minutes to years. Typical examples include cracking of cold-formed brass in ammonia environments, cracking of austenitic stainless steels in the presence of chlorides, cracking of Monel in hydrofluosihcic acid, and caustic embrittlement cracking of steel in caustic solutions. 

Serious stress-corrosion-cracldng failures have occurred when chloride-containing hydrotest water was not promptly removed from stainless-steel systems. Use of potable-quality water and complete draining after test comprise the most reliable solution to this problem. Use of chloride-free water is also helpful, especially when prompt drainage is not feasible. 

Few, if any, failure mechanisms have received as much attention as stress-corrosion cracking (SCC). Yet despite an enormous research effort over many years, an acceptable, generalized theory that satisfactorily explains all elements of the phenomenon has not been produced. SCC is a complex failure mechanism. Nevertheless, its basic characteristics are well known, and a wealth of practical experience permits at least a moderately comfortable working knowledge of the phenomenon. 

Visual identification prior to failure is difficult due to the typical tightness of stress-corrosion cracks. A low-power hand lens will greatly aid determination. Crack enhancement may be achieved through the use of dye penetrants. Severe cracking may be detectable using ultrasonic, radiographic, or acoustic emission techniques. 

Surface defects, if sufficiently severe, may result in failure by themselves. More commonly, they act as triggering mechanisms for other failure modes. For example, open laps or seams may lead to crevice corrosion or to concentration sites for ions that may induce stress-corrosion cracking. 

Although not commonly listed as a weld defect, high-welding stress nevertheless provides an essential ingredient to stress-corrosion cracking and other failures. It differs in an important respect from other types of weld defects in that stresses cannot be visually identified or revealed by conventional nondestructive testing techniques. 

Figure 15.18 Examples of crack patterns due to stress-corrosion cracking and corrosion fatigue in butt welds. (Reprinted with permission from Helmut Thielsch, Defects and Failures in Pressure Vessels and Piping, New York, Van Nostrand Reinhold, 1965.)...

It is worrying that a vessel which is safe when it enters service may become unsafe by slow crack growth - either by fatigue or by stress corrosion. If the consequences of catastrophic failure are very serious, then additional safety can be gained by designing the vessel so that it will leak before it breaks (like the partly inflated balloon of Chapter 13). Leaks are easy to detect, and a leaking vessel can be taken out of service and repaired. How do we formulate this leak-before-break condition ... 

Electrochemical corrosion is understood to include all corrosion processes that can be influenced electrically. This is the case for all the types of corrosion described in this handbook and means that data on corrosion velocities (e.g., removal rate, penetration rate in pitting corrosion, or rate of pit formation, time to failure of stressed specimens in stress corrosion) are dependent on the potential U [5]. Potential can be altered by chemical action (influence of a redox system) or by electrical factors (electric currents), thereby reducing or enhancing the corrosion. Thus exact knowledge of the dependence of corrosion on potential is the basic hypothesis for the concept of electrochemical corrosion protection processes. 

Fig. 2-17 Relation between the time to failure by intergranular stress corrosion cracking and potential for tensile specimens of soft iron (a) boiling 55% Ca(N03)2 solution, 5 = 0.65 R a = 0.90 R (b) 33% NaOH, a = 300 N mm, at various temperatures.

If, after fabrication, heat treatment is not possible, materials and fabrication methods must have optimum corrosion resistance in their as-fabricated form. Materials that are susceptible to stress corrosion cracking should not be employed in environments conducive to failure. Stress relieving alone does not always provide a reliable solution. 

S = Safety what are the consequences of failure If they are serious, a more resistant material than usual may be justified. For example, on a plant where leaking v. ater would react violently with process materials, the water lines were made from a grade of steel resistant to stress corrosion cracking (from the chloride in the cooling water) as well as rust. 

Consideration must be given to possible equipment corrosion from such external sources as a corrosive atmosphere, spills, insulation, or gland leakage. For example, insulation containing trace quantities of chlorides can cause stress corrosion failure of 18-8 stainless steel vessels and piping. ... 

Corrosion fatigue, therefore, is a special case of stress-corrosion cracking and fatigue failure. Figure 4-451 shows an example of pipe failures due to corrosion fatigue. Corrosion fatigue can be prevented or reduced by ... 

Cracking mechanisms in which corrosion is implicated include stress corrosion cracking, corrosion fatigue, hydrogen-induced cracking and liquid metal embrittlement. Purely mechanical forms of cracking such as brittle failure are not considered here. 

The corrodent is a liquid metal in this form of stress corrosion cracking. Mercury at ambient temperature and metals including zinc (from galvanized steel-work) and copper (from electric cables) when melted during welding or in a fire cause rapid failure of certain metals. 

The arbitrary division of behaviour has been made because of the extreme behaviour of some chemicals that initiate small areas of attack on a well-passivated metal surface. The form of attack may manifest itself as stress-corrosion cracking, crevice attack or pitting. At certain temperatures and pressures, minute quantities of certain chemicals can result in this form of attack. Chloride ions, in particular, are responsible for many of the failures observed, and it can be present as an impurity in a large number of raw materials. This has led to the development of metals and alloys that can withstand pitting and crevice corrosion, but on the whole these are comparatively expensive. It has become important, therefore, to be able to predict the conditions where more conventional materials may be used. The effect of an increase in concentration on pitting corrosion follows a similar relationship to the Freundlich equation where... 

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